Vague recipeSource: Main
Route 1: Unknown
p.7 / article p.2411386-7 · Experimental Section · Materials
Metal precursorsnot reported in this paper
Linker precursorsnot reported in this paper
Solventsnot reported in this paper
Synthesis evidence
Interconnected Lamellar 3D Semiconductive PCP for Rechargeable Aqueous Zinc Battery Cathodes
Lin Z., Otake K.-I., Kajiwara T. et al. · Small · 2025 · 2411386
4 structured synthesis routes
Completeness describes how fully the route could be reconstructed from the main article and supporting information.
Complete recipeSource: Main
Route 2: Drop Cast
p.8 / article p.2411386-8 · Electrochemical Measurements
Solventsdeionized water
AdditivesSuper P conductive additive; 10% PTFE binder
Atmosphereambient drying at room temperature
Temperatureroom temperature
Timeovernight drying
Substrate orientationgraphite foil discs, 11 mm diameter
Work-upSlurry drop-cast onto graphite foil and dried overnight.
ActivationCells tested after 1 GDC cycle to exclude irreversible double-layer migration/arrangement.
Scalability contextVO-HHTP mass loading about 1.3 mg cm-2.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | VO-HHTP | 5 parts by weight | p.8 / article p.2411386-8 · Electrochemical Measurements |
| Additive | Super P conductive additive | 4 parts by weight | p.8 / article p.2411386-8 · Electrochemical Measurements |
| Additive | 10% PTFE binder | 1 part by weight · 10% | p.8 / article p.2411386-8 · Electrochemical Measurements |
| Solvent | deionized water | not specified | p.8 / article p.2411386-8 · Electrochemical Measurements |
Complete recipeSource: Main
Route 3: Drop Cast
p.8 / article p.2411386-8 · Electrochemical Measurements
Solventsdeionized water
AdditivesSuper P conductive additive; 10% PTFE binder
Atmosphereambient drying at room temperature
Temperatureroom temperature
Timeovernight drying
Substrate orientationgraphite foil discs, 11 mm diameter
Work-upSlurry drop-cast onto graphite foil and dried overnight.
ActivationCells tested after 1 GDC cycle to exclude irreversible double-layer migration/arrangement.
Scalability contextVO-HHTP mass loading about 1.3 mg cm-2.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | VO-HHTP | 8 parts by weight | p.8 / article p.2411386-8 · Electrochemical Measurements |
| Additive | Super P conductive additive | 1 part by weight | p.8 / article p.2411386-8 · Electrochemical Measurements |
| Additive | 10% PTFE binder | 1 part by weight · 10% | p.8 / article p.2411386-8 · Electrochemical Measurements |
| Solvent | deionized water | not specified | p.8 / article p.2411386-8 · Electrochemical Measurements |
Complete recipeSource: Both
Route 4: Other
p.8 / article p.2411386-8 · Experimental Section · Synthesis of (VO)3(HHTP)2
Metal precursorsVOSO4 hydrate, 453 mg (2 mmol), 72%
Linker precursorsHHTP, 324 mg (1 mmol), 95.0%
SolventsWater, 50 mL
Atmospherenot specified; reflux in water
Temperaturereflux; final drying at 40 C
Time1 h room-temperature stirring plus 48 h reflux; vacuum oven overnight
Oxidant / reductantVO2+ source VOSO4; no separate oxidant/reductant reported
Work-upSolid separated by centrifugation while hot, then washed sequentially with water and methanol.
ActivationVacuum dried at 40 C overnight; separate activated sample under 100 C for 10 h under N2 reported for TG.
Scalability context125 mg product, 30% yield from 1 mmol HHTP scale.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | 2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP) | 324 mg (1 mmol) · 95.0% | p.8 / article p.2411386-8 · Experimental Section · Synthesis of (VO)3(HHTP)2 |
| Metal Source | vanadyl sulfate hydrate (VOSO4) | 453 mg (2 mmol) · 72% | p.8 / article p.2411386-8 · Experimental Section · Synthesis of (VO)3(HHTP)2 |
| Solvent | water | 50 mL | p.8 / article p.2411386-8 · Experimental Section · Synthesis of (VO)3(HHTP)2 |
| Solvent | methanol wash | not specified · 99.0% | p.8 / article p.2411386-8 · Experimental Section · Synthesis of (VO)3(HHTP)2 |