Two-dimensional conjugated metal-organic frameworks (2D c-MOFs): chemistry and function for MOFtronics

7review sections

7material families

12review claims

15secondary benchmarks

28cited studies

8research gaps

Review scope

Review the chemistry, synthetic methodologies, structure-electronic property relationships, charge transport properties, device integration and MOFtronics functions of two-dimensional conjugated MOFs.

Coverage: 2012–2021
Category: Review Theory Transport
Material scope: layer-stacked two-dimensional conjugated MOFs · benzene-, triphenylene-, coronene-, phthalocyanine-, naphthalocyanine- and related linker families · MO4, MN4, MS4, MN2S2 and MSe4 linkages · bulk powders, crystals, thin films, monolayers and exfoliated nanosheets
Transport scope: conductivity and mobility · through-bond, through-space and hopping transport pathways · field-effect, Hall, van der Pauw, two-probe/four-probe and TRTS measurement contexts · metallicity, semiconducting behaviour, superconductivity and spin-related transport

Application scope: field-effect transistors · chemiresistors and photodetectors · spintronics · thermoelectrics · metal-ion batteries and supercapacitors
Explicit exclusions: exhaustive primary-recipe extraction · traditional insulating MOFs except as background · primary-data leaderboard use of review-table values
Source: p. 2764 · Abstract
Evidence role: Context, taxonomy and secondary benchmarking

Section map

The review’s argument is preserved as a navigable set of section summaries.

2. Chemical methodologies of 2D c-MOFs

2765-2767

Classifies monomers, linkages and notation systems for benzene, triphenylene and larger 2D c-MOF families.

Relevance: Core · p. 2766 · 2. Chemical methodologies of 2D c-MOFs · Fig. 2

5. Device integration based on multi-dispersed 2D c-MOFs

2778-2779

Discusses bulk pellets, single-crystal devices, top-down exfoliation and bottom-up nanosheet synthesis for device integration.

Relevance: Core · p. 2779 · 5. Device integration based on multi-dispersed 2D c-MOFs · Figs. 17-18

6. Functions for MOFtronics

2779-2785

Reviews electronic, optoelectronic, spintronic, thermoelectric and electrochemical energy-storage functions enabled by conductive 2D c-MOFs.

Relevance: Supporting · p. 2779 · 6. Functions for MOFtronics

1. Introduction

2764-2765

Frames conductive MOFs and defines 2D c-MOFs as layer-stacked frameworks with in-plane extended conjugation and MOFtronics relevance.

Relevance: Core · p. 2765 · 1. Introduction · Fig. 1

7. Conclusions and outlook

2785-2788

Summarises performance advances while stressing limits in comparison metrics, layer-number control, crystallinity, device fabrication and controlled synthesis.

Relevance: Core · p. 2787 · 7. Conclusions and outlook

3. Chemical structure and electronic property relationship in 2D c-MOFs

2767-2773

Synthesises how ligand type, geometry, metal identity, redox state, stacking and crystallinity influence carrier generation, band structure and measured transport.

Relevance: Core · p. 2767 · 3. Chemical structure and electronic property relationship in 2D c-MOFs · Table 1

4. Synthetic methodologies of 2D c-MOFs

2774-2778

Compares bulk hydro-/solvothermal methods, wet interfacial film growth, Langmuir-Blodgett routes and on-surface synthesis.

Relevance: Core · p. 2774 · 4. Synthetic methodologies of 2D c-MOFs · Fig. 9

Taxonomies

Classification systems are attributed to this review and are not treated as a global material registry.

Carrier Migration Mechanism

Charge transport pathways

The review distinguishes intrinsic in-plane and interlayer pathways from extrinsic hopping through boundaries and defects.

Categories: through-bond · extended conjugation · through-space · hopping

p. 2767 · 3. Chemical structure and electronic property relationship in 2D c-MOFs

Network Topology And Monomer Symmetry

Framework lattice geometry

Ligand symmetry maps onto lattice geometry, which the review links to band-structure features such as Dirac points, flat bands and possible topological states.

Categories: hexagonal lattice · square lattice · honeycomb lattice · kagome metal-atom sublattice

p. 2769 · 3.2 Effect of ligand geometry · Figs. 4-5

Metal-Linker Coordination MotifAuthor-proposed

Chelating linkage chemistry

The review uses linkage chemistry to organise 2D c-MOF families and to interpret differences in pi-d hybridisation and transport.

Categories: metal-bis(dioxolene) MO4 · metal-bis(diimine) MN4 · metal-bis(dithiolene) MS4 · metal-diimine-dithiolene MN2S2 · metal-bis(diselenolene) MSe4

p. 2766 · 2. Chemical methodologies of 2D c-MOFs · Fig. 2

Device/Application FunctionAuthor-proposed

MOFtronics function classes

Applications are grouped around electronic transport, sensing, magnetic/spintronic phenomena and electrochemical energy storage.

Categories: field-effect transistors · superconductors · chemiresistors · photodetectors · spintronics · thermoelectrics · metal-ion batteries · supercapacitors

p. 2779 · 6. Functions for MOFtronics

Sample Form And Process RouteAuthor-proposed

Synthesis and processing formats

The review organises synthesis by whether it yields bulk particles/crystals, large-area films or processible nanosheets.

Categories: bulk hydro-/solvothermal powders and crystals · gas-liquid interfacial films · liquid-liquid interfacial films · liquid-solid interfacial films · Langmuir-Blodgett monolayers · top-down exfoliated nanosheets · bottom-up surfactant-assisted nanosheets

pp. 2774-2779 · 4-5 · Figs. 9, 11, 17

Material families

Review-defined families retain their representative materials and conduction descriptions.

Multicomponent 2D c-MOFs

Layer-Stacked Mixed-Component 2D Frameworks

2D c-MOFs incorporating mixed ligands or mixed metals within one framework to tune porosity, active sites and electronic structure.

Conduction: Mixed-metal HITP frameworks are used to demonstrate continuous conductivity changes with metal composition and interlayer displacement.

Representative materials: Cu3(HHTP)(HHB) · MnM'3-n(HITP)2

Nodes / linkers: Cu · Co · Ni · HHTP/HHB · HITP

p. 2771 · 3.3 Effect of metals · Fig. 6

MN4-linked diimine 2D c-MOFs

Layer-Stacked 2D Sheets, Powders, Films And Nanosheets

2D c-MOFs using metal-bis(diimine) or metal-bis(iminobenzosemiquinoid) coordination, commonly from hexaaminobenzene or hexaaminotriphenylene linkers.

Conduction: MN4 systems are highlighted for improved charge transport relative to MO4 analogues and for processible FET and energy-storage devices.

Representative materials: Ni3(HITP)2 · Cu3(HITP)2 · Co3(HITP)2 · M3(HIB)2 · Ni2[CuPc(NH)8]

Nodes / linkers: Ni · Cu · Co · HAB/HIB · HATP/HITP · amino-phthalocyanine

p. 2767 · 3.1 Effect of ligand type · Table 1

MO4-linked dioxolene 2D c-MOFs

Layer-Stacked 2D Frameworks, Often Porous Honeycomb Or Square Lattices

2D c-MOFs based on metal-bis(dioxolene) linkages, typically from hydroxy-substituted benzene, triphenylene, phthalocyanine or related ligands.

Conduction: The review portrays MO4-linked systems as broadly conductive but generally inferior in charge transport to analogous MN4 and MS4 systems.

Representative materials: Cu3(HHTP)2 · Ni9(HHTP)4 · Cu3(HHB)2 · M2[M'PcO8]

Nodes / linkers: Cu · Ni · Co · Fe · Zn · HHB · HHTP · phthalocyanine · naphthalocyanine · DBC

pp. 2767-2768 · 3.1 Effect of ligand type · Table 1

MS4-linked dithiolene 2D c-MOFs

Porous And Non-Porous 2D Layer-Stacked Frameworks And Films

2D c-MOFs based on metal-bis(dithiolene) linkages from thiol-substituted benzene, triphenylene or coronene ligands.

Conduction: MS4 linkages are described as having the highest pi-d hybridisation and some of the strongest reported conductivities and mobilities.

Representative materials: Cu3(HTB) · Ni3(HTB)2 · Fe3(HTTP)2 · Fe3(PTC)

Nodes / linkers: Cu · Ni · Fe · Co · Pt · BHT/HTB · THT/HTTP · PTC

p. 2767 · 3.1 Effect of ligand type · Table 1

MSe4-linked diselenolene 2D c-MOFs

Bulk 2D C-MOFs

Emerging selenium-analogue 2D c-MOFs with metal-bis(diselenolene) linkages.

Conduction: The review notes lower conductivity for reported MSe4-linked bulk examples than for MS4-linked bulk systems.

Representative materials: Cu3(HSeB) · Co3(HSeTP)2

Nodes / linkers: Cu · Co · HSeB · HSeTP

p. 2767 · 3.1 Effect of ligand type · Table 1

Exfoliated and surfactant-assisted 2D c-MOF nanosheets

Few-Layer Nanosheets

Few-layer nanosheets generated from bulk crystals or direct bottom-up nanosheet synthesis.

Conduction: Nanosheets are emphasised for solution processibility, accessible active sites and easier device integration rather than as intrinsic transport benchmarks.

Representative materials: Ni2[CuPc(NH)8] nanosheets · Cu3(HHB)2 nanosheets

Nodes / linkers: Ni · Cu · amino-phthalocyanine · HHB/THQ

p. 2779 · 5. Device integration based on multi-dispersed 2D c-MOFs · Fig. 18

Single-layer and monolayer 2D c-MOFs

Single-Layer 2D Frameworks

Atomically thin 2D c-MOF layers pursued through Langmuir-Blodgett or on-surface methods.

Conduction: The review treats monolayers as central to intrinsic transport/topological questions, while noting that large single-crystalline monolayers are missing.

Representative materials: single-layer Ni3(HTTP)2 · monolayer Ni3(HITP)2 · monolayer Ni3(HTB)2

Nodes / linkers: Ni · Cu · HTTP · HITP · HTB

p. 2787 · 7. Conclusions and outlook

Synthesis strategies

Review-level synthesis principles remain separate from primary-study recipes.

Bottom-up surfactant-assisted nanosheet synthesis

Surfactants restrict growth along the stacking direction and weaken interlayer interactions during direct nanosheet synthesis.

Claimed effects: Can produce single-crystalline, high-yield nanosheets with higher accessible surface area than bulk powders.

Controlling variables: surfactant identity · metal and ligand precursor concentrations · temperature · sonication · growth along c direction

Representative materials: Cu3(HHB)2 nanosheets

Caveat: Dispersion homogeneity, size/thickness/crystallinity control and restacking remain open process questions.

p. 2779 · 5. Device integration based on multi-dispersed 2D c-MOFs · Fig. 18

Bulk hydro-/solvothermal synthesis

Solution heating of ligands and metal salts to form bulk powders, nanocrystals or moderate-sized single crystals.

Claimed effects: Scalable and high-yield family expansion, but commonly yields small polycrystalline particles that complicate processing and transport analysis.

Controlling variables: solvent · temperature · volume and pressure · base/deprotonation conditions · atmosphere and deoxygenation

Representative materials: Cu3(HHTP)2 · Ni3(HITP)2 · Fe2[FePcO8]

Caveat: Crystal growth is hard to monitor or control; small bulk polycrystals impede nanodevice integration and neat transport interpretation.

pp. 2774-2775 · 4.1 Bulk 2D c-MOFs through hydro-/solvothermal syntheses · Fig. 9

Langmuir-Blodgett assisted monolayer synthesis

Ligands are compressed at the air/water interface and reacted with metal ions to form free-standing single-layer 2D c-MOF films.

Claimed effects: Targets large-area, free-standing single layers with high active-site exposure and processibility.

Controlling variables: surface pressure · ligand compression · metal-salt injection · transfer substrate · monolayer stability

Representative materials: single-layer Ni3(HTTP)2

Caveat: Successful examples remain limited and depend on soluble/selective building blocks and interfacial control.

p. 2777 · 4.2 2D c-MOF films through wet-interface-assisted synthesis · Fig. 14

Top-down exfoliation of bulk crystals

Mechanical ball-milling or sonication delaminates bulk 2D c-MOF crystals into few-layer nanosheets.

Claimed effects: Improves solution processibility and active-site exposure while maintaining aspects of intrinsic porosity/conductivity.

Controlling variables: bulk crystal quality · milling energy · salt assistance · solvent dispersion · restacking during solidification

Representative materials: Ni2[CuPc(NH)8] nanosheets

Caveat: Limited control over morphology, layer number and lateral domain size.

p. 2779 · 5. Device integration based on multi-dispersed 2D c-MOFs · Fig. 17

Wet-interface-assisted film synthesis

Gas-liquid, liquid-liquid and liquid-solid interfacial routes that confine polymerisation and film formation at an interface.

Claimed effects: Can yield large-area thin films with better device integration and charge transport than dispersed bulk particles.

Controlling variables: interface type · ligand and metal salt concentration · reaction time · substrate · film thickness · orientation

Representative materials: Ni3(HTB)2 · Cu3(HTB) · Ni3(HITP)2 · Fe3(HTTP)2

Caveat: Universality, crystallinity, mechanical strength and thickness control remain unresolved.

p. 2776 · 4.2 2D c-MOF films through wet-interface-assisted synthesis · Fig. 11

Review claims

These are the review authors’ synthesis, not newly measured results.

Consensus SummaryHigh supportMeasurement Interpretation

Crystallinity, grain boundaries, disorder and sample orientation strongly affect reported transport, so single-crystal or single-domain devices are needed for reliable intrinsic comparisons.

Evidence basis: multi_reference

Caveat: Review-table values span films, pellets, nanorods and nanosheets measured by different methods.

p. 2773 · 3.5 Effect of layer stacking and arrangement

DescriptiveHigh supportDefinition Scope

2D c-MOFs are layer-stacked MOFs built from ortho-substituted conjugated building blocks and square-planar linkages, combining in-plane conjugation with weaker out-of-plane van der Waals interactions.

Evidence basis: review_reasoning

Caveat: The review notes that 3D MOFs can also be built from similar planar ligands, so layer-stacked structure is part of the definition.

p. 2765 · 1. Introduction

Author InterpretationMedium supportCaveat

For batteries and supercapacitors, conductive 2D c-MOFs are promising but charge-storage mechanisms, ion/electron diffusion and binder/contact effects remain incompletely resolved.

Evidence basis: multi_reference

Caveat: Energy-storage performance examples should be treated as application context rather than direct evidence for intrinsic electronic conduction.

p. 2787 · 7. Conclusions and outlook

Author InterpretationHigh supportSynthesis Strategy

Hydro-/solvothermal methods are effective for expanding the material family but usually provide limited control over crystal growth and processability.

Evidence basis: review_reasoning

Caveat: The method can still produce important single-crystalline nanorods or nanoflakes in selected systems.

p. 2775 · 4.1 Bulk 2D c-MOFs through hydro-/solvothermal syntheses

Author InterpretationHigh supportSynthesis Strategy

Wet interfacial synthesis is presented as a route to large-area free-standing films that improve device integration and charge transport.

Evidence basis: multi_reference

Caveat: Applicable systems remain mainly benzene- or triphenylene-based, with unresolved film strength and thickness control.

p. 2788 · 7. Conclusions and outlook

Author InterpretationMedium supportStructure Property Link

Framework geometry is linked to electronic structure: honeycomb frameworks contain two distinct vertices and can host Dirac-point band features and kagome metal sublattices.

Evidence basis: multi_reference

Caveat: Several claims are theoretical or monolayer predictions rather than broad experimental demonstrations.

p. 2770 · 3.2 Effect of ligand geometry · Figs. 4-5

Author InterpretationHigh supportTransport Mechanism

Layer stacking and interlayer interactions can change band structure and contribute substantially to cross-plane conductivity.

Evidence basis: multi_reference

Caveat: Stacking sequence must be resolved carefully; assumed AA/AB models can mislead band-structure interpretation.

p. 2772 · 3.5 Effect of layer stacking and arrangement · Fig. 8

Author InterpretationMedium supportStructure Property Link

Changing functional groups from O to NH to S generally strengthens metal-linker bonding and increases pi-d hybridisation, with MS4-linked systems showing especially strong conductivity/mobility examples.

Evidence basis: multi_reference

Caveat: The authors warn that the few examples, heterogeneous morphologies and possible doping make quantitative comparison difficult.

p. 2769 · 3.1 Effect of ligand type · Table 1

Author InterpretationHigh supportStructure Property Link

Metal substitution in M3(HITP)2 changes coordination geometry, layer spacing/displacement, bandgap and conductivity, enabling continuous tuning across mixed-metal networks.

Evidence basis: single_reference

Caveat: The review treats mixed-metal studies as promising but still limited in number.

p. 2771 · 3.3 Effect of metals · Fig. 6

Author InterpretationMedium supportTransport Mechanism

Linkage redox state can inject or remove radical charge carriers, making redox activity a major design variable for conductivity.

Evidence basis: multi_reference

Caveat: Precise modulation and structural verification after redox reactions remain underdeveloped.

p. 2772 · 3.4 Effect of redox-activity in linkage · Fig. 7

Author InterpretationHigh supportCaveat

The authors caution that 2D c-MOFs should not be judged by replacing silicon; comparisons must specify the property, device type and measurement technique.

Evidence basis: review_reasoning

Caveat: This is a review-level framing claim, not a primary benchmark.

p. 2786 · 7. Conclusions and outlook

Consensus SummaryHigh supportTransport Mechanism

Intrinsic conductivity is attributed mainly to in-plane through-bond/extended conjugation and out-of-plane through-space pi-pi/metal-metal interactions, whereas hopping is associated with grain boundaries and defects.

Evidence basis: multi_reference

Caveat: The review emphasises that real samples mix intrinsic and extrinsic contributions.

p. 2767 · 3. Chemical structure and electronic property relationship in 2D c-MOFs

Secondary benchmarks

Every row remains visibly secondary and links to a primary dossier only where the mapping is verified.

Material	Property	Reported value	Context and quality	Primary evidence	Review source
SecondaryCu3(HHB)2 nanosheets	BET specific surface area	385 m2 g-1	Surfactant-assisted nanosheet synthesis with SDS; contrasted against powder sample. Text · Exact Reported	research_0043	p. 2779 · 5. Device integration based on multi-dispersed 2D c-MOFs · Fig. 18
SecondaryCu3(HTB)	field-effect mobility	116 (e), 99 (h) cm2 V-1 s-1	Film FET; electron and hole mobility reported in review Table 1. Table · Exact Reported	research_0006	p. 2779 · 6.1.1 Field-effect transistors · Fig. 19
SecondaryCu3(HTB)	electrical conductivity	2500 S cm-1	Film, 4-probe, room temperature; review Table 1. Table · Exact Reported	No verified corpus mapping	p. 2769 · 3.1 Effect of ligand type · Table 1
SecondaryCu3(HTB)	superconducting transition temperature	0.25 K	Electrical resistivity, AC magnetic susceptibility and specific heat measurements; transition disappears at 2500 Oe. Text · Exact Reported	No verified corpus mapping	p. 2780 · 6.1.2 Superconductors · Fig. 20
SecondaryFe3(HTTP)2	hole mobility	229 (Hall, h) cm2 V-1 s-1	Film, van der Pauw conductivity entry with Hall hole mobility in Table 1. Table · Exact Reported	research_0001	p. 2769 · 3.1 Effect of ligand type · Table 1
SecondaryFe3(HTTP)2	TRTS mobility	211 (TRTS) cm2 V-1 s-1	Film, time-resolved terahertz spectroscopy mobility in review Table 1. Table · Exact Reported	research_0001	p. 2769 · 3.1 Effect of ligand type · Table 1
SecondaryFe3(PTC)	electrical conductivity	10 S cm-1	Pellet, van der Pauw, room temperature; review Table 1. Table · Exact Reported	research_0045	p. 2769 · 3.1 Effect of ligand type · Table 1
SecondaryMnM'3-n(HITP)2 mixed-metal series	composition-tuned conductivity	0.024 to 55.4 S cm-1	Co/Ni mixed-metal HITP system; increasing Ni content tunes layer distance/displacement and conductivity. Text · Range	research_0041	p. 2771 · 3.3 Effect of metals · Fig. 6
SecondaryNi2[CuPc(NH)8] nanosheets	nanosheet thickness	~7 nm	NaCl-assisted low-energy ball milling; SEM/AFM/HR-TEM. Text · Approximate	No verified corpus mapping	p. 2779 · 5. Device integration based on multi-dispersed 2D c-MOFs · Fig. 18
SecondaryNi3(HIB)2	lithium-ion battery specific capacity	155 mA h g-1	Cathode material in 1 M LiPF6 electrolyte at 0.1 A g-1. Text · Exact Reported	No verified corpus mapping	p. 2783 · 6.5.1 Metal-ion batteries · Fig. 25
SecondaryNi3(HITP)2	EDL capacitor gravimetric capacitance	~110 F g-1	Pelletized Ni3(HITP)2, 1D channels, 0.05 A g-1 discharge rate. Text · Approximate	No verified corpus mapping	p. 2784 · 6.5.2 Supercapacitors · Fig. 26
SecondaryNi3(HITP)2	field-effect hole mobility	48.6 cm2 V-1 s-1	Film FET, p-type behaviour, as-synthesised sample. Text · Exact Reported	research_0015	p. 2780 · 6.1.1 Field-effect transistors · Fig. 19
SecondaryNi3(HITP)2	electrical conductivity	up to ~60 S cm-1	Polycrystalline 2D c-MOF, temperature-dependent semiconducting behaviour. Text · Approximate	No verified corpus mapping	p. 2773 · 3.5 Effect of layer stacking and arrangement
SecondaryNi3(HITP)2	cross-plane electrical conductivity	up to 150 S cm-1	Single-crystalline nanorod sample, cross-plane direction. Text · Approximate	research_0005	p. 2773 · 3.5 Effect of layer stacking and arrangement
SecondaryNi9(HHTP)4 on laser-scribed graphene	micro-supercapacitor areal capacitance	15.2 mF cm-2	Hybrid interdigitated on 3D porous laser-scribed graphene. Text · Exact Reported	No verified corpus mapping	p. 2785 · 6.5.2 Supercapacitors · Fig. 27

Research gaps

Open questions are presented as review-author priorities, not conclusions from the primary database.

device integration

High

Compression and drop-casting of bulk materials limit reproducible, high-performance MOFtronic devices.

Proposed direction: Improve film quality, mechanical strength, smoothness, contacts and integration methods.

p. 2787 · 7. Conclusions and outlook

transport interpretation

High

Boundaries, defects, edges and small domains obscure whether measured conductivity/mobility is intrinsic.

Proposed direction: Use reliable single-crystal or single-domain devices and control morphology/orientation before asserting structure-property relationships.

p. 2787 · 7. Conclusions and outlook

crystal growth

High

Hydro-/solvothermal synthesis barely controls crystal growth and often gives bulk samples that are hard to process.

Proposed direction: Design ligands/solvents and coordination reversibility to enlarge crystals, reduce defects and control morphology.

p. 2788 · 7. Conclusions and outlook

thin-film synthesis

Medium

Interfacial synthetic methods are limited to a narrow set of systems and still face strength, orientation and size-control challenges.

Proposed direction: Broaden interfacial chemistry and tune thickness, lateral size, orientation and mechanical strength.

p. 2788 · 7. Conclusions and outlook

chemical diversity

Medium

Current ligand design and linkage chemistry remain limited despite growth of the 2D c-MOF library.

Proposed direction: Expand rational ligand, linkage and multicomponent framework design while preserving conductivity and structural order.

p. 2787 · 7. Conclusions and outlook

single-layer materials

High

Large single-crystalline monolayers needed for topological and heterostructure studies are still missing.

Proposed direction: Develop controlled chemical synthesis for large monolayers and van der Waals heterostructures.

p. 2787 · 7. Conclusions and outlook

charge-state modulation

High

Precise redox-state modulation and post-redox structural verification are underexplored, especially for negatively charged frameworks.

Proposed direction: Combine controlled redox chemistry with compositional and crystallographic checks to establish structure-conductivity relationships.

p. 2787 · 7. Conclusions and outlook

material-family coverage

Medium

Functional studies remain concentrated on triphenylene-based systems, leaving other 2D c-MOF families underdeveloped.

Proposed direction: Extend MOFtronics testing across benzene, coronene, phthalocyanine and other linker families.

p. 2787 · 7. Conclusions and outlook

Cited-study map

Mappings show which printed review references have a verified counterpart in the frozen primary corpus.

Show 28 cited-study records

Reference	Study	Role and context	Corpus mapping
Ref. 582020	Title unavailable	mixed_metal · structure_property_relationship · conductivity_benchmarkCited for mixed-metal HITP frameworks, layer displacement and conductivity/bandgap tuning.	research_0041
Ref. 1132015	Title unavailable	band_structure · metal_substitution · stackingCited for DFT band-structure and stacking/metal-substitution interpretations of HITP frameworks.	Unmapped
Ref. 952019	Title unavailable	single_crystal · conductivity_benchmark · stackingCited for single-crystalline nanorods/nanoflakes, stacking analysis and cross-plane transport discussion.	research_0005
Ref. 452015	Title unavailable	langmuir_blodgett · monolayer · electrocatalysis_contextCited for large-area free-standing single-layer 2D c-MOF synthesis and water-splitting context.	Unmapped
Ref. 322018	Title unavailable	coronene_family · spintronics · conductivity_benchmarkCited for coronene-based MS4-linked Fe3(PTC), conductivity and ferromagnetic semiconductor discussion.	research_0045
Ref. 782018	Title unavailable	mobility_benchmark · photodetector · thin_film_synthesisCited for Fe3(HTTP)2 band-like transport, high mobility, interfacial film synthesis and photodetector application.	research_0001
Ref. 402017	Title unavailable	benzene_family · conductivity_benchmarkCited for MN4-linked M3(HIB)2 bulk samples and intrinsic metallicity in highly crystalline samples.	Unmapped
Ref. 2412020	10.1038/s41563-020-00847-710.1038/s41563-020-00847-7	outlook · single_crystal_needCited in the outlook for the urgent need for single-crystals or single-domain monolayers.	Unmapped
Ref. 382018	Title unavailable	pseudocapacitance · energy_storageCited for pseudocapacitor behaviour in MN4-linked benzene-based 2D c-MOFs.	Unmapped
Ref. 192012	Title unavailable	first_2d_c_mof · synthesis_strategyCited as the first 2D c-MOF report and as the representative hydro-/solvothermal synthesis of TP-based MO4-linked materials.	Unmapped
Ref. 312015	Title unavailable	fet_benchmark · wet_interface_synthesis · high_conductivityCited for Cu3(HTB) liquid-liquid interfacial film synthesis and ambipolar FET mobility.	research_0006
Ref. 412018	Title unavailable	ligand_family · dithioleneCited for benzenehexathiol/BHT ligand development and MS4-linked material family.	research_0735
Ref. 682018	Title unavailable	high_conductivity · superconductivityCited for very high Cu3(HTB) film conductivity and superconductivity measurements.	Unmapped
Ref. 742013	Title unavailable	liquid_liquid_interface · film_synthesisCited as an early liquid-liquid interfacial 2D c-MOF film synthesis.	Unmapped
Ref. 752014	Title unavailable	redox_activity · conductivity_benchmarkCited for redox modulation and conductivity changes in Ni3(HTB)2.	research_0361
Ref. 392018	Title unavailable	redox_activity · benzene_familyCited for negatively charged Cu3(HHB)2 and redox-state discussion.	research_0792
Ref. 572014	Title unavailable	ni_hitp_synthesis · conductivity_benchmarkCited for hydrothermal synthesis of Ni3(HITP)2 and polycrystalline conductivity behaviour.	Unmapped
Ref. 372017	Title unavailable	supercapacitor_benchmark · energy_storageCited for EDL capacitor behaviour of pelletized Ni3(HITP)2.	Unmapped
Ref. 862020	Title unavailable	topology · lattice_geometryCited for topology, lattice diagrams and geometry-band-structure discussion.	Unmapped
Ref. 362018	Title unavailable	battery_benchmark · energy_storageCited for Ni3(HIB)2 as a Li-ion battery cathode and ligand-based redox interpretation.	Unmapped
Ref. 1122013	Title unavailable	topological_state · theoryCited for predicted topological edge states in a Ni3(HTB)2 monolayer.	Unmapped
Ref. 552020	Title unavailable	nanosheets · micro_supercapacitor · device_integrationCited for ball-milling exfoliation into nanosheets and flexible MSC device integration.	Unmapped
Ref. 882020	Title unavailable	nanosheets · battery_benchmark · bottom_up_synthesisCited for surfactant-assisted single-crystalline Cu3(HHB)2 nanosheets and Li-ion battery performance.	research_0043
Ref. 292017	Title unavailable	fet_benchmark · thin_film_synthesisCited for Ni3(HITP)2 thin films and FET mobility/on-off performance.	research_0015
Ref. 1002019	Title unavailable	micro_supercapacitor · device_integrationCited for laser-scribed graphene-supported Ni9(HHTP)4 micro-supercapacitors.	Unmapped
Ref. 252020	Title unavailable	transport_mechanism · review_contextCited for transport mechanisms and charge-transport characterisation context in conductive MOFs.	Unmapped
Ref. 332019	Title unavailable	synthesis_strategy · phthalocyanine_family · magnetismCited for vacuum-promoted synthesis of oxygen-sensitive phthalocyanine 2D c-MOFs and ferromagnetic Fe2[FePcO8].	research_0267
Ref. 1262017	Title unavailable	superconductivity_theoryCited for calculated superconducting transition temperatures for monolayer and bulk Cu3(HTB).	Unmapped