Microscopy Morphology — Conductive metal-organic framework synthesis from metal nanoparticle precursors

6 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu-on-paper no-TBMAMS failed synthesis control · Thin Film

No-TBMAMS Cu-on-paper control; triangular prismatic crystals probed by EDX.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
no-electrolyte crystal carbon content	68.50 wt% carbon	—	—	Text Exact Reported	p019 · Method Development · Figure S21
no-electrolyte crystal nitrogen content	28.92 wt% nitrogen	—	—	Text Exact Reported	p019 · Method Development · Figure S21
no-electrolyte triangular crystal size	8 um edge length	—	—	Text Exact Reported	p018 · Method Development · Figure S20

Cu3(HITP)2 on white paper time-series samples · Thin Film

Optimised Cu-on-paper sample prepared with ligand, ammonia and TBMAMS electrolyte.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optimised electrolyte sample elemental co-presence	Cu, C and N present in material grown on paper	—	—	Text Qualitative	p020 · Method Development · Figure S22

Cu3(HITP)2 on white paper time-series samples · Thin Film

Cu nanoparticles on paper imaged after 0 min, 10 min, 1 h and 24 h submersion; 10 um and 1 um scale bars.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu MOF first visibly forms on paperMarked as a best value within this paper	visible within 10 min	—	—	Caption Rounded Reported	p008 · Results and discussion · Figure 5
Cu larger amalgamated crystallites on paper	larger rounded features after 1 h	—	—	Text Rounded Reported	p007 · Results and discussion · Figure 5
minimum Cu:Ni growth-rate ratio on paper	Cu MOF at least 6 times faster than Ni MOF	—	—	Calculated From Reported Approximate	p007 · Results and discussion · Figures S2-S3

Cu3(HITP)2 on cotton fabric · Thin Film

Cu3(HITP)2 on cotton, glass, Au(111), with supporting SI images on paper; 1 h growth.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu MOF forms on tested substrate set	features larger than initial nanoparticles on cotton, Au(111), Pt/glass IDE and paper	—	—	Text Qualitative	p007-p009 · Results and discussion · Figure 6

Ni3(HITP)2 on cotton fabric · Thin Film

Ni3(HITP)2 on fabric, gold, glass and paper after 1 h growth.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni MOF forms on tested substrate set	similar structures form on same substrates; broadening less pronounced within 1 h	—	—	Text Qualitative	p009 · Results and discussion · Figure S5

Ni3(HITP)2 on white paper time-series samples · Thin Film

Ni nanoparticles on paper imaged after the same submersion time series as Cu samples.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ni larger MOF features on paper	not until between 1 h and 2 h	—	—	Visual Estimate Range	p007 · Results and discussion · Figures S2-S3