cMOF Evidence Base
Electrical Transport — Conductive Metal-Organic Framework Thin Film Hybrids by Electropolymerization of Monosubstituted Acetylenes

Measurement evidence

Electrical Transport

Conductive Metal-Organic Framework Thin Film Hybrids by Electropolymerization of Monosubstituted Acetylenes · Klyatskaya S., Kanj A.B., Molina-Jiron C. et al. · ACS Applied Materials and Interfaces · 2020 · 30972-30979

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Current-voltage measurement

Electrical conductivity

BPA@Cu(BDC)-SURMOF-2 after electropolymerisation · Electrode

Keithley 2635B SourceMeter; pure nitrogen; sample equilibrated at least 2 h in nitrogen before measurement; room temperature.

Temperature
298
Atmosphere
pure nitrogen; argon storage for 3-month stability check
Geometry
Metrohm interdigitated gold electrodes, 10 um gap width, 1.69 m total gap length, approximately 100 nm SURMOF layer
Context
BPA@Cu(BDC)-SURMOF-2 after infiltration with 1-hexyne and EP
Measurement source
main p.5 · Results and Discussion · Figure 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BPA@Cu(BDC)-SURMOF-2 conductivityMarked as a best value within this paper0.098 S m-10.098 S m-1—Text
Exact Reported		main p.5 · Results and Discussion · Figure 4
Conductivity increase after in-pore EP8 orders of magnitude——Text
Rounded Reported		main p.5 · Results and Discussion · Figure 4
I-V stability after argon storageI-V curve after 3 months virtually identical——Caption
Qualitative		main p.5 · Figure 4 caption · Figure 4
Approximate target current at +/-1 V in I-V plotabout 1 x 10-3 A at +/-1 V—visual estimate from log-axis plotFigure Axis
Approximate		main p.5 · Results and Discussion · Figure 4

Current-voltage measurement

Electrical conductivity

Pristine Cu(BDC) SURMOF-2 thin-film device · Electrode

Keithley 2635B SourceMeter; pure nitrogen; sample equilibrated at least 2 h in nitrogen before measurement; room temperature.

Temperature
298
Atmosphere
pure nitrogen
Geometry
Metrohm interdigitated gold electrodes, 10 um gap width, 1.69 m total gap length
Context
empty Cu(BDC) SURMOF-2 thin-film device before infiltration and EP
Measurement source
SI p.S-2 · Electrical Conductivity · Figure 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Pristine Cu(BDC) SURMOF-2 conductivityabout 6 x 10-10 S m-16e-10 S m-1—Text
Approximate		main p.5 · Results and Discussion · Figure 4
Approximate pristine current at +/-1 V in I-V plotabout 1 x 10-11 A at +/-1 V—visual estimate from log-axis plotFigure Axis
Approximate		main p.5 · Results and Discussion · Figure 4