Zhu D., Du J., Peng Z. et al. · SmartMat · 2025 · e1322
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
PM1-based NeuVS devices support temporal light encoding, improved blue-colour extraction, trajectory display, and over-95% action recognition accuracy.
Caveat: Colour extraction and action recognition are simulations using measured device responses rather than standalone hardware classification experiments.
9-11 · 3.4-3.5 and Conclusion · Figures 4H and 5 · Linked to 5 structured results
Although the paper uses MOFs in device dielectrics, it does not report electrical conductivity, thermoelectric properties, electrochemical transport, or porosity measurements of a conductive MOF framework.
Caveat: The assigned category is thin-film device/application; MOFs are dielectric/polymer-coordination components.
2-6 · Abstract; 3.2 · Figure 2; Table 1 · Linked to 2 structured results
Adding Zr salts or Zr6 clusters alone decreases device performance, indicating that metal clusters in the MOF do not by themselves account for photoelectrical improvements.
Caveat: PZ1/PZ2 quantitative values are figure-only and are not exactly tabulated in text.
6 · 3.2 · Supporting Information Figures S14-S16 · Linked to 1 structured result
Zr-BTB coordinates with PAA carboxyl groups to improve polymer ordering and crystallinity, evidenced by new diffraction features, higher coherence lengths, increased rDoC, MOF peaks in composites, and modelling of extended PAA chains.
Caveat: Zr-BTB synthesis recipe itself is cited to an external previous method and not reproduced in the supplied documents.
4 · 3.1 · Figure 1; Supporting Information Tables S1-S2 · Linked to 8 structured results
Moderate Zr-BTB loading in PM1 improves C10-DNTT ordering on the dielectric and gives the best mobility, Ion/Ioff, photosensitivity, and dynamic response, whereas excessive MOF loading in PM2 lowers performance.
Caveat: Electrical transport is through C10-DNTT OFET channel; no intrinsic conductive-MOF transport is measured.
4-6 · 3.2 · Figure 2; Table 1; Table S3 · Linked to 7 structured results
The coordination between MOF nodes and polymer carboxyl groups is important, because Zr-BTB benefits carboxyl-containing polymers but harms PAN devices.
Caveat: Control data are mostly trend-level extractions from text/figures rather than exact tabulated values.
6-7 · 3.2 · Supporting Information Figures S19-S21 · Linked to 3 structured results
A moderate amount of MOF in PM1 reduces intermolecular hydrogen bonding, leaves freer hydroxyl groups, and enhances interfacial dipoles that generate more photocarriers.
Caveat: SFG evidence is author-interpreted; numerical peak intensities are not extracted.
6 · 3.2 · Figure 3 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| C10-DNTT organic semiconductor | Not specified | unknown · Pristine2,9-didecyldinaphtho[2,3-b:2,3-f]thieno[3,2-b]thiophene semiconductor channel in the OFET devices. | 2,5 · 2.1 Device Fabrication; 3.2 · Figure 2A |
| MOF-545Browse family: PCN-222 / MOF-545 | Zr6O8(H2O)8(TCPP-H2)2Zr6O8(H2O)8 clusters · TCPP-H2 | unknown · PristineZr MOF control with different particle sizes and rod-like morphologies. | 6 · 3.2 Preparation and Light Detection Properties of NeuVS Devices · Supporting Information Figure S17E |
| PAN/Zr-BTB control dielectrics | Not specifiedZr6 clusters from Zr-BTB · BTB plus PAN matrix | 2D · CompositeZr-BTB blended into polyacrylonitrile (PAN), labelled NM1 and NM2. | 7 · 3.2 Preparation and Light Detection Properties of NeuVS Devices · Supporting Information Figure S21 |
| polyacrylic acid/Zr-BTB control dielectrics | Not specifiedZr6 clusters from Zr-BTB · BTB plus polyacrylic acid carboxyl groups | 2D · CompositeZr-BTB blended into polyacrylic acid at two proportions, labelled aM1 and aM2. | 6-7 · 3.2 Preparation and Light Detection Properties of NeuVS Devices · Supporting Information Figure S20 |
| poly(amic acid) dielectric | Not specified | unknown · PristinePolymer dielectric with free acid groups used as the pristine dielectric control and host for MOF coordination. | 2-4 · 3.1 Preparation and Characterization of MOFs-Polymer Dielectric Layers · Figure 1A |
| PAA/Zr-BTB MOF-polymer dielectric | Not specifiedZr6 clusters from Zr-BTB · BTB in Zr-BTB plus PAA carboxyl groups | 2D · CompositeCoordination-oriented composite dielectric formed by blending Zr-BTB nanosheets into PAA; PM1 and PM2 differ by MOF loading. | 4 · 3.1 Preparation and Characterization of MOFs-Polymer Dielectric Layers · Figure 1 |
| ZrOCl2-8H2O and Zr6(C6H5COOH)12 cluster controls in PAA | ZrOCl2-8H2O; Zr6(C6H5COOH)12Zr species or Zr6 benzoate clusters · benzoate in Zr6(C6H5COOH)12 | 0D · CompositeNon-MOF zirconium species controls used to exclude simple metal-ion/cluster effects. | 6 · 3.2 Preparation and Light Detection Properties of NeuVS Devices · Supporting Information Figures S14-S16 |
| Zr-BTB | Not specifiedZr6 clusters · BTB = benzene-1,3,5-tribenzoate | 2D · PristineLayered Zr-based MOF; Zr6 clusters coordinate with six BTB linkers and have additional coordination sites above and below the layers. | 2-4 · 3.1 Preparation and Characterization of MOFs-Polymer Dielectric Layers · Figure 1A,F |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| aM1 and aM2 polyacrylic acid/Zr-BTB devicesresearch_0758__mat__mof_polyacrylic_acid_controls | Electrode · Composite Sample · Composite | Different Zr-BTB proportions added to polyacrylic acid solution and tested as transistor devices.ITO/glass | 6-7 · 3.2 · Supporting Information Figure S20 |
| MOF-545-T1 and MOF-545-T2 controlsresearch_0758__mat__mof545 | Nanosheet · Composite Component · Pristine Framework | MOF-545 particles added to PAA as PT1 and PT2 devices.~30 x 50 nm and ~15 x 25 nm | 6 · 3.2 · Supporting Information Figures S17C-E; S19 |
| PAA dielectric filmresearch_0758__mat__paa_polyamic_acid | Thin Film · Pristine Control · Unknown | PAA solution with 0 mg/mL MOF spin-coated at 3000 r/min.ITO/glass | 4 · 3.1 · Figure 1A |
| PAA and PAA-on-MOF molecular dynamics model systemsresearch_0758__mat__paa_zrtbtb_composite | Model · Model System · Model | Six PAA structural units per chain; six chains; PAA compared with PAA-on-MOF. | 2,4 · Experimental Section; 3.1 · Figure 1E; Supporting Information Figures S4-S5 |
| PAA-based NeuVS OFETresearch_0758__mat__paa_polyamic_acid | Electrode · Pristine Control · Composite | Bottom-gate top-contact OFET using PAA dielectric, C10-DNTT semiconductor, Au source/drain.ITO/glass · 20 nm C10-DNTT; 20 nm Au | 2 · 2.1 Device Fabrication · Figure 2A |
| PAN, NM1 and NM2 devicesresearch_0758__mat__mof_pan_controls | Electrode · Composite Sample · Composite | PAN pristine device and PAN devices with two ratios of Zr-BTB.ITO/glass | 7 · 3.2 · Supporting Information Figure S21 |
| PM0.5 and PM3 MOF-loading devicesresearch_0758__mat__paa_zrtbtb_composite | Electrode · Composite Sample · Composite | Additional lower/higher Zr-BTB loading systems prepared for optimum-ratio statistics.ITO/glass | 6 · 3.2 · Supporting Information Figure S13 |
| PM1 (PAA-MOF-1) dielectric filmresearch_0758__mat__paa_zrtbtb_composite | Thin Film · Target Sample · Composite | PAA blended with 0.37 mg/mL Zr-BTB, spin-coated at 3000 r/min.ITO/glass | 4 · 3.1 · Figure 1 |
| PM1-based NeuVS OFETresearch_0758__mat__paa_zrtbtb_composite | Electrode · Target Sample · Composite | Bottom-gate top-contact OFET using PM1 dielectric, C10-DNTT semiconductor, Au source/drain.ITO/glass · 20 nm C10-DNTT; 20 nm Au | 7 · 3.3 Temporal Behavior of NeuVS Devices · Figure 4A |
| PM2 (PAA-MOF-2) dielectric filmresearch_0758__mat__paa_zrtbtb_composite | Thin Film · Composite Sample · Composite | PAA blended with 0.73 mg/mL Zr-BTB, spin-coated at 3000 r/min.ITO/glass | 4 · 3.1 · Figure 1; Supporting Information Figure S2 |
| PM2-based NeuVS OFETresearch_0758__mat__paa_zrtbtb_composite | Electrode · Composite Sample · Composite | Bottom-gate top-contact OFET using PM2 dielectric.ITO/glass · 20 nm C10-DNTT; 20 nm Au | 4-5 · 3.2 · Figure 2; Table 1 |
| PM-T1 and PM-T2 devicesresearch_0758__mat__paa_zrtbtb_composite | Electrode · Composite Sample · Composite | PAA devices with thicker Zr-BTB nanosheets.ITO/glass · Zr-BTB-T1 ~15 nm or Zr-BTB-T2 ~40 nm | 6 · 3.2 · Supporting Information Figure S18 |
| PT1 and PT2 MOF-545/PAA devicesresearch_0758__mat__mof545 | Electrode · Composite Sample · Composite | MOF-545-T1 and MOF-545-T2 added into PAA solution and fabricated into C10-DNTT devices.ITO/glass · MOF-545-T1 ~30 x 50 nm; MOF-545-T2 ~15 x 25 nm | 6 · 3.2 · Supporting Information Figure S19 |
| PZ1 and PZ2 Zr-species control devicesresearch_0758__mat__zirconium_cluster_controls | Electrode · Pristine Control · Composite | PAA dielectrics blended with ZrOCl2-8H2O or Zr6(C6H5COOH)12 clusters.ITO/glass | 6 · 3.2 · Supporting Information Figures S14-S16 |
| Zr-BTB nanosheetsresearch_0758__mat__zrtbtb | Nanosheet · Composite Component · Pristine Framework | Synthesised according to previously reported method and blended into PAA.~3 nm | 4 · 3.1 · Supporting Information Figure S1 |
| Zr-BTB-T1 and Zr-BTB-T2 nanosheetsresearch_0758__mat__zrtbtb | Nanosheet · Composite Component · Pristine Framework | Thicker Zr-BTB nanosheets prepared and incorporated into PM-T1 and PM-T2 devices.~15 nm and ~40 nm | 6 · 3.2 · Supporting Information Figure S17A,B; Figure S18 |