Yan Y., Li Z.-Y., Qu K.-G. et al. · Inorganic Chemistry · 2024 · 22502-22511
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The NIR photoelectrical responses of compounds 1 and 2 imply potential use in NIR photodetector applications.
Caveat: Demonstrated on pressed pellets under ambient conditions; no optimised device architecture or external quantum efficiency is reported.
22508 · 3.5 Near-Infrared Photoelectrical Response · Figure 7 · Linked to 4 structured results
NIR photodetectors based on coordination polymers are described as relatively rare.
Caveat: This is a literature-context claim, not directly established by new measurements in this paper.
22508 · 3.5 Near-Infrared Photoelectrical Response · Linked to 2 structured results
X-aggregation in compound 2 gives more effective pi-pi interactions and higher NIR photothermal conversion efficiency than H-aggregation in compound 1.
Caveat: Comparison is between two different metal/coordination environments as well as different ligand aggregation modes.
22506, 22509 · 3.3; 4 Conclusions · Figures 4-5 · Linked to 4 structured results
The conductive performance is ascribed to synergistic band-like charge transport within crystals and hopping charge transport across grain boundaries.
Caveat: Band-like pathway is computationally inferred; hopping contribution is inferred from pressed-pellet measurement geometry rather than isolated directly.
22508-22509 · 3.4; 4 Conclusions · Figures 6, S14-S17 · Linked to 3 structured results
Both pristine coordination polymers are semiconductive pressed pellets with conductivities of 2.1e-7 and 3.0e-7 S/cm at 30 C in nitrogen.
Caveat: Pressed-pellet two-contact measurements may be lower than intrinsic single-crystal values because of grain-boundary resistance and anisotropy.
22507 · 3.4 Semiconductive Properties · Figure 6 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| compound 1 | {[Cd2(ONDI)(ox)].2/3(H2O)}nCd2+ centres; each cadmium cation is 8-fold coordinated · ONDI2- ligand from H2ONDI plus oxalate auxiliary ligand | 3D · PristineThree-dimensional dense coordination polymer with slip-stacked ONDI2- ligands, unidirectional supramolecular columns, and H-type aggregation. | 22503-22504 · Introduction; 3.1 Crystal Structure · Figure 1 |
| compound 2 | [Ba(ONDI)(H2O)2]nBa2+ centres; each barium ion is 10-fold coordinated · ONDI2- ligand from H2ONDI with coordinated water molecules | 3D · PristineThree-dimensional dense coordination polymer with ONDI2- ligands tightly packed along the c axis, unidirectional pi-pi stacking columns, and X-type aggregation. | 22503-22504 · Introduction; 3.1 Crystal Structure · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| compound 1 pure bulk product from CdCl2 variantresearch_0498__mat__mat_1_cd_ondi_ox | Powder · Target Sample · Pristine Framework | Bulk product obtained by replacing Cd(NO3)2.4H2O with CdCl2.2.5H2O; purity verified by PXRD. | 22503 · 2.1.1 Synthesis of Compound 1 · Figure S21a |
| compound 1 brown plate crystalsresearch_0498__mat__mat_1_cd_ondi_ox | Single Crystal · Target Sample · Pristine Framework | Solvothermal brown plate crystals from the compound 1 synthesis. | 22503 · 2.1.1 Synthesis of Compound 1 |
| compound 1 computational modelresearch_0498__mat__mat_1_cd_ondi_ox | Model · Model System · Model | Pi-dimer and periodic crystal models built directly from crystal structure data. | 22503-22504 · 2.6 Computational Details · Figures 3 and 6 |
| compound 1 thin square pellet for NIR photoelectrical responseresearch_0498__mat__mat_1_cd_ondi_ox | Pellet · Target Sample · Pristine Framework | Crystalline powder pressed into a thin square pellet; photocurrent and dark current measured under ambient conditions.5 x 5 x approximately 0.29 mm | 22503 · 2.5 NIR Photoelectrical Response · Figure 7 |
| compound 1 pressed pellet for NIR photothermal testingresearch_0498__mat__mat_1_cd_ondi_ox | Pellet · Target Sample · Pristine Framework | Crystalline powder pressed into a circular pellet with a tablet pressing machine.5 mm diameter; about 20.6 mg | 22503 · 2.3 Near-Infrared Photothermal Conversion Measurement · Figure 4 |
| compound 1 square pellet for electrical conductivityresearch_0498__mat__mat_1_cd_ondi_ox | Pellet · Target Sample · Pristine Framework | Crystalline powder pressed into a square pellet and measured by two-contact method under nitrogen.5 x 5 x 0.30 mm | 22503 · 2.4 Electrical Conductivity Measurements · Figure 6 |
| compound 2 pure microcrystalline productresearch_0498__mat__mat_2_ba_ondi | Powder · Target Sample · Pristine Framework | Microcrystalline brown product purified by repeated DMF suspension and brief ultrasonication. | 22503 · 2.1.3 Synthesis of Microcrystalline 2 |
| compound 2 computational modelresearch_0498__mat__mat_2_ba_ondi | Model · Model System · Model | Pi-dimer and periodic crystal models built directly from crystal structure data. | 22503-22504 · 2.6 Computational Details · Figures 3 and 6 |
| compound 2 thin square pellet for NIR photoelectrical responseresearch_0498__mat__mat_2_ba_ondi | Pellet · Target Sample · Pristine Framework | Crystalline powder pressed into a thin square pellet; photocurrent and dark current measured under ambient conditions.5 x 5 x approximately 0.26 mm | 22503 · 2.5 NIR Photoelectrical Response · Figure 7 |
| compound 2 pressed pellet for NIR photothermal testingresearch_0498__mat__mat_2_ba_ondi | Pellet · Target Sample · Pristine Framework | Crystalline powder pressed into a circular pellet with a tablet pressing machine.5 mm diameter; about 20.3 mg | 22503 · 2.3 Near-Infrared Photothermal Conversion Measurement · Figure 5 |
| compound 2 brown single crystalsresearch_0498__mat__mat_2_ba_ondi | Single Crystal · Target Sample · Pristine Framework | Solvothermal product contained brown crystals of 2 and byproduct crystals. | 22503 · 2.1.2 Synthesis of Single Crystals of Compound 2 |
| compound 2 square pellet for electrical conductivityresearch_0498__mat__mat_2_ba_ondi | Pellet · Target Sample · Pristine Framework | Crystalline powder pressed into a square pellet and measured by two-contact method under nitrogen.5 x 5 x 0.35 mm | 22503 · 2.4 Electrical Conductivity Measurements · Figure 6 |