Thermoelectric — Tunable Carrier Type of a Semiconducting 2D Metal-Organic Framework Cu3(HHTP)2

3 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CuHHTP-PAA-40 PAA-transferred Cu3(HHTP)2 film · Thin Film

Comparative charge transport data for PAA-transferred films dried at 40 C and 70 C.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Carrier concentration of CuHHTP-PAA-40	-9.54 x 10^15 cm-3	—	—	SI Table Exact Reported	SI p.S8 · Table S2 · Table S2
Carrier concentration of CuHHTP-PAA-70	+2.079 x 10^15 cm-3	—	—	SI Table Exact Reported	SI p.S8 · Table S2 · Table S2
Electrical conductivity of CuHHTP-PAA-40Marked as a best value within this paper	5.59 x 10-3 +/- 0.00003 S/cm	—	+/- 0.00003 S/cm	SI Table Exact Reported	SI p.S8 · Table S2 · Table S2
Electrical conductivity of CuHHTP-PAA-70	2.9 x 10-3 +/- 0.0045 S/cm	—	+/- 0.0045 S/cm	SI Table Exact Reported	SI p.S8 · Table S2 · Table S2
Carrier type switch also observed with PAA transfer	PAA films show similar switching behaviour, not restricted to PMMA transfer agent	—	—	Text Qualitative	main p.6, article p.12409 · Charge Transport Properties · Figure S6; Table S2
Seebeck coefficient of CuHHTP-PAA-40	-182.06 +/- 19.88 uV/K	—	+/- 19.88 uV/K	SI Table Exact Reported	SI p.S8 · Table S2 · Table S2
Seebeck coefficient of CuHHTP-PAA-70	+187.72 +/- 12.73 uV/K	—	+/- 12.73 uV/K	SI Table Exact Reported	SI p.S8 · Table S2 · Table S2

CuHHTP-40 PMMA-transferred Cu3(HHTP)2 film · Thin Film

Average from five independent films at drying temperature 40 C.

Temperature: room temperature measurement; Delta T varied in Figure 4a
Atmosphere: ambient conditions
Geometry: Transferred thin film; thermovoltage versus Delta T.
Context: PMMA-transferred CuHHTP-40 composite film.
Measurement source: main p.5, article p.12408 · Charge Transport Properties · Figure 4a; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Carrier type of CuHHTP-40 from Seebeck signMarked as a best value within this paper	n-type; electrons are majority charge carriers	—	—	Text Qualitative	main p.5, article p.12408 · Charge Transport Properties · Figure 4a
Seebeck coefficient of CuHHTP-40Marked as a best value within this paper	-117.0 +/- 13.4 uV K-1	—	+/- 13.4 uV K-1	Text Exact Reported	main p.5, article p.12408 · Charge Transport Properties · Figure 4a

CuHHTP-70 PMMA-transferred Cu3(HHTP)2 film · Thin Film

Average from five independent films at drying temperature 70 C.

Temperature: room temperature measurement; Delta T varied in Figure 4b
Atmosphere: ambient conditions
Geometry: Transferred thin film; thermovoltage versus Delta T.
Context: PMMA-transferred CuHHTP-70 composite film.
Measurement source: main p.5, article p.12408 · Charge Transport Properties · Figure 4b; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Carrier type of CuHHTP-70 from Seebeck signMarked as a best value within this paper	p-type semiconductor	—	—	Text Qualitative	main p.5, article p.12408 · Charge Transport Properties · Figure 4b
Seebeck coefficient of CuHHTP-70Marked as a best value within this paper	+269.5 +/- 21.6 uV K-1	—	+/- 21.6 uV K-1	Text Exact Reported	main p.5, article p.12408 · Charge Transport Properties · Figure 4b