Jeremias F., Henninger S.K., Janiak C. · Chemical Communications · 2012 · 9708-9710
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The porous, mechanically stable, thermally coupled HKUST-1 coatings are positioned for heat exchangers in sorption heat pumps, catalysis and gas storage.
Caveat: No device-level heat-pump or catalysis performance test is reported in this paper.
9710 · Summary · Linked to 4 structured results
Water-vapour cycling destroys the HKUST-1 crystal structure while leaving mechanical adhesion unchanged.
Caveat: Cycling conditions are severe and described specifically in the SI.
9710 · Results · Figure S7 · Linked to 3 structured results
The thicker top layer of the coating consists of HKUST-1 and the coating PXRD confirms HKUST-1 as the major crystalline phase.
Caveat: The complete coating also includes a carbon-rich bottom interlayer with non-HKUST-1 phases.
9709 · Results · Figure 3 · Linked to 1 structured result
High thermal conductivity is attributed to highly intergrown crystallites that facilitate heat transfer compared with loose particle or bead packings.
Caveat: Thermal analysis averages top and bottom coating layers and relies on assumed density and Basolite-derived heat capacity.
9710 · Results · Figure 5 · Linked to 3 structured results
The bottom layer is likely a mostly organic, polymeric carbon-rich material formed under copper-catalysed conditions, with Cu2O/rouaite also present.
Caveat: Authors explicitly state the organic phase is apparently amorphous and only anticipate a mostly organic/polymeric structure.
9709 · Results · Figure 4; Figure S4 · Linked to 6 structured results
The substrate itself plays a minor role as a metal source under the applied conditions because HKUST-1 layer formation was observed on copper, aluminium and stainless steel sheets.
Caveat: Detailed recipes and measurements for aluminium and stainless-steel coatings are not provided.
9709 · Results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Commercial copper trimesate Basolite C-300Browse family: HKUST-1 / Cu₃(BTC)₂ | commercial copper trimesate / HKUST-1-type materialCu centres · trimesate | 3D · Model SystemCommercial copper trimesate used only for heat-capacity regression supporting coating thermal-conductivity calculations. | 5 · Heat capacity measurements · Figure S6 |
| Carbon-rich bottom interlayer | unknown carbon-rich Cu/O/N-containing interlayer; crystalline Cu2(NO3)(OH)3 and Cu2O detectedCu species present; PXRD assigns rouaite Cu2(NO3)(OH)3 and Cu2O · not assigned; mostly organic/polymeric structure anticipated | unknown · UnknownNo PXRD reflections assigned to an organic phase; IR resembles HKUST-1 top layer with additional fingerprint bands. | 9709 · Results · Figure 3; Figure 4 |
| HKUST-1 / copper trimesateBrowse family: HKUST-1 / Cu₃(BTC)₂ | Cu3(btc)2Cu centres from copper nitrate precursor; HKUST-1 copper paddlewheel framework implied by copper trimesate assignment · benzene-1,3,5-tricarboxylate / trimesate (btc) from trimesic acid H3btc | 3D · PristineMajor crystalline phase assigned as HKUST-1 by PXRD against HKUST-1 simulation; top layer separated from copper surface is treated as crystalline HKUST-1. | 9708 · Abstract/Introduction |
| HKUST-1 coating on copper sheetBrowse family: HKUST-1 / Cu₃(BTC)₂ | HKUST-1 top layer plus carbon-rich bottom layer on Cu supportCu centres in HKUST-1 coating; Cu substrate; bottom layer contains Cu species including Cu2O/rouaite by PXRD · trimesate in HKUST-1 top layer; bottom layer contains carbon-rich amorphous/polymeric organic material | 3D · CompositeTwo-layer coating: thicker HKUST-1 top layer and thin carbon-rich bottom layer; whole coating was modelled as layer 2 in laser-flash analysis. | 9709 · Results · Figure 4e,f |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Commercial Basolite C-300 copper trimesateresearch_0271__mat__mat_basolite_c300 | Powder · Model System · Model | dehydrated under vacuum at 120 deg C before calorimetry; preliminary temperature run performed | 5 · Heat capacity measurements · Figure S6 |
| Separated thin bottom layerresearch_0271__mat__mat_bottom_layer | Thin Film · Composite Component · Unknown | separated bottom layer examined by PXRD, FTIR and XPS after sputteringformed between HKUST-1 top layer and copper sheet · thin bottom layer; numeric thickness not reported | 9709 · Results · Figure 3; Figure 4; Figure S4 |
| HKUST-1 coating on 5 cm x 5 cm copper sheetresearch_0271__mat__mat_hkust1_cu_coating | Thin Film · Target Sample · Composite | sanded and tempered copper sheet; thermal-gradient coated; rinsed/immersed in DMF, washed with ethanol, dried at 120 deg C overnight and stored inertETP copper sheet / Cu support, typically 50 mm x 50 mm x 0.60 mm · 100 um coating thickness; produced within 120 min; coating includes top and bottom layers | 9709 · Results |
| Separated crystalline HKUST-1 top layerresearch_0271__mat__mat_hkust1 | Powder · Target Sample · Pristine Framework | crystalline top layer separated from copper surface after coating purification/activationseparated from Cu surface before porosity/IR evaluation · top layer is the thicker layer of the coating; exact separated-layer thickness not reported | 9709 · Results · Figure S5; Figure 4 |
| HKUST-1 coating after 500 water-vapour ad/desorption cyclesresearch_0271__mat__mat_hkust1_cu_coating | Thin Film · Target Sample · Unknown | cycled 500 times between 15 and 120 deg C in 12 mbar water vapour; colour changed green; PXRD showed almost complete loss of HKUST-1 structurecopper sheet · derived from original coated sheet; thickness after cycling not reported | 6 · Water vapour cycling · Figure S7 |