Electrical Transport — Tunable Carrier Type of a Semiconducting 2D Metal-Organic Framework Cu3(HHTP)2

Measurement evidence

Electrical Transport

Tunable Carrier Type of a Semiconducting 2D Metal-Organic Framework Cu3(HHTP)2 · De Lourdes Gonzalez-Juarez M., Morales C., Flege J.I. et al. · ACS Applied Materials and Interfaces · 2022 · 12404-12411

4 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Four-point probe electrical conductivity; temperature-dependent conductivity

CuHHTP-40 PMMA-transferred Cu3(HHTP)2 film · Thin Film

Room-temperature four-point probe conductivity and temperature-dependent resistivity/conductivity trend.

Temperature
room temperature for reported conductivity; Figure 4 spans ca. 300-327 K by axis
Atmosphere
ambient conditions
Geometry
Transferred thin film contacted by four-point probe.
Context
PMMA-transferred CuHHTP-40 composite film.
Measurement source
main p.5, article p.12408 · Charge Transport Properties · Figure 4; Table S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Electrical conductivity of CuHHTP-40Marked as a best value within this paper2.28 x 10-3 +/- 0.0007 S cm-1+/- 0.0007 S cm-1SI Table
Exact Reported
SI p.S8 · Table S2 · Table S2
Conductivity ratio CuHHTP-40 versus CuHHTP-705-fold differenceText
Rounded Reported
main p.5, article p.12408 · Charge Transport Properties · Figure 4
Semiconducting temperature dependenceResistivity decreased upon increasing temperatureText
Qualitative
main p.5, article p.12408 · Charge Transport Properties · Figure 4

Four-point probe electrical conductivity; temperature-dependent conductivity

CuHHTP-70 PMMA-transferred Cu3(HHTP)2 film · Thin Film

Room-temperature four-point probe conductivity and temperature-dependent resistivity/conductivity trend.

Temperature
room temperature for reported conductivity; Figure 4 spans ca. 300-325 K by axis
Atmosphere
ambient conditions
Geometry
Transferred thin film contacted by four-point probe.
Context
PMMA-transferred CuHHTP-70 composite film.
Measurement source
main p.5, article p.12408 · Charge Transport Properties · Figure 4; Table S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Electrical conductivity of CuHHTP-704.86 x 10-4 +/- 0.0012 S cm-1+/- 0.0012 S cm-1SI Table
Exact Reported
SI p.S8 · Table S2 · Table S2

Hall effect measurement using commercial ECOPIA Hall effect measurement system

CuHHTP-40 PMMA-transferred Cu3(HHTP)2 film · Thin Film

Hall effect measurements at room temperature on CuHHTP-40 and CuHHTP-70 transferred films.

Temperature
room temperature
Atmosphere
ambient conditions
Geometry
Transferred thin films.
Context
PMMA-transferred composite films.
Measurement source
main p.5, article p.12408 · Charge Transport Properties · Table S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Carrier concentration of CuHHTP-40Marked as a best value within this paper-6.41 x 10^16 cm-3Text
Exact Reported
main p.5, article p.12408 · Charge Transport Properties · Table S2
Carrier concentration of CuHHTP-70+2.47 x 10^14 cm-3Text
Exact Reported
main p.5, article p.12408 · Charge Transport Properties · Table S2
Charge mobility of CuHHTP-40Marked as a best value within this paper0.364 cm2 V-1 s-1Text
Exact Reported
main p.6, article p.12409 · Charge Transport Properties
Charge mobility of CuHHTP-700.298 cm2 V-1 s-1Text
Exact Reported
main p.6, article p.12409 · Charge Transport Properties

Current-voltage (I-V) electrical contact assessment

CuHHTP-40 PMMA-transferred Cu3(HHTP)2 film · Thin Film

Four probe contacts A, B, C and D on transferred Cu3(HHTP)2 thin films.

Geometry
Four electrical probes placed on transferred film.
Context
PMMA-transferred films.
Measurement source
SI p.S4 · Figure S3 caption · Figure S3a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Electrical contact behaviourLinear I-V behaviour indicates good Ohmic contactText
Qualitative
main p.5, article p.12408 · Charge Transport Properties · Figure S3