Other — Emergence of Metallic Conductivity in Ordered One-Dimensional Coordination Polymer Thin Films upon Reductive Doping

Measurement evidence

Other

Emergence of Metallic Conductivity in Ordered One-Dimensional Coordination Polymer Thin Films upon Reductive Doping · Nisula M., Karttunen A.J., Solano E. et al. · ACS Applied Materials and Interfaces · 2021 · 10249-10256

1 measurement group · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

In situ spectroscopic ellipsometry during ALD/MLD growth

As-deposited Cu-DMD thin film on Si(100) with native oxide · Thin Film

Thickness fitted using a general oscillator model in CompleteEase; J.A. Woollam M-2000, 245-1500 nm

Temperature: 353
Atmosphere: ALD/MLD reactor with Ar carrier gas
Context: As-deposited pristine Cu-DMD film
Measurement source: p002 / article p.10250 · Experimental Section · Figure 1b; Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu(dmap)2 pulse saturation threshold	Saturative behaviour with Cu(dmap)2 pulse lengths above 20 s	—	threshold stated as above 20 s	Text Approximate	p003 / article p.10251 · Results and Discussion · Figure S1
DMD pulse saturation threshold	Saturative behaviour with DMD pulse lengths above 35 s	—	threshold stated as above 35 s	Text Approximate	p003 / article p.10251 · Results and Discussion · Figure S1
Approximate growth per cycle plateau	Approximately 0.46-0.48 A/cycle from Figure S1 axes for both precursors	—	visual estimate +/-0.02 A/cycle	Figure Axis Approximate	p002 / SI p.1 · Supporting Information · Figure S1
Linear thickness increase with ALD/MLD cycles	Well-controlled linear thickness increase after initial enhanced-growth regime	—	—	Text Qualitative	p003 / article p.10251 · Results and Discussion · Figure 1b