Electrical Transport — Stabilization of NASICON-Type Electrolyte against Li Anode via an Ionic Conductive MOF-Incorporated Adhesive Interlayer

Measurement evidence

Electrical Transport

Stabilization of NASICON-Type Electrolyte against Li Anode via an Ionic Conductive MOF-Incorporated Adhesive Interlayer · Zhao R., Gao L., Song M. et al. · ACS Energy Letters · 2021 · 3141-3150

4 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Electrochemical impedance spectroscopy (EIS)

sintered LAGP pellet · Pellet

Au sputtered on both sides as blocking current collectors; 1 Hz to 1 MHz, 10-50 mV disturbance

Temperature
303, 333, 373
Geometry
gold | LAGP pellet | gold
Context
pristine LAGP control
Measurement source
2 · 1.3 Electrochemical measurement
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
LAGP activation energy0.3 eVText
Exact Reported
3144 · Results · Figure 2a
LAGP ionic conductivity at 100 CMarked as a best value within this paper0.00175 S cm-1 at 100 CText
Approximate
3144 · Results · Figure 2a
LAGP ionic conductivity at 30 C0.00024 S cm-1 at 30 CText
Approximate
3144 · Results · Figure 2a
LAGP ionic conductivity at 60 C0.000825 S cm-1 at 60 CText
Rounded Reported
3144 · Results · Figure 2a

Electrochemical impedance spectroscopy (EIS)

MOF-free PEO/LiTFSI interlayer · Thin Film

MOF-free PEO/LiTFSI control at different temperatures

Temperature
303, 313, 323, 333
Geometry
16 mm disc, 240 um thick
Context
MOF-free polymer control
Measurement source
6 · Supplementary Figures · Figure S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
PEO/LiTFSI EIS film thickness240 umCaption
Exact Reported
6 · Supplementary Figures · Figure S5
PEO/LiTFSI ionic conductivity at 30 C1e-07 S cm-1 at 30 CCaption
Rounded Reported
6 · Supplementary Figures · Figure S5
PEO/LiTFSI ionic conductivity at 40 C4.2e-07 S cm-1 at 40 CCaption
Rounded Reported
6 · Supplementary Figures · Figure S5
PEO/LiTFSI ionic conductivity at 50 C1.8e-06 S cm-1 at 50 CCaption
Rounded Reported
6 · Supplementary Figures · Figure S5
PEO/LiTFSI ionic conductivity at 60 CMarked as a best value within this paper3.8e-05 S cm-1 at 60 CCaption
Rounded Reported
6 · Supplementary Figures · Figure S5

Electrochemical impedance spectroscopy (EIS)

ZCPL film/interlayer · Thin Film

ZCPL encapsulated in coin-type cell; stainless-steel blocking electrodes; 1 Hz to 1 MHz, 10-50 mV

Temperature
303, 333
Geometry
stainless steel | ZCPL film | stainless steel; 10 mm disc, about 150 um thick
Context
MOF-polymer composite
Measurement source
3143-3144 · Figure caption and Results · Figure 2b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZCPL EIS film thicknessabout 150 umCaption
Approximate
3143 · Figure caption · Figure 2b
ZCPL ionic conductivity at 30 Caround 1.4e-06 S cm-1 at 30 CText
Approximate
3144 · Results · Figure 2b
ZCPL ionic conductivity at 60 CMarked as a best value within this paperaround 0.00026 S cm-1 at 60 CText
Approximate
3144 · Results · Figure 2b

Electrochemical impedance spectroscopy (EIS)

ZCPL-LAGP electrolyte · Pellet

Sandwich-structured ZCPL-LAGP electrolyte; fitted by equivalent circuit with bulk and interfacial components

Temperature
333 and room temperature
Geometry
ZCPL | LAGP | ZCPL sandwich electrolyte
Context
composite MOF-polymer coated LAGP
Measurement source
3144 · Results · Figure 2c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZCPL-LAGP total LAGP+ZCPL resistance at 60 CR0 + R1 = 230 ohm at 60 CText
Exact Reported
3144 · Results · Figure 2c
ZCPL-LAGP total LAGP+ZCPL resistance at room temperatureRLAGP+RZCPL = 4610 ohmCaption
Exact Reported
8 · Supplementary Figures · Figure S10
ZCPL-LAGP interfacial resistance at 60 CR2 = 355 ohm at 60 CText
Exact Reported
3144 · Results · Figure 2c
ZCPL-LAGP interfacial resistance at room temperatureRLAGP/ZCPL = 3250 ohmCaption
Exact Reported
8 · Supplementary Figures · Figure S10