Porosity — A Novel Electrically Conductive Perylene Diimide-Based MOF-74 Series Featuring Luminescence and Redox Activity

3 measurement groups · 17 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

PDI-MOF-74(Mg) powder · Powder

N2 adsorption/desorption at 77.3 K after high-vacuum activation at 120 C for at least 12 h

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface areaMarked as a best value within this paper	1222 m2 g-1	—	—	Text Exact Reported	4 · Results and Discussion · Figure S17
initial low-pressure nitrogen uptake	about 210 cm3 g-1	—	—	Text Approximate	4 · Results and Discussion · Figure S17A-C
maximum nitrogen uptake	about 540 cm3 g-1 at 0.98 p/p0	—	—	Text Approximate	4 · Results and Discussion · Figure S17A-C
QSDFT pore size	1.9 nm	—	—	Text Rounded Reported	4 · Results and Discussion · Figure S17D-F
second nitrogen uptake	about 70 cm3 g-1 at 0.01-0.05 p/p0	—	—	Text Approximate	4 · Results and Discussion · Figure S17A-C
nitrogen isotherm type	IUPAC Type IV(a)	—	—	Text Qualitative	4 · Results and Discussion · Figure S17A-C

PDI-MOF-74(Ni) powder · Powder

N2 adsorption/desorption at 77.3 K after high-vacuum activation at 120 C for at least 12 h

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	897 m2 g-1	—	—	Text Exact Reported	4 · Results and Discussion · Figure S17
initial low-pressure nitrogen uptake	about 130 cm3 g-1	—	—	Text Approximate	4 · Results and Discussion · Figure S17A-C
QSDFT pore size	2.5 nm	—	—	Text Rounded Reported	4 · Results and Discussion · Figure S17D-F
second nitrogen uptake	about 50 cm3 g-1 at 0.01-0.05 p/p0	—	—	Text Approximate	4 · Results and Discussion · Figure S17A-C
nitrogen isotherm type	IUPAC Type IV(a)	—	—	Text Qualitative	4 · Results and Discussion · Figure S17A-C

PDI-MOF-74(Zn) powder · Powder

N2 adsorption/desorption at 77.3 K after high-vacuum activation at 120 C for at least 12 h

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	730 m2 g-1	—	—	Text Exact Reported	4 · Results and Discussion · Figure S17
initial low-pressure nitrogen uptake	about 175 cm3 g-1	—	—	Text Approximate	4 · Results and Discussion · Figure S17A-C
maximum nitrogen uptake	about 515 cm3 g-1 at 0.98 p/p0	—	—	Text Approximate	4 · Results and Discussion · Figure S17A-C
QSDFT pore size	1.9 nm	—	—	Text Rounded Reported	4 · Results and Discussion · Figure S17D-F
second nitrogen uptake	about 20 cm3 g-1 at 0.01-0.05 p/p0	—	—	Text Approximate	4 · Results and Discussion · Figure S17A-C
nitrogen isotherm type	IUPAC Type IV(a)	—	—	Text Qualitative	4 · Results and Discussion · Figure S17A-C