Synthesis · Detection of Ascorbic Acid by Two-Dimensional Conductive Metal-Organic Framework-Based Electrochemical Sensors

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

8 · 3.2.2. The Synthesis of Cu3(HHTP)2

Metal precursors0.320 g Cu(OAc)2-H2O

Linker precursors0.260 g HHTP

SolventsCH4O (methanol), 100 mL for Cu(OAc)2-H2O and 125 mL for HHTP

Atmospheresealed volumetric flask; atmosphere not specified

Temperature65

Time24

Work-upBlue-black solid washed with methanol and acetone.

ActivationDried under vacuum at 80 C for 12 h.

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(OAc)2-H2O	0.320 g	8 · 3.2.2. The Synthesis of Cu3(HHTP)2
Linker	HHTP	0.260 g	8 · 3.2.2. The Synthesis of Cu3(HHTP)2
Solvent	CH4O	100 mL + 125 mL	8 · 3.2.2. The Synthesis of Cu3(HHTP)2
Solvent	methanol	wash solvent	8 · 3.2.2. The Synthesis of Cu3(HHTP)2
Solvent	acetone	wash solvent	8 · 3.2.2. The Synthesis of Cu3(HHTP)2

Complete recipeSource: Main

8 · 3.2.3. The Preparation of Cu3(HHTP)2/SPE

Metal precursorsCu3(HHTP)2 powder

SolventsCH4O (methanol)

Atmosphereambient; not explicitly specified

Temperatureroom temperature

Substrate orientationworking electrode surface of SPE

Work-upDried at room temperature and stored at room temperature.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Cu3(HHTP)2	4 mg · 4 mg/mL dispersion	8 · 3.2.3. The Preparation of Cu3(HHTP)2/SPE
Solvent	CH4O	1 mL	8 · 3.2.3. The Preparation of Cu3(HHTP)2/SPE
Other	Cu3(HHTP)2 dispersion	2 uL applied dropwise · 4 mg/mL	8 · 3.2.3. The Preparation of Cu3(HHTP)2/SPE

Complete recipeSource: Main

7-8 · 3.2.1. Electrode Pretreatment

Solvents0.5 mol/L H2SO4 aqueous solution

Atmospherenot specified

Work-upRinsed with deionized water and blow-dried.

ActivationCV from -1.0 to 1.0 V at 100 mV/s until baseline stabilised.

Show 2 structured reagent records

Role	Reagent	Amount / concentration	Source
Acid	H2SO4 solution	0.5 mol/L	7-8 · 3.2.1. Electrode Pretreatment
Solvent	deionized water	rinse	7-8 · 3.2.1. Electrode Pretreatment