Spectroscopy — Stabilization of NASICON-Type Electrolyte against Li Anode via an Ionic Conductive MOF-Incorporated Adhesive Interlayer

2 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

sintered LAGP pellet · Pellet

Li 1s and Ge 3d spectra before and after Li/LAGP/Li cycling

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ge3+ peak after LAGP cycling	31.4 eV attributed to Ge3+	—	—	Text Exact Reported	3146 · Results · Figure 4b
Pristine LAGP Ge 3d binding energy	32.6 eV; Ge4+	—	—	Text Exact Reported	3146 · Results · Figure 4a
Metallic Ge peak after LAGP cycling	29.4 eV attributed to metallic Ge	—	—	Text Exact Reported	3146 · Results · Figure 4b
Pristine LAGP Li 1s binding energy	55.8 eV	—	—	Text Exact Reported	3146 · Results · Figure 4a
Li2O2 peak after LAGP cycling	additional Li 1s peak at 54.8 eV revealing Li2O2	—	—	Text Exact Reported	3146 · Results · Figure 4b

ZCPL-LAGP electrolyte · Pellet

Li 1s and Ge 3d spectra of LAGP part after cycling; Co 2p and N 1s spectra of ZCPL part before/after cycling

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ZCPL Co 2p1/2 before cycling	796.7 eV assigned to Co 2p1/2	—	—	Text Exact Reported	3146 · Results · Figure S16
ZCPL Co 2p3/2 before cycling	781.6 eV assigned to Co 2p3/2	—	—	Text Exact Reported	3146 · Results · Figure S16
ZCPL-LAGP LAGP-part XPS stability	Li 1s and Ge 3d spectra almost the same before and after cycling	—	—	Text Qualitative	3146 · Results · Figure 4c
ZCPL N 1s before cycling	singlet peak at 399.0 eV corresponding to N atom of 2-methylimidazolate	—	—	Text Exact Reported	3146 · Results · Figure S17
ZCPL Co 2p and N 1s after cycling	spectra remained consistent with before cycling	—	—	Text Qualitative	3146 · Results · Figures S18-S19