Microscopy Morphology — Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages

3 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CuPc-O-Cu black powder · Powder

SEM at 10 kV and HR-TEM after acetone suspension/drop-cast onto lacey carbon copper mesh; FFT used for lattice orientation.

Context: pristine
Measurement source: SI p.25-30 · Section S4 SEM and HR-TEM · Figures 2d,f; S12,S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
morphology description	tens-of-nanometres cubic-type crystallites; HR-TEM [001] lattice	—	—	Text Qualitative	main p.4-5 · Results and Discussion · Figures 2d,f; S12,S14
reported crystallite/domain size	tens of nanometers; SI image caption says 50 nm size of crystallite	—	—	Caption Approximate	SI p.28-30 · Section S4 SEM and HR-TEM · Figures 2d,f; S12,S14
HR-TEM/FFT in-plane periodicity	1.76 +/- 0.05 nm	—	+/- 0.05 nm	Text Rounded Reported	main p.4-5 · Results and Discussion · Figure 2

CuPc-O-Ni black powder · Powder

SEM at 10 kV and HR-TEM after acetone suspension/drop-cast onto lacey carbon copper mesh; FFT used for lattice orientation.

Context: pristine
Measurement source: SI p.25-30 · Section S4 SEM and HR-TEM · Figures 2c,e; S11,S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
morphology description	tens-of-nanometres flake-type crystallites; HR-TEM [001] lattice	—	—	Text Qualitative	main p.4-5 · Results and Discussion · Figures 2c,e; S11,S13
HR-TEM/FFT in-plane periodicity	1.76 +/- 0.05 nm	—	+/- 0.05 nm	Text Rounded Reported	main p.4-5 · Results and Discussion · Figure 2

CuPc-O-Zn black powder · Powder

SEM at 10 kV and HR-TEM after acetone suspension/drop-cast onto lacey carbon copper mesh; FFT used for lattice orientation.

Context: pristine
Measurement source: SI p.25-30 · Section S4 SEM and HR-TEM · Figures 2g-k; S15,S16

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
morphology description	few-hundreds-nanometres slightly angled rectangular crystallites; extended pore channels along [100]	—	—	Text Qualitative	main p.4-5 · Results and Discussion · Figures 2g-k; S15,S16
reported crystallite/domain size	over 500 nm / SI caption: 500 nm size of crystallite	—	—	Text Approximate	main p.5 · Results and Discussion · Figures 2g-k; S15,S16
inclined FFT/interlayer angle	84 deg relative to direction of extended pore channel	—	—	Text Exact Reported	main p.5 · Results and Discussion · Figure 2j
HR-TEM/FFT in-plane periodicity	1.75 nm	—	—	Text Exact Reported	main p.4-5 · Results and Discussion · Figure 2