Electrochemistry Application — A Novel Electrically Conductive Perylene Diimide-Based MOF-74 Series Featuring Luminescence and Redox Activity

3 measurement groups · 15 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry

Voltammetry

PDI-MOF-74(Mg) CV mesh electrode · Electrode

Three-electrode setup; Pt-wire counter electrode; silver wire pseudo-reference; dry DMF; 0.1 M TBAPF6; scan rate 0.1 V/s; argon; ferrocene added after CV for reference

Atmosphere: argon
Geometry: MOF pressed into stainless steel mesh
Context: composite
Measurement source: 5-6, SI 4 and 33 · Results and Discussion · Figure 6; Figure S26; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CV cycling stability	stable during several cycles	—	—	Text Qualitative	6 · Results and Discussion · Figure S26
first reduction onset potential	-0.2 V vs Ag/Ag+	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2
second reduction onset potential	-0.5 V vs Ag/Ag+	—	—	Text Rounded Reported	6 · Results and Discussion · Figure 6; Figure S26
HOMO / valence-band edge against vacuum	-6.1 eV	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2
LUMO / conduction-band edge against vacuum	-4.0 eV	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2

cyclic voltammetry

Voltammetry

PDI-MOF-74(Ni) CV mesh electrode · Electrode

Three-electrode setup; Pt-wire counter electrode; silver wire pseudo-reference; dry DMF; 0.1 M TBAPF6; scan rate 0.1 V/s; argon; ferrocene added after CV for reference

Atmosphere: argon
Geometry: MOF pressed into stainless steel mesh
Context: composite
Measurement source: 5-6, SI 4 and 33 · Results and Discussion · Figure 6; Figure S26; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CV cycling stability	stable during several cycles	—	—	Text Qualitative	6 · Results and Discussion · Figure S26
first reduction onset potential	-0.2 V vs Ag/Ag+	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2
second reduction onset potential	-0.5 V vs Ag/Ag+	—	—	Text Rounded Reported	6 · Results and Discussion · Figure 6; Figure S26
HOMO / valence-band edge against vacuum	-6.1 eV	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2
LUMO / conduction-band edge against vacuum	-4.0 eV	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2

cyclic voltammetry

Voltammetry

PDI-MOF-74(Zn) CV mesh electrode · Electrode

Three-electrode setup; Pt-wire counter electrode; silver wire pseudo-reference; dry DMF; 0.1 M TBAPF6; scan rate 0.1 V/s; argon; ferrocene added after CV for reference

Atmosphere: argon
Geometry: MOF pressed into stainless steel mesh
Context: composite
Measurement source: 5-6, SI 4 and 33 · Results and Discussion · Figure 6; Figure S26; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CV cycling stability	stable during several cycles	—	—	Text Qualitative	6 · Results and Discussion · Figure S26
first reduction onset potential	-0.2 V vs Ag/Ag+	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2
second reduction onset potential	-0.5 V vs Ag/Ag+	—	—	Text Rounded Reported	6 · Results and Discussion · Figure 6; Figure S26
HOMO / valence-band edge against vacuum	-6.1 eV	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2
LUMO / conduction-band edge against vacuum	-4.0 eV	—	—	SI Table Exact Reported	33 · Cyclic voltammetry · Table S2