Spectroscopy — Synthesis of a highly conductive coordination polymer film via a vapor-solid phase chemical conversion process

Measurement evidence

Spectroscopy

Synthesis of a highly conductive coordination polymer film via a vapor-solid phase chemical conversion process · Li Z., Jin Y., Li C. et al. · Chemical Communications · 2024 · 8720-8723

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FT-IR spectroscopy, VERTEX 70v vacuum micro-FTIR

Ag5BHT thin films · Thin Film

FT-IR spectra before and after reaction; comparison of Ag2O/H6BHT film and Ag5BHT thin film.

Context
Ag5BHT thin film after conversion versus precursor
Measurement source
8722 · Results · Fig. 2f
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
S-H stretching feature removed after conversion2500 cm^-1 S-H stretch vanishedText
Rounded Reported
8722 · Results · Fig. 2f

X-ray photoelectron spectroscopy, AXIS Ultra-DLD with monochromatic magnesium Ka source

Ag5BHT thin films · Thin Film

Full XPS spectrum and Ag 3d/S 2p regions compared for thin films, powder, and H6BHT ligand.

Atmosphere
ultrahigh vacuum
Context
Ag5BHT thin film and Ag5BHT powder comparison
Measurement source
SI p002 · Characterization · Fig. S10-S11 and Fig. 2g
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Ag 3d3/2 binding energy374 eVText
Rounded Reported
8722 · Results · Fig. S11
Ag 3d5/2 binding energy368 eVText
Rounded Reported
8722 · Results · Fig. S11
XPS elemental contentcarbon, sulfur, silver, silicon, and oxygen peaks presentText
Qualitative
8722 · Results · Fig. S10
Ag and S chemical environmentstwo distinct chemical environments of Ag and SText
Qualitative
8722 · Results · Fig. 2g