Vague recipeSource: SI
Route 1: Unknown
p004 · Synthesis of JUK-1
Synthesis evidence
From non-conductive MOF to proton-conducting metal-HOFs: a new class of reversible transformations induced by solvent-free mechanochemistry
Lupa-Myszkowska M., Oszajca M., Matoga D. · Chemical Science · 2023 · 14176-14181
4 structured synthesis routes
Completeness describes how fully the route could be reconstructed from the main article and supporting information.
Vague recipeSource: SI
Route 2: Unknown
p004 · Synthesis of JUK-2
AdditivesNH4SCN, from cited prior mechanochemical route
ActivationFor water vapour adsorption, JUK-2 samples were activated at 25 deg C under vacuum for 24 h.
Show 1 structured reagent record
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Additive | NH4SCN | Not specified | p004 · Synthesis of JUK-2 |
Complete recipeSource: Both
Route 3: Other
p004 · Synthesis of Mn-HOF-FA
Metal precursorsJUK-1 parent Mn MOF, 100.0 mg, 0.138 mmol
Linker precursorsIsonicotinate already present in JUK-1
Solvents75 uL 92% EtOH as LAG liquid
AdditivesCH(NH2)2SCN, 56.8 mg, 0.550 mmol
AtmosphereAir
Temperatureroom temperature
Time0.167
ActivationFor water vapour adsorption, Mn-HOF samples were activated at 25 deg C under vacuum for 24 h. For EIS, approx. 30 mg was equilibrated at the specified RH for 1 day at 25 deg C.
Scalability contextFast solvent-free/liquid-assisted grinding in an agate mortar for approx. 10 min.
Show 3 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | JUK-1 | 100.0 mg, 0.138 mmol | p004 · Synthesis of Mn-HOF-FA |
| Additive | CH(NH2)2SCN | 56.8 mg, 0.550 mmol | p004 · Synthesis of Mn-HOF-FA |
| Solvent | 92% EtOH | 75 uL · 92% | p004 · Synthesis of Mn-HOF-FA |
Complete recipeSource: Both
Route 4: Other
p004 · Synthesis of Mn-HOF-MA
Metal precursorsJUK-1 parent Mn MOF, 100.0 mg, 0.138 mmol
Linker precursorsIsonicotinate already present in JUK-1
Solvents75 uL 92% EtOH as LAG liquid
AdditivesCH3NH3SCN, 49.6 mg, 0.550 mmol
AtmosphereAir
Temperatureroom temperature
Time0.167
ActivationFor water vapour adsorption, Mn-HOF samples were activated at 25 deg C under vacuum for 24 h. For EIS, approx. 30 mg was equilibrated at the specified RH for 1 day at 25 deg C.
Scalability contextFast solvent-free/liquid-assisted grinding in an agate mortar for approx. 10 min.
Show 3 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | JUK-1 | 100.0 mg, 0.138 mmol | p004 · Synthesis of Mn-HOF-MA |
| Additive | CH3NH3SCN | 49.6 mg, 0.550 mmol | p004 · Synthesis of Mn-HOF-MA |
| Solvent | 92% EtOH | 75 uL · 92% | p004 · Synthesis of Mn-HOF-MA |