Electrochemistry Application — Conductive Metal-Organic Framework Thin Film Hybrids by Electropolymerization of Monosubstituted Acetylenes

Measurement evidence

Electrochemistry Application

Conductive Metal-Organic Framework Thin Film Hybrids by Electropolymerization of Monosubstituted Acetylenes · Klyatskaya S., Kanj A.B., Molina-Jiron C. et al. · ACS Applied Materials and Interfaces · 2020 · 30972-30979

1 measurement group · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

1-hexyne-loaded Cu(BDC) SURMOF-2 · Thin Film

Dry dichloromethane with 0.1 M TBAHFP/TBAF supporting electrolyte, argon atmosphere in main text; 20 mM 1-hexyne present or absent; working electrode Cu(BDC)/(Au@Si), counter Pt-wire, reference Ag/Ag+.

Atmosphere: argon
Geometry: 40 nm Cu(BDC)/(Au@Si) working electrode, S = 3 cm2 in SI caption
Context: 1-hexyne-loaded SURMOF compared with blank/no 1-hexyne control
Measurement source: main p.3 · Results and Discussion · Figure S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Substantial current density for 1-hexyne-loaded samples	10 mA cm-2	—	—	Text Rounded Reported	main p.4 · Results and Discussion · Figure S3
No redox process from Cu paddlewheel	No evidence of Cu-node redox processes observed	—	—	Text Qualitative	main p.4 · Results and Discussion · Figure S3
Oxidation peak assigned to 1-hexyne	+0.5 V vs Ag/Ag+ (irreversible)	—	—	Figure Axis Rounded Reported	SI p.S-5 · Figure S3 caption and embedded table · Figure S3
Irreversible cathodic reduction peak	-1.25 V vs Ag/Ag+	—	—	Text Exact Reported	main p.4 · Results and Discussion · Figure S3
Irreversible cathodic reduction peak	-1.60 V vs Ag/Ag+	—	—	Text Exact Reported	main p.4 · Results and Discussion · Figure S3