Complete recipeSource: SI
Route 1: Other
SI text · S-3.2 Synthesis of Co3(HITP)2
Metal precursorsCobalt(II) nitrate hexahydrate, Co(NO3)2.6H2O, 162.7 mg (0.56 mmol)
Linker precursorsHATP.6HCl, 30 mg (0.056 mmol)
Solvents9 mL DMF for cobalt salt; 9 mL water for HATP; 12 mL aqueous NaOAc
AdditivesNaOAc aqueous solution, 2 mol L-1, 12 mL
AtmosphereOpen beaker; atmosphere not otherwise specified
Temperature65
Time2
Work-upCentrifuged; washed with ultrapure water and methanol.
ActivationDried under vacuum at 60 deg C.
Scalability context20 mL open beaker batch.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | cobalt(II) nitrate hexahydrate (Co(NO3)2.6H2O) | 162.7 mg (0.56 mmol) | SI text · S-3.2 Synthesis of Co3(HITP)2 |
| Linker | HATP.6HCl | 30 mg (0.056 mmol) | SI text · S-3.2 Synthesis of Co3(HITP)2 |
| Solvent | DMF | 9 mL | SI text · S-3.2 Synthesis of Co3(HITP)2 |
| Solvent | water | 9 mL | SI text · S-3.2 Synthesis of Co3(HITP)2 |
| Base | NaOAc aqueous solution | 12 mL · 2 mol L-1 | SI text · S-3.2 Synthesis of Co3(HITP)2 |