cMOF Evidence Base
Diffraction Structure — Metal-organic framework glass stabilizes high-voltage cathodes for efficient lithium-metal batteries

Measurement evidence

Diffraction Structure

Metal-organic framework glass stabilizes high-voltage cathodes for efficient lithium-metal batteries · Bai L., Xu Y., Liu Y. et al. · Nature Communications · 2025 · 3484

2 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

XRD and HR-TEM of cycled cathodes

X-ray diffraction and scatteringTransmission electron microscopy

Glass@NCM-811, 2 wt% MOF Glass coating · Powder

Cycled Glass@NCM-811 and bare NCM-811 after electrochemical cycling; XRD I003/I104 and TEM/FTIR surface analysis.

Atmosphere
Ar transfer and DME washing for cycled samples
Geometry
cycled cathode particles
Context
composite with pristine control
Measurement source
main p.6 · Glass@NCM-811 cathode suppresses cathode cracks · Fig. 3k,l-q
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Bare NCM-811 cycled CEI thickness30-60 nm, up to 80 nm——Text
Range		main p.6 · Glass@NCM-811 cathode suppresses cathode cracks · Fig. 3l; Supplementary Figs. 47-48
Glass@NCM-811 cycled cation mixingno obvious cation-mixed rock-salt phases detected——Qualitative
Qualitative		main p.6 · Glass@NCM-811 cathode suppresses cathode cracks · Fig. 3o-q
Cycled I(003)/I(104) for bare NCM-8111.56——Figure Axis
Rounded Reported		main p.6 · Fig. 3 axis · Fig. 3k
Cycled I(003)/I(104) for Glass@NCM-8111.83——Figure Axis
Rounded Reported		main p.6 · Fig. 3 axis · Fig. 3k
Initial I(003)/I(104) for bare NCM-8111.82——Figure Axis
Rounded Reported		main p.5 · Fig. 2 caption/axis · Fig. 2a
Initial I(003)/I(104) for Glass@NCM-8111.86——Figure Axis
Rounded Reported		main p.5 · Fig. 2 caption/axis · Fig. 2a

Powder X-ray diffraction

X-ray diffraction and scattering

Bulk Zn-P-dmbIm MOF Glass · Unknown

Cu-Kalpha XRD, scan rate 0.016 deg/s; compares Zn-P-dmbIm MOF powder, MOF liquid and MOF Glass.

Geometry
powder/glass
Context
pristine MOF/glass
Measurement source
main p.2-3 · Results and discussion · Fig. 1c; Supplementary Fig. 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
MOF Glass phase assignmentshort-range ordered/amorphous XRD characteristic——Qualitative
Qualitative		main p.2 · Results and discussion · Fig. 1c; Supplementary Fig. 4