Spectroscopy — From non-conductive MOF to proton-conducting metal-HOFs: a new class of reversible transformations induced by solvent-free mechanochemistry

2 measurement groups · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Mn-HOF-FA powder · Powder

Room-temperature PXRD and ATR-FTIR after liquid-assisted grinding of JUK-1 with CH(NH2)2SCN

Temperature: 295
Atmosphere: Ambient
Context: Target MHOF compared with JUK-1 and FASCN
Measurement source: p003 · Postsynthetic modification and physicochemical characterization · Fig. 1, Fig. S2, Fig. S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Mn-HOF-FA coordinated thiocyanate CN stretch	2098 cm-1	—	—	Text Exact Reported	p003 · Postsynthetic modification and physicochemical characterization · Fig. 1

Mn-HOF-MA powder · Powder

Room-temperature PXRD and ATR-FTIR after liquid-assisted grinding of JUK-1 with CH3NH3SCN

Temperature: 295
Atmosphere: Ambient
Context: Target MHOF compared with JUK-1 and MASCN
Measurement source: p003 · Postsynthetic modification and physicochemical characterization · Fig. 1, Fig. S3, Fig. S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Mn-HOF-MA coordinated thiocyanate CN stretch	2078 cm-1	—	—	Text Exact Reported	p003 · Postsynthetic modification and physicochemical characterization · Fig. 1