cMOF Evidence Base
Other — Metal-organic framework glass stabilizes high-voltage cathodes for efficient lithium-metal batteries

Measurement evidence

Other

Metal-organic framework glass stabilizes high-voltage cathodes for efficient lithium-metal batteries · Bai L., Xu Y., Liu Y. et al. · Nature Communications · 2025 · 3484

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Contact-angle/wetting observation of MOF liquid on cathode electrodes

Contact angle and wettability

Glass@NCM-811, 2 wt% MOF Glass coating · Powder

MOF liquid at 175-195 deg C contacted NCM-811; 175 deg C also tested on LRMO and LCO.

Temperature
448-468
Atmosphere
not specified
Geometry
droplet on cathode electrode
Context
MOF liquid infusion into cathode electrodes
Measurement source
main p.4 · Results and discussion · Fig. 1i; Supplementary Figs. 23-24
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
MOF liquid wetting time on LRMO/LCO at 175 deg C6-8 s——Text
Range		SI p.25 · Supplementary Fig. 23 · Supplementary Fig. 23
MOF liquid wetting time on NCM-811 at 175 deg Cabout 6 s from Supplementary Fig. 24 frames——Visual Estimate
Approximate		SI p.26 · Supplementary Fig. 24 · Supplementary Fig. 24

TGA/DSC thermal analysis

Calorimetry and thermal analysisThermogravimetric analysis

As-prepared Zn-P-dmbIm MOF powder · Powder

Under N2 in SI discussion; DSC method also states dry Ar from 30 to 300 deg C at 5 deg C/min.

Atmosphere
N2 for SI TGA/DSC discussion; dry Ar for DSC method
Geometry
powder
Context
pristine MOF powder and derived glass
Measurement source
SI p.3 · Supplementary Fig. 2 · Supplementary Fig. 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Zn-P-dmbIm decomposition temperatureTd = 219.3 deg C——Figure Axis
Rounded Reported		SI p.3 · Supplementary Fig. 2 · Supplementary Fig. 2
MOF Glass glass-transition temperatureabout 112.5 deg C——Text
Approximate		SI p.3 · Supplementary Fig. 2 · Supplementary Fig. 2
Zn-P-dmbIm melting temperatureabout 175 deg C——Text
Approximate		SI p.3 · Supplementary Fig. 2 · Supplementary Fig. 2

Viscosity measurement of MOF liquid

Bulk Zn-P-dmbIm MOF Glass · Unknown

MOF liquid viscosity measured at 115, 175, 185 and 195 deg C.

Temperature
388-468
Atmosphere
not specified
Geometry
MOF liquid
Context
pristine MOF liquid precursor to glass
Measurement source
SI p.7 · Supplementary Fig. 5 · Supplementary Fig. 5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
MOF liquid viscosity at 115 deg C60.5 Pa.s——Text
Exact Reported		SI p.7 · Supplementary Fig. 5 · Supplementary Fig. 5
MOF liquid viscosity at 175 deg C45.2 Pa.s——Text
Exact Reported		SI p.7 · Supplementary Fig. 5 · Supplementary Fig. 5
MOF liquid viscosity at 185 deg C38.6 Pa.s——Text
Exact Reported		SI p.7 · Supplementary Fig. 5 · Supplementary Fig. 5
MOF liquid viscosity at 195 deg C27.6 Pa.s——Text
Exact Reported		SI p.7 · Supplementary Fig. 5 · Supplementary Fig. 5