cMOF Evidence Base
Other — Microfluidic Printing-Induced Dynamic Splitting of Conductive MOF to Expose High-Density Active Sites for Boosted CO2 Electroreduction

Measurement evidence

Other

Microfluidic Printing-Induced Dynamic Splitting of Conductive MOF to Expose High-Density Active Sites for Boosted CO2 Electroreduction · Yue J.-N., Wang Y., Meng J. et al. · Small · 2026 · e00018

9 measurement groups · 93 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

H-cell economic viability table

ST-cMOF H-cell electrode ink · Electrode

Rendered SI Table S5: ST-cMOF H-cell economic calculation at -1.1 to -1.5 V vs RHE.

Atmosphere
CO2RR H-cell
Geometry
H-cell economic model
Context
ST-cMOF control electrode
Measurement source
32 · Section S2 Supplementary figures and tables · Table S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ST-cMOF H-cell economic viability at -1.1 VSTY 1.78 kg m^-3 day^-1; electric cost 8.16 USD day^-1; FE CH4 31%; output CH4 279 mL h^-1; economic viability 1.729e3 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		32 · Section S2 Supplementary figures and tables · Table S5
ST-cMOF H-cell economic viability at -1.2 VMarked as a best value within this paperSTY 1.78 kg m^-3 day^-1; electric cost 8.64 USD day^-1; FE CH4 44%; output CH4 396 mL h^-1; economic viability 2.458e3 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		32 · Section S2 Supplementary figures and tables · Table S5
ST-cMOF H-cell economic viability at -1.3 VSTY 1.78 kg m^-3 day^-1; electric cost 9.12 USD day^-1; FE CH4 38%; output CH4 342 mL h^-1; economic viability 2.121e3 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		32 · Section S2 Supplementary figures and tables · Table S5
ST-cMOF H-cell economic viability at -1.4 VSTY 1.78 kg m^-3 day^-1; electric cost 9.6 USD day^-1; FE CH4 34%; output CH4 306 mL h^-1; economic viability 1.897e3 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		32 · Section S2 Supplementary figures and tables · Table S5
ST-cMOF H-cell economic viability at -1.5 VSTY 1.78 kg m^-3 day^-1; electric cost 10.8 USD day^-1; FE CH4 35%; output CH4 315 mL h^-1; economic viability 1.953e3 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		32 · Section S2 Supplementary figures and tables · Table S5

H-cell economic viability table

MF-cMOFQx/ty H-cell electrode inks · Electrode

Rendered SI Table S6: MF-cMOF H-cell economic calculation across flow-rate and residence-time variants.

Atmosphere
CO2RR H-cell
Geometry
H-cell economic model
Context
MF-cMOF electrode series
Measurement source
33-34 · Section S2 Supplementary figures and tables · Table S6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
mf_cmof_q0_64_t5 H-cell economic viability at -1.1 VSTY 460 kg m^-3 day^-1; FE CH4 62%; output CH4 558 mL h^-1; economic viability 8.984e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q0_64_t5 H-cell economic viability at -1.2 VSTY 460 kg m^-3 day^-1; FE CH4 70%; output CH4 630 mL h^-1; economic viability 1.014e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q0_64_t5 H-cell economic viability at -1.3 VSTY 460 kg m^-3 day^-1; FE CH4 68%; output CH4 612 mL h^-1; economic viability 9.853e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q0_64_t5 H-cell economic viability at -1.4 VSTY 460 kg m^-3 day^-1; FE CH4 69%; output CH4 621 mL h^-1; economic viability 9.998e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q0_64_t5 H-cell economic viability at -1.5 VSTY 460 kg m^-3 day^-1; FE CH4 62%; output CH4 558 mL h^-1; economic viability 8.984e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t10 H-cell economic viability at -1.1 VSTY 251 kg m^-3 day^-1; FE CH4 51%; output CH4 459 mL h^-1; economic viability 4.032e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t10 H-cell economic viability at -1.2 VSTY 251 kg m^-3 day^-1; FE CH4 67%; output CH4 603 mL h^-1; economic viability 5.297e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t10 H-cell economic viability at -1.3 VSTY 251 kg m^-3 day^-1; FE CH4 39%; output CH4 351 mL h^-1; economic viability 3.083e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t10 H-cell economic viability at -1.4 VSTY 251 kg m^-3 day^-1; FE CH4 36%; output CH4 324 mL h^-1; economic viability 2.846e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t10 H-cell economic viability at -1.5 VSTY 251 kg m^-3 day^-1; FE CH4 35%; output CH4 315 mL h^-1; economic viability 2.767e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t20 H-cell economic viability at -1.1 VSTY 151 kg m^-3 day^-1; FE CH4 42%; output CH4 378 mL h^-1; economic viability 1.998e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t20 H-cell economic viability at -1.2 VSTY 151 kg m^-3 day^-1; FE CH4 42%; output CH4 378 mL h^-1; economic viability 1.998e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t20 H-cell economic viability at -1.3 VSTY 151 kg m^-3 day^-1; FE CH4 56%; output CH4 504 mL h^-1; economic viability 2.664e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t20 H-cell economic viability at -1.4 VSTY 151 kg m^-3 day^-1; FE CH4 46%; output CH4 414 mL h^-1; economic viability 2.188e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t20 H-cell economic viability at -1.5 VSTY 151 kg m^-3 day^-1; FE CH4 41%; output CH4 369 mL h^-1; economic viability 1.950e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t2_5 H-cell economic viability at -1.1 VSTY 1047 kg m^-3 day^-1; FE CH4 22%; output CH4 198 mL h^-1; economic viability 7.256e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t2_5 H-cell economic viability at -1.2 VSTY 1047 kg m^-3 day^-1; FE CH4 43%; output CH4 387 mL h^-1; economic viability 1.418e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t2_5 H-cell economic viability at -1.3 VSTY 1047 kg m^-3 day^-1; FE CH4 38%; output CH4 342 mL h^-1; economic viability 1.253e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t2_5 H-cell economic viability at -1.4 VSTY 1047 kg m^-3 day^-1; FE CH4 15%; output CH4 135 mL h^-1; economic viability 4.947e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t2_5 H-cell economic viability at -1.5 VSTY 1047 kg m^-3 day^-1; FE CH4 27%; output CH4 243 mL h^-1; economic viability 8.095e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t5 H-cell economic viability at -1.1 VSTY 502 kg m^-3 day^-1; FE CH4 75%; output CH4 675 mL h^-1; economic viability 1.186e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t5 H-cell economic viability at -1.2 VMarked as a best value within this paperSTY 502 kg m^-3 day^-1; FE CH4 79%; output CH4 711 mL h^-1; economic viability 1.249e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t5 H-cell economic viability at -1.3 VSTY 502 kg m^-3 day^-1; FE CH4 73%; output CH4 657 mL h^-1; economic viability 1.154e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t5 H-cell economic viability at -1.4 VSTY 502 kg m^-3 day^-1; FE CH4 76%; output CH4 684 mL h^-1; economic viability 1.202e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q1_28_t5 H-cell economic viability at -1.5 VSTY 502 kg m^-3 day^-1; FE CH4 77%; output CH4 693 mL h^-1; economic viability 1.218e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q2_56_t5 H-cell economic viability at -1.1 VSTY 523 kg m^-3 day^-1; FE CH4 47%; output CH4 423 mL h^-1; economic viability 7.743e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q2_56_t5 H-cell economic viability at -1.2 VSTY 523 kg m^-3 day^-1; FE CH4 44%; output CH4 396 mL h^-1; economic viability 7.249e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q2_56_t5 H-cell economic viability at -1.3 VSTY 523 kg m^-3 day^-1; FE CH4 46%; output CH4 414 mL h^-1; economic viability 7.578e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q2_56_t5 H-cell economic viability at -1.4 VSTY 523 kg m^-3 day^-1; FE CH4 49%; output CH4 441 mL h^-1; economic viability 8.072e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q2_56_t5 H-cell economic viability at -1.5 VSTY 523 kg m^-3 day^-1; FE CH4 54%; output CH4 486 mL h^-1; economic viability 8.896e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q5_12_t5 H-cell economic viability at -1.1 VSTY 251 kg m^-3 day^-1; FE CH4 40%; output CH4 360 mL h^-1; economic viability 3.163e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q5_12_t5 H-cell economic viability at -1.2 VSTY 251 kg m^-3 day^-1; FE CH4 53%; output CH4 477 mL h^-1; economic viability 4.190e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q5_12_t5 H-cell economic viability at -1.3 VSTY 251 kg m^-3 day^-1; FE CH4 47%; output CH4 423 mL h^-1; economic viability 3.716e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q5_12_t5 H-cell economic viability at -1.4 VSTY 251 kg m^-3 day^-1; FE CH4 44%; output CH4 396 mL h^-1; economic viability 3.479e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6
mf_cmof_q5_12_t5 H-cell economic viability at -1.5 VSTY 251 kg m^-3 day^-1; FE CH4 39%; output CH4 351 mL h^-1; economic viability 3.083e5 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		33-34 · Section S2 Supplementary figures and tables · Table S6

Flow-cell economic viability table

MF-cMOFQ1.28/t5 flow-cell electrode · Electrode

Rendered SI Table S7: MF-cMOFQ1.28/t5 vs ST-cMOF flow-cell economic calculation.

Atmosphere
CO2RR flow cell
Geometry
flow-cell economic model
Context
target vs control flow-cell electrodes
Measurement source
34-35 · Section S2 Supplementary figures and tables · Table S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
mf_cmof_q1_28_t5 flow-cell economic viability at -0.9 VSTY 502 kg m^-3 day^-1; FE CH4 68%; output CH4 612 mL h^-1; economic viability 1.29e7 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
mf_cmof_q1_28_t5 flow-cell economic viability at -1.0 VSTY 502 kg m^-3 day^-1; FE CH4 67%; output CH4 605 mL h^-1; economic viability 1.28e7 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
mf_cmof_q1_28_t5 flow-cell economic viability at -1.1 VMarked as a best value within this paperSTY 502 kg m^-3 day^-1; FE CH4 73%; output CH4 661 mL h^-1; economic viability 1.39e7 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
mf_cmof_q1_28_t5 flow-cell economic viability at -1.2 VSTY 502 kg m^-3 day^-1; FE CH4 62%; output CH4 565 mL h^-1; economic viability 1.19e7 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
mf_cmof_q1_28_t5 flow-cell economic viability at -1.3 VSTY 502 kg m^-3 day^-1; FE CH4 50%; output CH4 453 mL h^-1; economic viability 9.57e6 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
st_cmof flow-cell economic viability at -0.9 VSTY 1.78 kg m^-3 day^-1; FE CH4 43%; output CH4 387 mL h^-1; economic viability 2.89e4 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
st_cmof flow-cell economic viability at -1.0 VSTY 1.78 kg m^-3 day^-1; FE CH4 46%; output CH4 414 mL h^-1; economic viability 3.09e4 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
st_cmof flow-cell economic viability at -1.1 VSTY 1.78 kg m^-3 day^-1; FE CH4 54%; output CH4 491 mL h^-1; economic viability 3.67e4 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
st_cmof flow-cell economic viability at -1.2 VSTY 1.78 kg m^-3 day^-1; FE CH4 48%; output CH4 439 mL h^-1; economic viability 3.29e4 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7
st_cmof flow-cell economic viability at -1.3 VSTY 1.78 kg m^-3 day^-1; FE CH4 42%; output CH4 381 mL h^-1; economic viability 2.85e4 USD kg^-1 m^-3 day^-1——SI Table
Exact Reported		34-35 · Section S2 Supplementary figures and tables · Table S7

Reynolds number calculation for microfluidic flow

MF-cMOFQx/ty series · Nanosheet

Re calculated for pipe flow rates 0.64, 1.28, 2.56, and 5.12 mL min^-1 with D = 0.002 m.

Geometry
microfluidic PTFE tubing
Context
synthesis fluid dynamics
Measurement source
4 · 2.1 Synthesis and Characterization of cMOF · Figure S25; Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Reynolds number range0.033 to 2.110—rangeSI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3

Reynolds-number table calculation

MF-cMOFQx/ty series · Nanosheet

Rendered SI Table S3: Re values and flow state for MF-cMOFQx/t5.

Atmosphere
not stated
Geometry
0.002 m pipe diameter microfluidic tubing
Context
synthesis fluid dynamics
Measurement source
16-17 · Section S2 Supplementary figures and tables · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
mf_cmof_q0_64_t5 Reynolds numberRe 0.033; v 0.0034 m s^-1; laminar flow——SI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3
mf_cmof_q1_28_t5 Reynolds numberRe 0.132; v 0.0068 m s^-1; laminar flow——SI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3
mf_cmof_q2_56_t5 Reynolds numberRe 0.527; v 0.0136 m s^-1; laminar flow——SI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3
mf_cmof_q5_12_t5 Reynolds numberRe 2.110; v 0.0272 m s^-1; laminar flow——SI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3
mf_cmof_q0_64_t5 flow velocity0.0034 m s^-1——SI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3
mf_cmof_q1_28_t5 flow velocity0.0068 m s^-1——SI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3
mf_cmof_q2_56_t5 flow velocity0.0136 m s^-1——SI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3
mf_cmof_q5_12_t5 flow velocity0.0272 m s^-1——SI Table
Exact Reported		16-17 · Section S2 Supplementary figures and tables · Table S3

Space-time yield (STY) calculation

MF-cMOFQx/ty series · Nanosheet

STY defined as mass of product per unit reactor volume per day; fixed 5 min residence time for MF-cMOFQx/t5 series.

Geometry
microfluidic reaction tube
Context
synthesis productivity
Measurement source
Section S2 Supplementary figures and tables · Equation S2; Figure 5a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Reaction time reduction for MF-cMOFQ1.28/t5 versus ST-cMOFMarked as a best value within this paper24 h to 5 min——Text
Exact Reported		7 · 2.3 Mechanism Study · Figure 5a
STY enhancement of MF-cMOFQ1.28/t5 over ST-cMOFMarked as a best value within this paper282-fold——Text
Rounded Reported		7 · 2.3 Mechanism Study · Figure 5a
MF-cMOFQ0.64/t5 space-time yield460 kg m^-3 day^-1——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
MF-cMOFQ1.28/t5 space-time yield502 kg m^-3 day^-1——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
MF-cMOFQ2.56/t5 space-time yieldMarked as a best value within this paper523 kg m^-3 day^-1——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
MF-cMOFQ5.12/t5 space-time yield251 kg m^-3 day^-1——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
ST-cMOF space-time yield1.78 kg m^-3 day^-1——Text
Exact Reported		7 · 2.3 Mechanism Study · Figure 5a; Equation S2
MF-cMOFQ1.28/t5 production yieldMarked as a best value within this paper0.29 g h^-1——Text
Exact Reported		1 · Abstract

Microfluidic synthesis parameter table

MF-cMOFQx/ty series · Nanosheet

Rendered SI Table S1: MF-cMOFQx/t5 flow-rate series at 5 min residence time.

Temperature
338.15
Atmosphere
not stated
Geometry
PTFE microfluidic tube
Context
framework synthesis productivity
Measurement source
6 · Section S2 Supplementary figures and tables · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
mf_cmof_q0_64_t5 actual reaction time132 min——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q0_64_t5 isolated quantity22 mg——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q0_64_t5 yield rate0.268 g h^-1——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q1_28_t5 actual reaction time66 min——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q1_28_t5 isolated quantity24 mg——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q1_28_t5 yield rate0.293 g h^-1——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q2_56_t5 actual reaction time33 min——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q2_56_t5 isolated quantity25 mg——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q2_56_t5 yield rate0.305 g h^-1——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q5_12_t5 actual reaction time7 min——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q5_12_t5 isolated quantity12 mg——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1
mf_cmof_q5_12_t5 yield rate0.146 g h^-1——SI Table
Exact Reported		6 · Section S2 Supplementary figures and tables · Table S1

Microfluidic residence-time synthesis parameter table

MF-cMOFQx/ty series · Nanosheet

Rendered SI Table S2: MF-cMOFQ1.28/ty residence-time series at Qt 1.28 mL min^-1.

Temperature
338.15
Atmosphere
not stated
Geometry
PTFE microfluidic tube
Context
framework synthesis productivity
Measurement source
6-7 · Section S2 Supplementary figures and tables · Table S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
mf_cmof_q1_28_t10 space-time yield251 kg m^-3 day^-1——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2
mf_cmof_q1_28_t20 space-time yield151 kg m^-3 day^-1——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2
mf_cmof_q1_28_t2_5 space-time yieldMarked as a best value within this paper1047 kg m^-3 day^-1——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2
mf_cmof_q1_28_t10 isolated quantity24 mg——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2
mf_cmof_q1_28_t10 yield rate0.146 g h^-1——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2
mf_cmof_q1_28_t20 isolated quantity29 mg——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2
mf_cmof_q1_28_t20 yield rate0.088 g h^-1——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2
mf_cmof_q1_28_t2_5 isolated quantity25 mg——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2
mf_cmof_q1_28_t2_5 yield rate0.611 g h^-1——SI Table
Exact Reported		6-7 · Section S2 Supplementary figures and tables · Table S2

Simplified techno-economic analysis

MF-cMOFQ1.28/t5 · Nanosheet

Profit-based comparison from CH4 revenue minus CO2 feedstock and electricity costs; H-cell data and flow-cell current density data considered.

Geometry
H-cell and flow-cell economic scenarios
Context
target vs ST-cMOF comparison
Measurement source
32-35 · 2.3 Mechanism Study · Figure 5d,e; Tables S5-S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
CH4 price assumptionapproximately 0.35 USD m^-3—approximatelyText
Approximate		8 · 2.3 Mechanism Study · Figure 5d,e
CO2 cost assumptionapproximately 0.05 USD m^-3—approximatelyText
Approximate		8 · 2.3 Mechanism Study · Figure 5d,e
Daily revenue increase for MF-cMOFQ1.28/t5 versus ST-cMOFMarked as a best value within this paper506.2-fold increase——Text
Exact Reported		8 · 2.3 Mechanism Study · Tables S5-S6
Calculated daily CH4 revenue for MF-cMOFQ1.28/t5Marked as a best value within this paper1.249 x 10^6 USD kg^-1 m^-3 day^-1——Text
Exact Reported		8 · 2.3 Mechanism Study · Tables S5-S6
Calculated daily CH4 revenue for ST-cMOF2.458 x 10^3 USD kg^-1 m^-3 day^-1——Text
Exact Reported		8 · 2.3 Mechanism Study · Tables S5-S6