Porosity — From non-conductive MOF to proton-conducting metal-HOFs: a new class of reversible transformations induced by solvent-free mechanochemistry

Measurement evidence

Porosity

From non-conductive MOF to proton-conducting metal-HOFs: a new class of reversible transformations induced by solvent-free mechanochemistry · Lupa-Myszkowska M., Oszajca M., Matoga D. · Chemical Science · 2023 · 14176-14181

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CO2 adsorption/desorption

Mn-HOF-FA powder · Powder

CO2 adsorption measurement at 195 K for Mn-HOF-MA and Mn-HOF-FA

Temperature
195
Atmosphere
CO2
Geometry
Powder sorption
Context
Target MHOFs
Measurement source
p024 · Figures and Tables · Figure S38
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Mn-HOF-FA CO2 uptake near p/p0 0.9approximately 6.5 cm3 STP g-1Visual Estimate
Approximate
p024 · Figures and Tables · Figure S38
Mn-HOF-MA CO2 uptake near p/p0 0.9approximately 6.5 cm3 STP g-1Visual Estimate
Approximate
p024 · Figures and Tables · Figure S38

N2 adsorption/desorption

Mn-HOF-FA powder · Powder

N2 adsorption measurement at 77 K for Mn-HOF-MA and Mn-HOF-FA

Temperature
77
Atmosphere
N2
Geometry
Powder sorption
Context
Target MHOFs
Measurement source
p024 · Figures and Tables · Figure S37
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Mn-HOF-FA N2 uptake near p/p0 1.0approximately 15-16 cm3 STP g-1Visual Estimate
Approximate
p024 · Figures and Tables · Figure S37
Mn-HOF-MA N2 uptake near p/p0 1.0approximately 21 cm3 STP g-1Visual Estimate
Approximate
p024 · Figures and Tables · Figure S37

Water vapour adsorption/desorption

Mn-HOF-FA powder · Powder

H2O adsorption at 293 K for JUK-1, JUK-2, Mn-HOF-FA and Mn-HOF-MA

Temperature
293
Atmosphere
Water vapour
Geometry
Powder sorption; Autosorb iQ-CXR-XR EPDM
Context
Target and comparison frameworks
Measurement source
p026 · Figures and Tables · Figure S40
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Mn-HOF-FA H2O uptake near p/p0 0.9approximately 320-340 cm3 STP g-1Visual Estimate
Approximate
p026 · Figures and Tables · Figure S40
JUK-2 H2O uptake near p/p0 0.9approximately 1200 cm3 STP g-1Visual Estimate
Approximate
p026 · Figures and Tables · Figure S40
Mn-HOF-MA H2O uptake near p/p0 0.9approximately 850-900 cm3 STP g-1Visual Estimate
Approximate
p026 · Figures and Tables · Figure S40