Li Y., Wang R., Wang G.-E. et al. · ACS Nano · 2022 · 473-484
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The MOF-MSMC-5h sensor can monitor pulse, temporomandibular pressure changes, and spatial pressure-temperature distributions in a 3 x 3 array.
Caveat: Application demonstrations are qualitative; no long-term implanted device performance reported.
481 · Dual-Modal Applications · Figure 2; Figure 5 · Linked to 4 structured results
The PDMS-sealed MOF-MSMC implant was classified as no inflammatory reaction in the rat histology scoring used here.
Caveat: Small animal-number table; tested sample average has minor fatty infiltration/neovascularization/fibrosis scores.
478 · Pressure-Sensing Properties · Figure S11; Table S4 · Linked to 3 structured results
Changing the substrate from MSMC to PP produces a flatter Ni3(HiTP)2 film and markedly lower pressure sensitivity.
Caveat: PP control has different PDMS curing constraints.
477 · Pressure-Sensing Properties · Figure S5; Figure S6 · Linked to 3 structured results
Continuous conductive Ni3(HiTP)2 MOF film was successfully grown on MSMC by liquid-solid interfacial growth.
Caveat: Conductivity is cited from prior reports; XRD peak values are not tabulated in the SI text layer.
476 · Results and Discussion · Figure 1; Figure S1 · Linked to 3 structured results
The rough, fibre-like Ni3(HiTP)2-MSMC morphology and high Ra of the 5 h film produce the best pressure-sensing performance.
Caveat: Correlation across three growth times and PP control; not a mechanistic isolation of every variable.
477 · Pressure-Sensing Properties · Table S1; Table S2; Figure S2 · Linked to 4 structured results
The MOF-MSMC composite suppresses stretch interruptions because its Young modulus is larger than PDMS and tensile strain hardly changes resistance or thermocurrent.
Caveat: The strain-interference results are mostly qualitative from SI plots.
481 · Conclusion · Figure S8; Figure S13 · Linked to 4 structured results
Pressure sensing and temperature sensing are mutually noninterfering because pressure changes carrier migration paths while temperature sensing reflects carrier energy differences.
Caveat: Supported by device experiments plus COMSOL/DFT calculations; raw simulation files were not provided.
480 · Analysis of the Mutual Noninterference Mechanism · Figure 3; Figure 4 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Ni3(HiTP)2-on-microstructured mixed cellulose composite filmBrowse family: Ni₃(HITP)₂ / Ni–HITP | Ni3(HiTP)2/MSMCNi(II) · HiTP-derived linker | 2D · CompositeNi3(HiTP)2 conformal film wrapped around MSMC fibres; liquid-solid interfacial growth. | 476 · Fabrication, Sensing Mechanisms and Characterizations · Figure 1 |
| Ni3(HiTP)2-on-polypropylene composite filmBrowse family: Ni₃(HITP)₂ / Ni–HITP | Ni3(HiTP)2/PPNi(II) · HiTP-derived linker | 2D · CompositeControl substrate composite fabricated using PP membrane instead of MSMC membrane. | 477 · Pressure-Sensing Properties · Figure S5; Figure S6 |
| Ni3(HiTP)2 conductive metal-organic frameworkBrowse family: Ni₃(HITP)₂ / Ni–HITP | Ni3(HiTP)2Ni(II) · HiTP / 2,3,6,7,10,11-hexaaminotriphenylene-derived ligand | 2D · PristineConductive MOF film assigned by XRD and literature-prepared Ni3(HiTP)2; band-structure model shown for Ni3(HiTP)2. | 476 · Results and Discussion · Figure 1; Figure S1 |
| Ni3(HiTP)2 computational modelBrowse family: Ni₃(HITP)₂ / Ni–HITP | Ni3(HiTP)2Ni · HiTP-derived linker | 2D · Model SystemFirst-principles model for band structures under 0 and 300 kPa. | 480 · Analysis of the Mutual Noninterference Mechanism · Figure 4g-i |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| MOF-MSMC-2.5h composite film/sensorresearch_0723__mat__mat_mof_msmc | Thin Film · Composite Sample · Composite | Ni3(HiTP)2 grown for 2.5 h; used as sensor variantMSMC membrane · ca. 58.8, 62.1, 54.3 nm local cross-sectional labels in Figure S3b | 476 · Results and Discussion · Figure S3; Table S1; Table S2 |
| MOF-MSMC-5h composite film/sensorresearch_0723__mat__mat_mof_msmc | Thin Film · Target Sample · Composite | Ni3(HiTP)2 grown for 5 h; primary dual-modal sensorMSMC membrane with PDMS in assembled sensor · 245.4 nm MOF film on MSMC; sensor size 2 mm x 1 mm x 0.4 mm for rat measurement and 2 mm x 1 mm x 0.7 mm when sealed by PDMS | 476 · Results and Discussion · Figure 1; Figure 2 |
| MOF-MSMC-5h tensile-strain test deviceresearch_0723__mat__mat_mof_msmc | Electrode · Composite Sample · Composite | two Cu conductive wires separately installed on two sides for tensile strain sensing testMSMC membrane | 481 · Preparation of the MOF-MSMC/PP Sensor |
| MOF-MSMC-7.5h composite film/sensorresearch_0723__mat__mat_mof_msmc | Thin Film · Composite Sample · Composite | Ni3(HiTP)2 grown for 7.5 h; used as sensor variantMSMC membrane · ca. 130.1, 106.8, 125.7 nm local cross-sectional labels in Figure S3d | 476 · Results and Discussion · Figure S3; Table S1; Table S2 |
| 3 x 3 MOF-MSMC-5h sensor arrayresearch_0723__mat__mat_mof_msmc | Electrode · Composite Sample · Composite | 3 x 3 array for spatial pressure-temperature mappingarray substrate with nine sensing units | 480-481 · Dual-Modal Applications · Figure 5; Figure S15 |
| MOF-MSMC-5h sensor sealed by PDMS implantresearch_0723__mat__mat_mof_msmc | Electrode · Composite Sample · Composite | PDMS-sealed sterile implant for rat condyle experimentMSMC membrane / PDMS-sealed implant · 2 mm x 1 mm x 0.7 mm | 481 · Animal Experiments |
| MOF-PP-5h composite film/sensorresearch_0723__mat__mat_mof_pp | Thin Film · Pristine Control · Composite | Ni3(HiTP)2 grown for 5 h on PP and assembled into sensorpolypropylene membrane · approximately 428 nm | 477 · Pressure-Sensing Properties · Figure S5; Figure S6 |
| naked MSMC substrateresearch_0723__mat__mat_mof_msmc | Thin Film · Pristine Control · Composite | substrate before MOF growthmicrostructured mixed cellulose membrane | 476 · Fabrication, Sensing Mechanisms and Characterizations · Figure 1g,i,k,m |
| Ni3(HiTP)2 band-structure model under 0 and 300 kParesearch_0723__mat__mat_ni3_hitp2_model | Model · Model System · Model | geometrically optimized computational crystal modelnone | 482 · Macroscopic FEA Model and Microscopic First-Principles Calculations |