Other — Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field

6 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Vector network analyser EMW absorption and complex permittivity/permeability

60 wt.% Cu3(HHTP)2 in paraffin coaxial ring · Pellet

Keysight N5222B; 60 wt.% MOF/paraffin coaxial rings; 2-18 GHz electromagnetic parameters; reflection loss calculated by transmission-line theory under metallic backing.

Geometry: coaxial ring, phi_in 3.04 mm and phi_out 7.00 mm; variable absorber thickness
Context: 60 wt.% MOF/paraffin composite ring with pristine c-MOF component
Measurement source: 9 · Electromagnetic Measurement · Figures 3d, 5a-b; S20-S28

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
fitted conduction-loss epsilon double-prime component	1.175	—	—	Figure Axis Rounded Reported	6 · Section 2.3 · Figure 4f
maximum effective absorption bandwidthMarked as a best value within this paper	4.88 GHz	—	—	Text Rounded Reported	7 · Section 2.3 · Figure 5a-b
real permittivity epsilon prime range	8.54 to 4.39	—	—	Text Range	5-6 · Section 2.3 · Figure 3d
fitted polarization-loss epsilon double-prime component	0.672	—	—	Figure Axis Rounded Reported	6 · Section 2.3 · Figure 4f
minimum reflection loss RLmin	-60.07 dB	—	—	Text Rounded Reported	7 · Section 2.3 · Figure 5a-b

Vector network analyser EMW absorption and complex permittivity/permeability

60 wt.% Cu3(HITP)2 in paraffin coaxial ring · Pellet

Keysight N5222B; 60 wt.% MOF/paraffin coaxial rings; 2-18 GHz electromagnetic parameters; reflection loss calculated by transmission-line theory under metallic backing.

Geometry: coaxial ring, phi_in 3.04 mm and phi_out 7.00 mm; variable absorber thickness
Context: 60 wt.% MOF/paraffin composite ring with pristine c-MOF component
Measurement source: 9 · Electromagnetic Measurement · Figures 3d, 5a-b; S20-S28

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
fitted conduction-loss epsilon double-prime componentMarked as a best value within this paper	1.205	—	—	Figure Axis Rounded Reported	6 · Section 2.3 · Figure 4f
maximum effective absorption bandwidth	3.44 GHz	—	—	Text Rounded Reported	7 · Section 2.3 · Figure 5a-b
real permittivity epsilon prime rangeMarked as a best value within this paper	17.50 to 7.67	—	—	Text Range	5-6 · Section 2.3 · Figure 3d
effective absorption frequency coverage by thickness tuningMarked as a best value within this paper	3-18 GHz	—	—	Text Range	7 · Section 2.3 · Figure 5a-i
fitted polarization-loss epsilon double-prime componentMarked as a best value within this paper	0.705	—	—	Figure Axis Rounded Reported	6 · Section 2.3 · Figure 4f
minimum reflection loss RLminMarked as a best value within this paper	-63.03 dB at 3.2 mm	—	—	Text Rounded Reported	7 · Section 2.3 · Figure 5a-b

Vector network analyser EMW absorption and complex permittivity/permeability

60 wt.% Cu3(THT)2 in paraffin coaxial ring · Pellet

Keysight N5222B; 60 wt.% MOF/paraffin coaxial rings; 2-18 GHz electromagnetic parameters; reflection loss calculated by transmission-line theory under metallic backing.

Geometry: coaxial ring, phi_in 3.04 mm and phi_out 7.00 mm; variable absorber thickness
Context: 60 wt.% MOF/paraffin composite ring with pristine c-MOF component
Measurement source: 9 · Electromagnetic Measurement · Figures 3d, 5a-b; S20-S28

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
fitted conduction-loss epsilon double-prime component	0.593	—	—	Figure Axis Rounded Reported	6 · Section 2.3 · Figure 4f
maximum effective absorption bandwidth	2.24 GHz	—	—	Text Rounded Reported	7 · Section 2.3 · Figure 5a-b
real permittivity epsilon prime range	8.77 to 7.73	—	—	Text Range	5-6 · Section 2.3 · Figure 3d
fitted polarization-loss epsilon double-prime component	0.401	—	—	Figure Axis Rounded Reported	6 · Section 2.3 · Figure 4f
minimum reflection loss RLmin	-56.16 dB	—	—	Text Rounded Reported	7 · Section 2.3 · Figure 5a-b

Thermogravimetric analysis (TGA)

Thermogravimetric analysis

As-synthesised Cu3(HHTP)2 powder · Powder

30 to 900 °C, heating rate 10 °C min-1 under nitrogen atmosphere.

Atmosphere: nitrogen
Geometry: powder TGA
Context: pristine framework powder
Measurement source: SI · Section 8 · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability below temperature	stable below 200 °C	—	—	Text Approximate	SI · Section 8 · Figure S13
TGA annotated weight-loss delta	Delta = 62.6 wt.%	—	—	Figure Axis Rounded Reported	17 · Section 8 · Figure S13

Thermogravimetric analysis (TGA)

Thermogravimetric analysis

As-synthesised Cu3(HITP)2 powder · Powder

30 to 900 °C, heating rate 10 °C min-1 under nitrogen atmosphere.

Atmosphere: nitrogen
Geometry: powder TGA
Context: pristine framework powder
Measurement source: SI · Section 8 · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability below temperature	stable below 200 °C	—	—	Text Approximate	SI · Section 8 · Figure S13
TGA annotated weight-loss delta	Delta = 72.8 wt.%	—	—	Figure Axis Rounded Reported	17 · Section 8 · Figure S13

Thermogravimetric analysis (TGA)

Thermogravimetric analysis

As-synthesised Cu3(THT)2 powder · Powder

30 to 900 °C, heating rate 10 °C min-1 under nitrogen atmosphere.

Atmosphere: nitrogen
Geometry: powder TGA
Context: pristine framework powder
Measurement source: SI · Section 8 · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability below temperature	stable below 200 °C	—	—	Text Approximate	SI · Section 8 · Figure S13
TGA annotated weight-loss delta	Delta = 58.4 wt.%	—	—	Figure Axis Rounded Reported	17 · Section 8 · Figure S13