Gao S., Huang Y., Tan J. et al. · ACS Applied Materials and Interfaces · 2023 · 32637-32646
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The flexible PI-based MSM photodetector retains photoresponse after 120 bending cycles, supporting wearable-optoelectronics relevance.
Caveat: Bending retention is read mainly from Figure 5d; no tabulated uncertainty or repeated-device statistics are provided.
p008 · Conclusions · Figure 5d · Linked to 2 structured results
The p-a-Cu-HHTP/n-Si self-powered photodetector is claimed to have record response time and detectivity among MOF-based photodetectors.
Caveat: Record comparison is against literature values listed by the authors in Table 1, not an independently exhaustive survey.
p006 · Results and Discussion · Table 1 · Linked to 3 structured results
p-a-Cu-HHTP is assigned as an amorphous Cu-HHTP MOF film, with broad SAED rings and no crystalline XRD peaks.
Caveat: No crystallographic model or CIF is expected for the amorphous film.
p003 · Results and Discussion · Figure 1f · Linked to 1 structured result
The authors link amorphous active defect sites and excess HHTP to richer hole density and rapid charge transport.
Caveat: Mechanistic link is inferred from spectroscopy and device behaviour rather than direct defect-density quantification.
p007 · Results and Discussion · Figure 6a,b · Linked to 3 structured results
Electrostatic spinning followed by surface-decoration layer-by-layer Cu/HHTP growth is presented as a simple route to amorphous conductive MOF films.
Caveat: The route is detailed for this Cu-HHTP system; generality to other amorphous MOFs is proposed but not demonstrated here.
p008 · Experimental Section · Figure S3 · Linked to 2 structured results
The film is inferred to be p-type, with holes as transport carriers, because O/Cu exceeds the standard stoichiometric ratio and dark p-a-Cu-HHTP/n-Si I-V behaviour is diode-like.
Caveat: The paper does not report direct Hall, Seebeck, carrier density, or mobility measurements.
p007 · Results and Discussion · Figure 6 · Linked to 2 structured results
Temperature-dependent conductivity is described by extended-state, tailed-state, and short-range hopping components, with extended-state conduction active around room temperature.
Caveat: Only fitted activation energies and normalised plots are reported; raw conductivity data are not tabulated.
p004 · Results and Discussion · Figure 3d · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| p-type amorphous Cu-HHTP film (p-a-Cu-HHTP)Browse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu-HHTP; nonstoichiometric film with O/Cu about 5/1 by XPSCu2+ coordinated by HHTP; Cu 2p XPS also deconvoluted into Cu(II) and Cu(I) components · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineAmorphous Cu-HHTP MOF film with graphite-like 2D layered local structure; broad SAED rings and no crystalline XRD peaks. | p001 · Abstract |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| p-a-Cu-HHTP MOF film on electrospun nanofibresresearch_0851__mat__mat_p_a_cu_hhtp | Thin Film · Pristine Control · Pristine Framework | Electrostatic-spun nanofibre surface decorated by layer-by-layer Cu/HHTP growth; dried under nitrogenElectrospun PAN/Cu(Ac)2-derived nanofibres on n-Si, PI, or glass depending on test | p002 · Introduction |
| p-a-Cu-HHTP/glass optical filmresearch_0851__mat__mat_p_a_cu_hhtp | Thin Film · Pristine Control · Pristine Framework | Transparent film prepared for UV-vis transmittance and Tauc analysisglass | p004 · Results and Discussion · Figure 3a,b |
| p-a-Cu-HHTP/n-Si self-powered photodetectorresearch_0851__mat__mat_p_a_cu_hhtp | Electrode · Composite Sample · Composite | p-a-Cu-HHTP/n-Si heterojunction with Ag electrodes on p-a-Cu-HHTP and n-Sin-type Si | p005 · Results and Discussion · Figure 4a |
| flexible p-a-Cu-HHTP MSM photodetector on PIresearch_0851__mat__mat_p_a_cu_hhtp | Electrode · Composite Sample · Composite | p-a-Cu-HHTP film on PI with Ag electrodes forming an MSM photodetectorpolyimide (PI) | p006 · Results and Discussion · Figure 5a |