Other — Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages

6 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CuPc-O-Cu black powder · Powder

2 mg MOF in 0.1 mM dye aqueous solution (2 mL), stirred at room temperature for 12 h; filtrate UV-vis-NIR monitored.

Context: pristine
Measurement source: SI p.34 · Section S6 Dye adsorption experiments · Figure S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
methylene blue adsorption	complete adsorption of MB+ after 12 h	—	—	Text Qualitative	main p.5 · Results and Discussion · Figure S20
methyl orange adsorption	MO- remained in solution after 12 h	—	—	Text Qualitative	main p.5 · Results and Discussion · Figure S20

CuPc-O-Ni black powder · Powder

2 mg MOF in 0.1 mM dye aqueous solution (2 mL), stirred at room temperature for 12 h; filtrate UV-vis-NIR monitored.

Context: pristine
Measurement source: SI p.34 · Section S6 Dye adsorption experiments · Figure S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
methylene blue adsorption	complete adsorption of MB+ after 12 h	—	—	Text Qualitative	main p.5 · Results and Discussion · Figure S20
methyl orange adsorption	MO- remained in solution after 12 h	—	—	Text Qualitative	main p.5 · Results and Discussion · Figure S20

CuPc-O-Zn black powder · Powder

2 mg MOF in 0.1 mM dye aqueous solution (2 mL), stirred at room temperature for 12 h; filtrate UV-vis-NIR monitored.

Context: pristine
Measurement source: SI p.34 · Section S6 Dye adsorption experiments · Figure S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
methylene blue adsorption	complete adsorption of MB+ after 12 h	—	—	Text Qualitative	main p.5 · Results and Discussion · Figure S20
methyl orange adsorption	MO- remained in solution after 12 h	—	—	Text Qualitative	main p.5 · Results and Discussion · Figure S20

CuPc-O-Cu black powder · Powder

TGA from 30 to 800 deg C with 10 deg C min-1 ramp under N2 atmosphere.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal weight-loss pattern	two gradual weight losses before 150 deg C and after about 400 deg C	—	—	Text Qualitative	main p.6 · Results and Discussion · Figure S23

CuPc-O-Ni black powder · Powder

TGA from 30 to 800 deg C with 10 deg C min-1 ramp under N2 atmosphere.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal weight-loss pattern	two gradual weight losses before 150 deg C and after about 400 deg C	—	—	Text Qualitative	main p.6 · Results and Discussion · Figure S23

CuPc-O-Zn black powder · Powder

TGA from 30 to 800 deg C with 10 deg C min-1 ramp under N2 atmosphere.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
greater low-temperature weight loss	higher weight loss before 150 deg C than Ni and Cu analogues	—	—	Text Qualitative	main p.6 · Results and Discussion · Figure S23
thermal weight-loss pattern	two gradual weight losses before 150 deg C and after about 400 deg C	—	—	Text Qualitative	main p.6 · Results and Discussion · Figure S23