cMOF Evidence Base
Electrochemistry Application — Electrochemical Synthesis of Cu3(HHTP)2Metal–Organic Frameworks from Cu Nanoparticles for Chemiresistive Gas Sensing

Measurement evidence

Electrochemistry Application

Electrochemical Synthesis of Cu3(HHTP)2Metal–Organic Frameworks from Cu Nanoparticles for Chemiresistive Gas Sensing · Lister A.M., Armitage B.I., Wang Y. et al. · ACS Applied Nano Materials · 2025 · 15114-15121

1 measurement group · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry (CV)

Voltammetry

Cu nanoparticle-decorated Pt/glass IDE (precursor, pre-growth) · Thin Film

Cu-NP-decorated IDE in HHTP+TBMAMS growth solution; potential ramped -0.80 to +1.20 V at 0.02 V/s in 0.00244 V steps, 40 cycles; two IDE sides connected as working electrode, Ag/AgCl reference

Atmosphere
N2-degassed solution
Geometry
3-electrode cell (Cu-NP IDE working, Pt counter, Ag/AgCl reference)
Context
pristine framework precursor (electrochemical growth mechanism study)
Measurement source
1 · SI 1. Cyclic Voltammetry · Figure S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Selected MOF-growth potential (near Cu+/Cu2+ onset)Marked as a best value within this paper+0.435 V vs RHE——Text
Exact Reported		2 · SI 1. Cyclic Voltammetry · Figure S1
CV forward oxidation peak (Cu -> Cu+)0.148 V (forward)——Text
Exact Reported		1 · SI 1. Cyclic Voltammetry · Figure S1
CV forward oxidation peak (Cu+ -> Cu2+)0.766 V (forward)——Text
Exact Reported		1 · SI 1. Cyclic Voltammetry · Figure S1
CV reverse reduction peak (Cu+ -> Cu)0.140 V (reverse, negative current)——Text
Exact Reported		1 · SI 1. Cyclic Voltammetry · Figure S1
CV reverse crossover peak (max ligand-oxidation rate)0.579 V (reverse, positive current)——Text
Exact Reported		1 · SI 1. Cyclic Voltammetry · Figure S1