Measurement evidence
Does the Mode of Metal-Organic Framework/Electrode Adhesion Determine Rates for Redox-Hopping-Based Charge Transport within Thin-Film Metal-Organic Frameworks? · Duan J., Goswami S., Patwardhan S. et al. · Journal of Physical Chemistry C · 2022 · 4601-4611
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
EPD-MOF-525 · Thin Film
0.1 M TBAPF6 in DCM; 100 mV/s scan rate from 0 to 2 V; current density normalised to immersed electrode area
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| approximate current density at 2.0 V | ~0.04 uA/cm2 | — | — | Figure Axis Approximate | 5 · Figure read · Figure 4 |
| redox wave assignment | TCPP+/0 wave; anodic/cathodic waves widely separated and poorly defined | — | — | Text Qualitative | 4 · Film Characterization · Figure 4 |
EPD-MOF-525 · Thin Film
0.5 M TBAPF6 in DCM
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| approximate EPD oxidation feature current density | ~0.09 uA/cm2 near 1.8-2.0 V | — | — | Figure Axis Approximate | 2 · Figure read · Figure S2 |
FTO blank CV control · Electrode
FTO blank CV in 0.5 M TBAPF6 in DCM
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| FTO blank current | near zero across plotted window | — | — | Figure Axis Approximate | 2 · Figure read · Figure S2b |
ST-MOF-525 · Thin Film
0.1 M TBAPF6 in DCM; 100 mV/s scan rate from 0 to 2 V; current density normalised to immersed electrode area
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| approximate current density at 2.0 V | ~0.078 uA/cm2 | — | — | Figure Axis Approximate | 5 · Figure read · Figure 4 |
| redox wave assignment | TCPP+/0 wave; anodic/cathodic waves widely separated and poorly defined | — | — | Text Qualitative | 4 · Film Characterization · Figure 4 |
ST-MOF-525 · Thin Film
0.5 M TBAPF6 in DCM
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| approximate oxidation peak current density | ~0.58 uA/cm2 near 1.55 V | — | — | Figure Axis Approximate | 2 · Figure read · Figure S2 |
free TCPP linker in DCM/DMF · Unknown
Free linker in DCM with small amount of DMF; redox-wave assignment
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| TCPP2+/+ formal potential | near 1.5 V vs Ag/AgCl | — | — | Text Approximate | 4 · Film Characterization · Figure S2 |