Spectroscopy — Growth mechanisms and anisotropic softness-dependent conductivity of orientation-controllable metal-organic framework nanofilms

Measurement evidence

Spectroscopy

Growth mechanisms and anisotropic softness-dependent conductivity of orientation-controllable metal-organic framework nanofilms · Yao M.-S., Otake K.-I., Koganezawa T. et al. · Proceedings of the National Academy of Sciences of the United States of America · 2023 · e2305125120

1 measurement group · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

TEM plus Cu K-edge XAFS/EXAFS

Cu0.1 P2.0-20C · Thin Film

Lattice spacings and orientation-dependent fluorescence XAFS for films of similar thickness.

Context
pristine Cu-HHTP unless noted
Measurement source
SI p008 · Fig. S5 text · Fig. S5-S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
edge-on (002) spacing~0.31-0.33 nmText
Range
SI p008 · Fig. S5 text · Fig. S5
TEM visible channel spacing~1.8 nm for (100)/(010)Text
Approximate
SI p008 · Fig. S5 text · Fig. S5
edge-on EXAFS stronger k rangestronger signals at k = 3-7 A-1Text
Range
SI p008 · Fig. S5 text · Fig. S5-S8
dominant Cu(II) XANES featuredominant Cu(II) peak above 8985 eVText
Approximate
SI p008 · Fig. S5 text · Fig. S6