Other — Enhancing Near-Infrared Photothermal Performance by Molecular Aggregation Optimization in Semiconductive Coordination Polymers

3 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

NIR photothermal conversion under 808 nm laser; HIKMICRO K20 IR camera

compound 1 pressed pellet for NIR photothermal testing · Pellet

Laser spot diameter about 7 mm; pellet diameter 5 mm; varied power density from 0.125 to 1.25 W/cm2.

Temperature: ambient start, about 302 K
Atmosphere: ambient
Geometry: pressed circular pellet
Context: pristine framework
Measurement source: 22503-22506 · 2.3; 3.3 Near-Infrared Photothermal Effects · Figures 4, S9, S10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
absorbance at 808 nm used for PCE calculation	0.41 F(R)	—	—	Caption Exact Reported	S7 · Figure section · Figure S10
maximum temperature change used for PCE calculationMarked as a best value within this paper	53.1 K	—	—	Caption Exact Reported	S7 · Figure section · Figure S10
NIR photothermal conversion efficiency	38.8%	—	—	SI Table Exact Reported	S3 · Table section · Table S2
steady photothermal temperature at 0.125 W/cm2	36.0 C	—	—	Visual Estimate Approximate	22505 · 3.3 Near-Infrared Photothermal Effects · Figure 4a
steady photothermal temperature at 0.25 W/cm2	41.6 C	—	—	Visual Estimate Approximate	22505 · 3.3 Near-Infrared Photothermal Effects · Figure 4a
steady photothermal temperature at 0.375 W/cm2	45.4 C	—	—	Visual Estimate Approximate	22505 · 3.3 Near-Infrared Photothermal Effects · Figure 4a
steady photothermal temperature at 0.5 W/cm2	49.6 C	—	—	Visual Estimate Approximate	22505 · 3.3 Near-Infrared Photothermal Effects · Figure 4a
steady photothermal temperature at 0.625 W/cm2	54.6 C	—	—	Visual Estimate Approximate	22505 · 3.3 Near-Infrared Photothermal Effects · Figure 4a
steady photothermal temperature at 0.75 W/cm2	61.7 C	—	—	Visual Estimate Approximate	22505 · 3.3 Near-Infrared Photothermal Effects · Figure 4a
steady photothermal temperature at 1.0 W/cm2	71.4 C	—	—	Visual Estimate Approximate	22505 · 3.3 Near-Infrared Photothermal Effects · Figure 4a
steady photothermal temperature at 1.25 W/cm2Marked as a best value within this paper	83.1 C	—	—	Text Rounded Reported	22506 · 3.3 Near-Infrared Photothermal Effects · Figure 4a,b

NIR photothermal conversion under 808 nm laser; HIKMICRO K20 IR camera

compound 2 pressed pellet for NIR photothermal testing · Pellet

Laser spot diameter about 7 mm; pellet diameter 5 mm; varied power density from 0.125 to 0.75 W/cm2.

Temperature: ambient start, about 302 K
Atmosphere: ambient
Geometry: pressed circular pellet
Context: pristine framework
Measurement source: 22503-22506 · 2.3; 3.3 Near-Infrared Photothermal Effects · Figures 5, S9, S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
absorbance at 808 nm used for PCE calculationMarked as a best value within this paper	2.62 F(R)	—	—	Caption Exact Reported	S8 · Figure section · Figure S11
maximum temperature change used for PCE calculation	50.3 K	—	—	Caption Exact Reported	S8 · Figure section · Figure S11
NIR photothermal conversion efficiencyMarked as a best value within this paper	68.6%	—	—	SI Table Exact Reported	S3 · Table section · Table S2
steady photothermal temperature at 0.125 W/cm2	38.5 C	—	—	Text Rounded Reported	22506 · 3.3 Near-Infrared Photothermal Effects · Figure 5a,b
steady photothermal temperature at 0.25 W/cm2	45.4 C	—	—	Visual Estimate Approximate	22506 · 3.3 Near-Infrared Photothermal Effects · Figure 5a
steady photothermal temperature at 0.375 W/cm2	52.1 C	—	—	Visual Estimate Approximate	22506 · 3.3 Near-Infrared Photothermal Effects · Figure 5a
steady photothermal temperature at 0.5 W/cm2	59.2 C	—	—	Visual Estimate Approximate	22506 · 3.3 Near-Infrared Photothermal Effects · Figure 5a
steady photothermal temperature at 0.625 W/cm2	69.0 C	—	—	Visual Estimate Approximate	22506 · 3.3 Near-Infrared Photothermal Effects · Figure 5a
steady photothermal temperature at 0.75 W/cm2Marked as a best value within this paper	76.5 C	—	—	Text Rounded Reported	22506 · 3.3 Near-Infrared Photothermal Effects · Figure 5a,b

Thermogravimetric analysis under nitrogen

Thermogravimetric analysis

compound 1 pure bulk product from CdCl2 variant · Powder

Al2O3 crucibles, N2 flow 20 mL/min, heating rate 10 K/min over 30-900 C.

Temperature: 303-1173
Atmosphere: N2
Geometry: powder in Al2O3 crucible
Context: pristine frameworks
Measurement source: 22503 · 2.1 Materials and Measurements · Figure S22

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
compound 1 TG weight loss before 300 C	approximately 1.1%	—	—	Caption Approximate	S12 · Figure section · Figure S22
compound 2 TG weight loss below 250 C	observed 7.62%; calculated 7.67%	—	—	Caption Exact Reported	S12 · Figure section · Figure S22