Synthesis · Controlled synthesis of Cu-/Ni-based 1D c-MOFs and their application in near-linear temperature sensing

16 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.25 mL

Atmospherenot reported

Temperature80

Time3

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.25 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 2: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.75 mL

Atmospherenot reported

Temperature80

Time6

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.75 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 3: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.75 mL

Atmospherenot reported

Temperature80

Time12

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.75 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 4: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.75 mL

Atmospherenot reported

Temperature80

Time24

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.75 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 5: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.25 mL

Atmospherenot reported

Temperature80

Time6

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.25 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 6: Hydrothermal

main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.25 mL

Atmospherenot reported

Temperature80

Time12

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1
Linker	HHTP	35 mg, 0.110 mmol	main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1
Solvent	deionised water	7 mL	main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1
Solvent	DMF	0.25 mL	main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1

Partial recipeSource: Main

Route 7: Hydrothermal

main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.25 mL

Atmospherenot reported

Temperature80

Time24

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1
Linker	HHTP	35 mg, 0.110 mmol	main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1
Solvent	deionised water	7 mL	main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1
Solvent	DMF	0.25 mL	main p.4 · 2.2-2.3 Preparation; Table 1 · Fig. 3; Table 1

Partial recipeSource: Main

Route 8: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.50 mL

Atmospherenot reported

Temperature80

Time3

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.50 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 9: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.50 mL

Atmospherenot reported

Temperature80

Time6

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.50 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 10: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Abstract

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.50 mL

Atmospherenot reported

Temperature80

Time12

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Abstract
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Abstract
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Abstract
Solvent	DMF	0.50 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Abstract

Partial recipeSource: Main

Route 11: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.50 mL

Atmospherenot reported

Temperature80

Time24

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.50 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 12: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Metal precursorsCu(CH3COO)2.H2O (39 mg, 0.195 mmol)

Linker precursorsHHTP (35 mg, 0.110 mmol)

Solventsdeionised water 7 mL; DMF 0.75 mL

Atmospherenot reported

Temperature80

Time3

Oxidant / reductantnone reported

Work-upPowders collected after drying to constant weight; washing not reported for Cu route.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(CH3COO)2.H2O	39 mg, 0.195 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Linker	HHTP	35 mg, 0.110 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	deionised water	7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3
Solvent	DMF	0.75 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 3

Partial recipeSource: Main

Route 13: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2

Metal precursorsNi(CH3COO)2.4H2O (114 mg, 0.458 mmol)

Linker precursorsHHTP (50 mg, 0.154 mmol)

Solventsdioxane added to reach total volume of 7 mL

Atmospherenot reported

Temperature80

Time3

Oxidant / reductantnone reported

Work-upCooled to room temperature naturally; crude products washed three times by anhydrous ethanol and deionised water; dried to constant weight.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(CH3COO)2.4H2O	114 mg, 0.458 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2
Linker	HHTP	50 mg, 0.154 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2
Solvent	dioxane	total reaction volume 7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2

Partial recipeSource: Main

Route 14: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2

Metal precursorsNi(CH3COO)2.4H2O (114 mg, 0.458 mmol)

Linker precursorsHHTP (50 mg, 0.154 mmol)

Solventsdioxane added to reach total volume of 7 mL

Atmospherenot reported

Temperature80

Time6

Oxidant / reductantnone reported

Work-upCooled to room temperature naturally; crude products washed three times by anhydrous ethanol and deionised water; dried to constant weight.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(CH3COO)2.4H2O	114 mg, 0.458 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2
Linker	HHTP	50 mg, 0.154 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2
Solvent	dioxane	total reaction volume 7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2

Partial recipeSource: Main

Route 15: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2

Metal precursorsNi(CH3COO)2.4H2O (114 mg, 0.458 mmol)

Linker precursorsHHTP (50 mg, 0.154 mmol)

Solventsdioxane added to reach total volume of 7 mL

Atmospherenot reported

Temperature80

Time12

Oxidant / reductantnone reported

Work-upCooled to room temperature naturally; crude products washed three times by anhydrous ethanol and deionised water; dried to constant weight.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(CH3COO)2.4H2O	114 mg, 0.458 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2
Linker	HHTP	50 mg, 0.154 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2
Solvent	dioxane	total reaction volume 7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2

Partial recipeSource: Main

Route 16: Hydrothermal

main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2

Metal precursorsNi(CH3COO)2.4H2O (114 mg, 0.458 mmol)

Linker precursorsHHTP (50 mg, 0.154 mmol)

Solventsdioxane added to reach total volume of 7 mL

Atmospherenot reported

Temperature80

Time24

Oxidant / reductantnone reported

Work-upCooled to room temperature naturally; crude products washed three times by anhydrous ethanol and deionised water; dried to constant weight.

Activationnot reported

Scalability context10 mL glass vial batch; no scale-up demonstrated.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Ni(CH3COO)2.4H2O	114 mg, 0.458 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2
Linker	HHTP	50 mg, 0.154 mmol	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2
Solvent	dioxane	total reaction volume 7 mL	main p.3 · 2.2-2.3 Preparation; Table 1 · Table 1; Fig. 2