cMOF Evidence Base

Synthesis evidence

Metal–Organic Frameworks Coordination-Oriented Polymer Dielectrics for Neuromorphic Vision Sensors

Zhu D., Du J., Peng Z. et al. · SmartMat · 2025 · e1322

9 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Main

Route 1: Unknown

6 · 3.2 · Supporting Information Figure S17C-E

Metal precursorsZr precursor not specified
Linker precursorsTCPP-H2 inferred from reported formula
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
LinkerTCPP-H2Not specified6 · 3.2 · Supporting Information Figure S17C-E
Vague recipeSource: Main

Route 2: Other

6-7 · 3.2 · Supporting Information Figure S20

Metal precursorsZr-BTB nanosheets
Additivespolyacrylic acid solution
Substrate orientationITO/glass device substrate
Work-upDifferent proportions of Zr-BTB added to polyacrylic acid solution; devices tested as aM1 and aM2.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
Otherpolyacrylic acidNot specified6-7 · 3.2 · Supporting Information Figure S20
OtherZr-BTBNot specified6-7 · 3.2 · Supporting Information Figure S20
Partial recipeSource: Main

Route 3: Other

2 · 2.1 Device Fabrication · Figure 2A,B

Metal precursorsAu source/drain electrode
Solventsdeionized water, acetone, isopropanol for substrate cleaning
AdditivesC10-DNTT semiconductor
Atmospherenitrogen drying; evaporation atmosphere not specified
Substrate orientationITO glass, bottom-gate top-contact geometry
Oxidant / reductantO2 plasma
Work-upITO cleaned with deionized water, acetone, isopropanol; dried with nitrogen; O2 plasma (50 W, 5 min); dielectric spin-coated; 20 nm C10-DNTT thermally evaporated at 0.05 A/s; 20 nm Au evaporated through shadow mask.
Scalability context48-device arrays shown; no yield or scale-up recipe.
Show 6 structured reagent records
RoleReagentAmount / concentrationSource
Solventdeionized waterNot specified2 · 2.1 Device Fabrication · Figure 2A,B
SolventacetoneNot specified2 · 2.1 Device Fabrication · Figure 2A,B
SolventisopropanolNot specified2 · 2.1 Device Fabrication · Figure 2A,B
OtherC10-DNTT20 nm film2 · 2.1 Device Fabrication · Figure 2A,B
OtherAu20 nm electrode2 · 2.1 Device Fabrication · Figure 2A,B
OxidantO2 plasma50 W, 5 min2 · 2.1 Device Fabrication · Figure 2A,B
Partial recipeSource: Main

Route 4: Other

2,4 · 2.1 Device Fabrication; 3.1 · Figure 1A

AdditivesPAA polymer solution
Substrate orientationITO/glass
Work-upSpin-coated at 3000 r/min
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
OtherPAANot specified2,4 · 2.1 Device Fabrication; 3.1 · Figure 1A
Partial recipeSource: Both

Route 5: Other

2,4 · 2.1 Device Fabrication; 3.1 · Figure 1A

Metal precursorsZr-BTB nanosheets
AdditivesPAA polymer solution
Substrate orientationITO/glass
Work-upBlend PAA with Zr-BTB; spin-coated at 3000 r/min
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherPAANot specified2,4 · 2.1 Device Fabrication; 3.1 · Figure 1A
OtherZr-BTB MOF nanosheets0.37 mg/mL for PM12,4 · 2.1 Device Fabrication; 3.1 · Figure 1A
Vague recipeSource: Main

Route 6: Other

7 · 3.2 · Supporting Information Figure S21

Metal precursorsZr-BTB nanosheets
AdditivesPAN solution
Substrate orientationITO/glass device substrate
Work-upDifferent ratios of Zr-BTB added to PAN solution; devices tested as NM1 and NM2.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherPANNot specified7 · 3.2 · Supporting Information Figure S21
OtherZr-BTBNot specified7 · 3.2 · Supporting Information Figure S21
Partial recipeSource: Both

Route 7: Other

4 · 3.1 · Figure 1A; Supporting Information Figure S2

Metal precursorsZr-BTB nanosheets
AdditivesPAA polymer solution
Substrate orientationITO/glass
Work-upBlend PAA with Zr-BTB; spin-coated at 3000 r/min
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
OtherPAANot specified4 · 3.1 · Figure 1A; Supporting Information Figure S2
OtherZr-BTB MOF nanosheets0.73 mg/mL for PM24 · 3.1 · Figure 1A; Supporting Information Figure S2
Vague recipeSource: Main

Route 8: Other

6 · 3.2 · Supporting Information Figures S14-S16

Metal precursorsZrOCl2-8H2O; Zr6(C6H5COOH)12 clusters
AdditivesPAA polymer solution
Substrate orientationITO/glass device substrate
Work-upZr species blended into PAA and fabricated into NeuVS devices by the same OFET stack process.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceZrOCl2-8H2ONot specified6 · 3.2 · Supporting Information Figures S14-S16
Metal SourceZr6(C6H5COOH)12Not specified6 · 3.2 · Supporting Information Figures S14-S16
OtherPAANot specified6 · 3.2 · Supporting Information Figures S14-S16
Vague recipeSource: Main

Route 9: Unknown

4 · 3.1 · Supporting Information Figure S1

Linker precursorsBTB = benzene-1,3,5-tribenzoate
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
LinkerBTB = benzene-1,3,5-tribenzoateNot specified4 · 3.1 · Supporting Information Figure S1