cMOF Evidence Base

Synthesis evidence

Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal-Organic Framework Under Electromagnetic Field

Cheng S., Zhou Q., Sheng D. et al. · Advanced Science · 2025 · e08379

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Other

9 · Experimental Section

Metal precursorsCu(OAc)2.H2O (320 mg, 1.6 mmol) in 100 mL DI water
Linker precursorsHHTP (260 mg, 0.8 mmol) dispersed in 125 mL DI water
SolventsDI water; methanol for washing
Additivesnone reported
Atmosphereair environment
Temperature85
Time15
Oxidant / reductantAir used to fully oxidise ligand and avoid reduction of metal ions
Work-upCool to room temperature; filter blue-black precipitate; wash three times alternately with H2O and methanol.
ActivationDry in vacuum oven at 60 °C for 12 h.
Scalability contextBatch solution synthesis; no yield or scale-up discussion reported.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
LinkerHHTP260 mg, 0.8 mmol · dispersed in 125 mL DI-Water9 · Experimental Section
Metal SourceCu(OAc)2.H2O320 mg, 1.6 mmol · dissolved in 100 mL DI-Water9 · Experimental Section
SolventDI-Water225 mL total before workup9 · Experimental Section
Solventmethanolwash solvent9 · Experimental Section
Complete recipeSource: Main

Route 2: Other

9 · Experimental Section

Metal precursorsCuSO4.5H2O (162 mg, 0.672 mmol) in 72 mL DMA
Linker precursorsHITP.6HCl (240 mg, 0.446 mmol) dispersed in 72 mL DI water
SolventsDI water; DMA; H2O and methanol for washing
Additives32 mL NaOAc aqueous solution (2 mol/L)
Atmospherenot specified after reagent mixing
Temperature65
Time32
Oxidant / reductantLigand oxidation/deprotonation implied; no separate oxidant reported.
Work-upCool to room temperature; filter brown-black precipitate; wash three times alternately with H2O and methanol.
ActivationDry in vacuum oven at 60 °C for 12 h.
Scalability contextBatch solution synthesis; no yield or scale-up discussion reported.
Show 6 structured reagent records
RoleReagentAmount / concentrationSource
LinkerHITP.6HCl240 mg, 0.446 mmol · dispersed in 72 mL DI-water9 · Experimental Section
Metal SourceCuSO4.5H2O162 mg, 0.672 mmol · dissolved in 72 mL DMA9 · Experimental Section
BaseNaOAc aqueous solution32 mL · 2 mol/L9 · Experimental Section
SolventDI-water72 mL plus wash solvent9 · Experimental Section
SolventDMA72 mL9 · Experimental Section
Solventmethanolwash solvent9 · Experimental Section
Complete recipeSource: Main

Route 3: Other

9 · Experimental Section

Metal precursorsCopper(II) trifluoroacetylacetonate (355 mg, 0.96 mmol) in 15 mL degassed DI water
Linker precursorsTHT (200 mg, 0.48 mmol) dispersed in 15 mL degassed DI water adjusted to pH 10
SolventsDegassed DI water; H2O and acetone for washing
Additives300 uL of 28% ammonium hydroxide to adjust pH to 10
AtmosphereN2; degassed solutions and reaction stirred under N2
Temperature65
Time24
Oxidant / reductantNo separate oxidant/reductant reported; N2 used.
Work-upCool to room temperature; filter black precipitate; wash three times alternately with H2O and acetone.
ActivationDry in vacuum oven at 60 °C for 12 h.
Scalability contextBatch solution synthesis; no yield or scale-up discussion reported.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
LinkerTHT200 mg, 0.48 mmol · dispersed in 15 mL DI-water, adjusted to pH 109 · Experimental Section
Metal SourceCopper(II) trifluoroacetylacetonate355 mg, 0.96 mmol · dissolved in 15 mL DI-water9 · Experimental Section
Baseammonium hydroxide300 uL · 28%9 · Experimental Section
SolventDI-water, degassed with N230 mL plus wash solvent9 · Experimental Section
Solventacetonewash solvent9 · Experimental Section