Thermoelectric

Calorimetry heat-capacity regression

Commercial Basolite C-300 copper trimesate · Powder

Setaram C-80 calorimeter; Basolite C-300 dehydrated under vacuum at 120 deg C; preliminary temperature run; temperature steps 25 K/h; polynomial fit used for coating thermal-conductivity measurements.

Temperature: approximately 303-403 K from plotted axis
Atmosphere: vacuum dehydration before measurement
Geometry: commercial powder sample
Context: model system used for coating heat-capacity input
Measurement source: 5 · Heat capacity measurements · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cp polynomial adjusted R-square	0.99966	—	—	Visual Estimate Rounded Reported	5 · Heat capacity measurements · Figure S6
Cp polynomial B1	-0.00345	—	standard error 1.56844E-4	Visual Estimate Rounded Reported	5 · Heat capacity measurements · Figure S6
Cp polynomial B2	6.53692E-5	—	standard error 4.40066E-6	Visual Estimate Rounded Reported	5 · Heat capacity measurements · Figure S6
Cp polynomial B3	-4.95737E-7	—	standard error 5.86112E-8	Visual Estimate Rounded Reported	5 · Heat capacity measurements · Figure S6
Cp polynomial B4	2.95031E-9	—	standard error 3.72709E-10	Visual Estimate Rounded Reported	5 · Heat capacity measurements · Figure S6
Cp polynomial B5	-9.27675E-12	—	standard error 9.1024E-13	Visual Estimate Rounded Reported	5 · Heat capacity measurements · Figure S6
Cp polynomial intercept	1.01366	—	standard error 0.00211	Visual Estimate Rounded Reported	5 · Heat capacity measurements · Figure S6

Laser flash thermal analysis using Cowan 2-layer model

Thermal transport measurements

HKUST-1 coating on 5 cm x 5 cm copper sheet · Thin Film

Netzsch Microflash LFA 457 under vacuum on 10 mm x 10 mm samples; graphite coated both sides and dehumidified at 120 deg C; three shots per temperature, arithmetic means; Cu substrate properties from Netzsch database and coating heat capacity from Figure S6 regression.

Temperature: 303-393 K for activated coating in main text; contact-resistance text states 298-423 K, inconsistent with plotted axis
Atmosphere: vacuum
Geometry: 2-layer Cowan model: layer 1 Cu substrate, layer 2 coating averaging bottom and top layers
Context: MOF coating plus bottom interlayer on Cu substrate
Measurement source: 5 · Thermal conductivity measurements · Figure 5; Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
coating/Cu contact resistance lower boundMarked as a best value within this paper	2.6 x 10^-5 to 2.8 x 10^-5 m2 K W^-1	—	range lower bound	Text Range	9710 · Results · Figure 5
coating/Cu contact resistance upper boundMarked as a best value within this paper	2.6 x 10^-5 to 2.8 x 10^-5 m2 K W^-1	—	range upper bound	Text Range	9710 · Results · Figure 5
assumed coating density for laser-flash model	1.22 g cm^-3	—	assumed	Text Approximate	9710 · Results
thermal diffusivity lower visual estimate	approximately 1.05 to 1.15 mm2 s^-1	—	visual range lower bound	Figure Axis Approximate	9710 · Results · Figure 5
thermal diffusivity upper visual estimate	approximately 1.05 to 1.15 mm2 s^-1	—	visual range upper bound	Figure Axis Approximate	9710 · Results · Figure 5
thermal conductivity lower boundMarked as a best value within this paper	1.2 to 1.4 W m^-1 K^-1	—	range lower bound	Text Range	9710 · Results · Figure 5
thermal conductivity upper boundMarked as a best value within this paper	1.2 to 1.4 W m^-1 K^-1	—	range upper bound	Text Range	9710 · Results · Figure 5

2 measurement groups · 14 results