Electrochemistry Application — Stabilization of NASICON-Type Electrolyte against Li Anode via an Ionic Conductive MOF-Incorporated Adhesive Interlayer

8 measurement groups · 30 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Galvanostatic charge-discharge full-cell cycling

Galvanostatic cycling

Li/LAGP/LFP full cell · Electrode

Li/LAGP/LFP, 0.1 C, 60 C, 2.7-3.9 V; cells equilibrated at 60 C for 12 h before test

Temperature: 333
Atmosphere: assembled in Ar glove box
Geometry: Li | LAGP | LFP
Context: unprotected LAGP full-cell control
Measurement source: 3147 · Results · Figure 5a,c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li/LAGP/LFP capacity after 35 cycles	62 mAh g-1 after 35 cycles	—	—	Text Exact Reported	3147 · Results · Figure 5c
Li/LAGP/LFP charge plateau	3.49 V	—	—	Text Exact Reported	3147 · Results · Figure 5a
Li/LAGP/LFP discharge plateau	3.35 V	—	—	Text Exact Reported	3147 · Results · Figure 5a
Li/LAGP/LFP initial specific capacity	87 mAh g-1	—	—	Text Exact Reported	3147 · Results · Figure 5a

Galvanostatic charge-discharge full-cell cycling

Galvanostatic cycling

Li/ZCPL-LAGP/LFP full cell · Electrode

Li/ZCPL-LAGP/LFP, 0.1 C, 60 C, 2.7-3.9 V; cells equilibrated at 60 C for 12 h before test

Temperature: 333
Atmosphere: assembled in Ar glove box
Geometry: Li | ZCPL-LAGP | LFP
Context: MOF-polymer coated LAGP full cell
Measurement source: 3147 · Results · Figure 5b,d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li/ZCPL-LAGP/LFP capacity after 10 cycles	134 mAh g-1 after 10 cycles	—	—	Text Exact Reported	3147 · Results · Figure 5d
Li/ZCPL-LAGP/LFP capacity after 35 cycles	130 mAh g-1 after 35 cycles	—	—	Text Exact Reported	3147 · Results · Figure 5d
Li/ZCPL-LAGP/LFP capacity after 60 cyclesMarked as a best value within this paper	110 mAh g-1 after 60 cycles	—	—	Text Exact Reported	3147 · Results · Figure 5d
Li/ZCPL-LAGP/LFP charge plateau	3.44 V	—	—	Text Exact Reported	3147 · Results · Figure 5b
Li/ZCPL-LAGP/LFP discharge plateau	3.40 V	—	—	Text Exact Reported	3147 · Results · Figure 5b
Li/ZCPL-LAGP/LFP initial specific capacityMarked as a best value within this paper	138 mAh g-1	—	—	Text Exact Reported	3147 · Results · Figure 5b

Galvanostatic cycling under stepwise increased current densities

Galvanostatic cycling

Li/ZCPL-LAGP/Li symmetric cell · Electrode

60 C; fixed step 0.1 mA cm-2; 30 min plating/stripping; cutoff -4 to 4 V

Temperature: 333
Atmosphere: coin cell assembled in Ar glove box
Geometry: Li | ZCPL-LAGP | Li
Context: MOF-polymer coated LAGP
Measurement source: 10-11 · Supplementary Figures · Figures S14-S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li/ZCPL-LAGP/Li critical current density before cutoffMarked as a best value within this paper	sustain a high current density of 1.8 mA cm-2 until cutoff voltage (-4 to 4 V) was exceeded	—	—	Text Exact Reported	3146 · Results · Figure S14
Li/ZCPL-LAGP/Li polarisation at 0.3 mA cm-2	0.4 V at 0.3 mA cm-2	—	—	Text Exact Reported	3146 · Results · Figure S15
Li/ZCPL-LAGP/Li polarisation at 0.4 mA cm-2	0.6 V at 0.4 mA cm-2	—	—	Text Exact Reported	3146 · Results · Figure S15

Time-dependent EIS of symmetric cell

Impedance spectroscopy

Li/LAGP/Li symmetric cell · Electrode

Li/LAGP/Li after 0, 100, 200, 300 h operating times, fitted with Figure S12 equivalent circuit

Temperature: 333
Atmosphere: coin cell assembled in Ar glove box
Geometry: Li | LAGP | Li
Context: unprotected LAGP control
Measurement source: 3146 · Results · Figure 3b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li/LAGP/Li initial per-interface resistance	580 ohm	—	—	Calculated From Reported Exact Reported	3146 · Results · Figure 3b
Li/LAGP/Li initial total interface resistance	around 1160 ohm for two symmetric interfaces	—	—	Text Approximate	3146 · Results · Figure 3b
Li/LAGP/Li initial LAGP pellet resistance	around 120 ohm	—	—	Text Approximate	3146 · Results · Figure 3b
Li/LAGP/Li whole-cell resistance after 300 h	15470 ohm	—	—	Text Exact Reported	3146 · Results · Figure 3b
Li/LAGP/Li whole-cell resistance initial	1280 ohm	—	—	Text Exact Reported	3146 · Results · Figure 3b
Li/LAGP/Li interfacial resistance after 100 h	around 3940 ohm	—	—	Text Approximate	3146 · Results · Figure 3b
Li/LAGP/Li interfacial resistance after 200 h	around 5180 ohm	—	—	Text Approximate	3146 · Results · Figure 3b
Li/LAGP/Li interfacial resistance after 300 hMarked as a best value within this paper	around 7670 ohm	—	—	Text Approximate	3146 · Results · Figure 3b

Time-dependent EIS of symmetric cell

Impedance spectroscopy

Li/ZCPL-LAGP/Li symmetric cell · Electrode

Li/ZCPL-LAGP/Li after 0, 100, 200, 300 h operating times, fitted with Figure S12 equivalent circuit

Temperature: 333
Atmosphere: coin cell assembled in Ar glove box
Geometry: Li | ZCPL-LAGP | Li
Context: MOF-polymer coated LAGP
Measurement source: 3146 · Results · Figure 3c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li/ZCPL-LAGP/Li initial interfacial resistance	about 240 ohm	—	—	Text Approximate	3146 · Results · Figure 3c
Li/ZCPL-LAGP/Li interfacial resistance after 100 h	around 270 ohm	—	—	Text Approximate	3146 · Results · Figure 3c
Li/ZCPL-LAGP/Li interfacial resistance after 200 h	around 260 ohm	—	—	Text Approximate	3146 · Results · Figure 3c
Li/ZCPL-LAGP/Li interfacial resistance after 300 hMarked as a best value within this paper	around 285 ohm	—	—	Text Approximate	3146 · Results · Figure 3c

Galvanostatic Li plating/stripping

Galvanostatic cycling

Li/PEO-LiTFSI-LAGP/Li symmetric cell · Electrode

Li/PEO-LiTFSI-LAGP/Li symmetric cell at 60 C; 0.05 mA cm-2 before 300 h and 0.1 mA cm-2 after 300 h

Temperature: 333
Atmosphere: coin cell assembled in Ar glove box
Geometry: Li | PEO/LiTFSI-LAGP | Li
Context: MOF-free coated LAGP control
Measurement source: 9 · Supplementary Figures · Figure S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li/PEO-LiTFSI-LAGP/Li polarisation voltage in first 300 h	~0.25 V	—	—	Text Approximate	3145-3146 · Results · Figure S11

Galvanostatic Li plating/stripping

Galvanostatic cycling

Li/ZCPL-LAGP/Li symmetric cell · Electrode

Li/ZCPL-LAGP/Li symmetric cell at 60 C; current densities 0.05, 0.1, 0.15 mA cm-2

Temperature: 333
Atmosphere: coin cell assembled in Ar glove box
Geometry: Li | ZCPL-LAGP | Li
Context: MOF-polymer coated LAGP
Measurement source: 3145 · Results · Figure 3a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li/ZCPL-LAGP/Li polarisation voltage at 0.05 mA cm-2Marked as a best value within this paper	0.06 V at 0.05 mA cm-2	—	—	Text Exact Reported	3145 · Results · Figure 3a
Li/ZCPL-LAGP/Li polarisation voltage at 0.1 mA cm-2	0.14 V at 0.1 mA cm-2	—	—	Text Exact Reported	3145 · Results · Figure 3a
Li/ZCPL-LAGP/Li polarisation voltage at 0.15 mA cm-2	0.26 V at 0.15 mA cm-2	—	—	Text Exact Reported	3145 · Results · Figure 3a

Linear sweep voltammetry (LSV)

Voltammetry

ZCPL film/interlayer · Thin Film

ZCPL and PEO/LiTFSI at 60 C; inset zoom around 4 V

Temperature: 333
Geometry: polymer electrolyte electrochemical window test
Context: MOF-polymer composite vs MOF-free polymer
Measurement source: 8 · Supplementary Figures · Figure S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ZCPL electrochemical stability window vs PEO/LiTFSI	ZCPL showed a much higher voltage window than PEO/LiTFSI at 60 C	—	—	Caption Qualitative	8 · Supplementary Figures · Figure S9