Xiaoyu Song, Jingjuan Liu, Ting Zhang, Long Chen · Science China Chemistry · 2020
Survey the electrical, magnetic and quantum properties of 2D conductive metal-organic frameworks, with emphasis on electronics, spintronics, semiconductors, metals, superconductors, topological insulators and porous magnets.
The review’s argument is preserved as a navigable set of section summaries.
Synthesises future needs around ordered layers, intrinsic mechanism identification, single-crystal and film growth, stability, processing and device fabrication.
Relevance: Core · 1398 · Challenges and opportunities
Defines semiconductor/metal distinctions, through-bond versus through-space pathways, hopping versus band-like transport, and reviews key semiconducting and metallic 2D c-MOF examples.
Relevance: Core · 1392 · Electrical properties
Introduces 2D c-MOFs as designable, conjugated organic/inorganic 2D materials and positions the review around charge and spin degrees of freedom rather than only electrical applications.
Relevance: Core · 1392 · Introduction
Explains spintronic motivation, magnet classes, radical/metal-linker design strategies, conductive porous magnets, ferromagnetic semiconductors and 2D c-MOF organic spin-valve examples.
Relevance: Core · 1394 · Magnetic properties
Frames quantum states arising from coupled charge, spin, lattice and orbital degrees of freedom, focusing on superconductors and topological insulators.
Relevance: Core · 1397 · Quantum properties
Reviews theoretical and experimental Cu-BHT superconductivity as the key 2D c-MOF superconducting case, including crystallinity dependence and possible second phase.
Relevance: Core · 1397 · Superconductor · Figure 7
Summarises 2D organometallic and 2D c-MOF topological-insulator proposals, emphasising lattice symmetry, spin-orbit coupling, redox control and heavy-atom effects.
Relevance: Supporting · 1397 · Topological insulator
Classification systems are attributed to this review and are not treated as a global material registry.
The review uses Fermi-level position and band gap concepts to distinguish metallic conductors, semiconductors and insulators before applying them to 2D c-MOFs.
Categories: metal · semiconductor · insulator
1392 · Electrical properties
The review classifies magnetic behaviour by alignment and magnitude of adjacent spins, illustrated by the Figure 3 schematic.
Categories: diamagnet · paramagnet · ferromagnet · ferrimagnet · antiferromagnet
1394 · Magnetic properties · Figure 3
The review contrasts shortening metal-metal distances with radical ligands that relay exchange between metal centres, while noting porosity trade-offs.
Categories: paramagnetic first-row transition metals · small diamagnetic linkers · radical-based ligands · redox-active radical linkers
1394 · Magnetic properties
Quantum properties are framed as emergent states from coupled charge, spin, lattice and orbital degrees of freedom.
Categories: Dirac semimetals · superconductors · topological insulators · quantum Hall effects
1397 · Quantum properties
In the outlook, synthesis is organised around top-down versus bottom-up routes, with high-quality single/few-layer growth highlighted as unresolved.
Categories: top-down methods · bottom-up methods · interfacial synthesis · chemical vapour deposition · liquid-air interfacial synthesis
1398 · Challenges and opportunities
For 2D organic/organometallic TIs, the review emphasises SOC and lattice symmetry, then discusses doping and heavy atoms as tuning handles.
Categories: lattice symmetry · spin-orbit coupling · redox-controlled doping · heavy-atom effect
1397 · Topological insulator
In-plane metal d orbital to ligand pi-system conjugation is described as the dominant through-bond route, while through-space transport depends on compact pi-pi stacked neighbouring ligands.
Categories: through-bond · through-space
1392 · Electrical properties
Increasing conductivity with temperature is associated with hopping semiconductor behaviour; decreasing conductivity with increasing temperature indicates band-like transport in metals or doped low-ionisation semiconductors.
Categories: hopping transport · band-like transport
1392 · Electrical properties
Review-defined families retain their representative materials and conduction descriptions.
2D c-MOFs based on compact benzene-derived HIB, HAB or HHB linkers that can increase orbital overlap and conductivity.
Conduction: The review associates smaller benzene-core linkers with higher conductivity and possible metallic behaviour, although anisotropy and grain-boundary effects complicate assignment.
Representative materials: Ni3(HIB)2 · Cu3(HIB)2 · M-HAB · Cu3(C6O6)2
Nodes / linkers: Ni · Cu · Co · hexaiminobenzene · hexaaminobenzene · hexahydroxybenzene
1393 · Electrical properties
Sulfur- or selenium-rich 2D frameworks using BHT or BHS ligands, prominent in metallic, superconducting and topological-insulator discussions.
Conduction: Strong metal-chalcogen coordination and pi conjugation support metallic behaviour, redox-tuned conductivity and, for Cu-BHT, superconductivity at low temperature.
Representative materials: Cu-BHT · Cu-BHS · Ni3(BHT)2 · NiDT · PtDT
Nodes / linkers: Cu · Ni · Pt · benzenehexathiol · benzenehexaselenol · bis(dithiolene)
1397 · Superconductor · Figure 7
Layered 2D c-MOFs built from triphenylene-derived HITP, HHTP or HOTP linkers and transition-metal nodes, used as central examples for semiconducting films, single-crystal transport and spin valves.
Conduction: Often semiconducting in polycrystalline films, but grain boundaries, dimensionality and out-of-plane interactions can alter the apparent transport nature.
Representative materials: Ni3(HITP)2 · Cu3HHTP2 · Cu3HITP2 · Cu3(HHTP)2
Nodes / linkers: Ni · Cu · HITP · HHTP · HOTP
1394 · Electrical properties
NiTAA-MOF is used to discuss ligand oxidation, doped semiconducting behaviour and weak antiferromagnetic coupling.
Conduction: Bulk NiTAA-MOF is insulating, while I2 doping creates semiconducting behaviour through ligand oxidation and associated spin carriers.
Representative materials: NiTAA-MOF · I2-doped NiTAA-MOF
Nodes / linkers: Ni · tetraaza[14]annulene
1396 · Magnetic properties
Metal phthalocyanine or octahydroxyphthalocyaninato frameworks proposed or demonstrated for high-temperature magnetic correlations and spin/electronic coupling.
Conduction: Reviewed as p-type semiconducting or half-metallic/ferromagnetic candidates, with carrier-moment coupling inferred through negative magnetoresistance and magnetic measurements.
Representative materials: NiMn-OIPc · K3Fe2[PcFe-O8]
Nodes / linkers: Ni · Mn · Fe · octaiminophthalocyanine · octahydroxyphthalocyaninato iron
1396 · Magnetic properties · Figure 5
An extended planar ligand and square-planar metal-linkage framework reviewed as a ferromagnetic semiconductor.
Conduction: Semiconducting pellets with high room-temperature conductivity and ferromagnetic behaviour below 20 K.
Representative materials: PTC-Fe
Nodes / linkers: Fe · perthiolated coronene
1395 · Magnetic properties · Figure 5
Redox-active radical-containing 2D frameworks where ligand mixed valency and metal centres create magnetic ordering, porosity and sometimes switchable conductivity.
Conduction: Radical linkers relay magnetic interactions; redox state can switch magnetism and conductivity, although absolute conductivity may remain low in some examples.
Representative materials: (Me2NH2)2[Fe2L3] · (Cp2Co)1.43(Me2NH2)1.57[Fe2L3] · (Me4N)2[Mn2(L)3] · Na3(Me4N)2[Mn2(L)3]
Nodes / linkers: Fe · Mn · chloranilate · benzoquinoid linkers · semiquinone radicals
1395 · Magnetic properties · Figure 4
Extended chalcogenated triphenylene frameworks such as Fe/Co-THT and Co-TPHS that highlight band-like transport, metal-semiconductor transitions and magnetic behaviour.
Conduction: Transport can be band-like and semi-metallic, with interlayer d/p orbital overlap and air oxidation affecting metallic transition behaviour.
Representative materials: Fe3(THT)2(NH4)3 · Co-THT · Fe-THT · Co-TPHS
Nodes / linkers: Fe · Co · hexathioltriphenylene · triphenylenehexaselenol
1393 · Electrical properties
Review-level synthesis principles remain separate from primary-study recipes.
The review repeatedly cites interface-grown membranes, nanosheets and films as routes to smoother or more device-compatible 2D c-MOF materials.
Claimed effects: Can produce smoother membranes or nanosheets suitable for FETs, thin films and improved crystallinity relative to granular powders.
Controlling variables: interface choice · metal salt and ligand pairing · film thickness · crystallinity · transfer/lift-off processing
Representative materials: Ni3(HITP)2 membrane · M-HAB nanosheets · NiDT nanosheets · PtDT
Caveat: Interfacial synthesis is a strategy-level route; the review does not provide full recipes and still notes immature film processing.
1392 · Electrical properties
The outlook identifies bottom-up solution preparation as efficient, convenient and cost-effective for 2D c-MOF synthesis.
Claimed effects: Provides practical access to 2D c-MOF powders and films, but usually gives polycrystalline samples with short-range order.
Controlling variables: metal precursor · ligand · solvent · additives · concentration · pressure · atmosphere · reaction time
Representative materials: general 2D c-MOFs
Caveat: Most reported samples remain polycrystalline powders, limiting intrinsic-property interpretation.
1398 · Challenges and opportunities
The review calls for improved interfacial synthesis, liquid-phase epitaxy, electrochemical deposition, solvo/hydrothermal methods and composite-film preparation for devices.
Claimed effects: Better films and MOF/COF or MOF/MOF composites should improve device integration and multifunctional behaviour.
Controlling variables: film thickness · interface definition · crystal domain size · heterostructure composition · electrode integration
Representative materials: Cu3HHTP2 OSV layer · MOF thin films · COF-MOF composite films · MOF-MOF composite films
Caveat: The review explicitly says current film processing is immature and thicker polycrystalline films have ill-defined interfaces.
1400 · Challenges and opportunities
Guest oxidants/reductants or post-synthetic redox chemistry tune oxidation state, carrier density, magnetic state and conductivity.
Claimed effects: Can increase conductivity, switch magnetism, create radical spin carriers and tune topological or metallic states.
Controlling variables: dopant identity · oxidation state · air or iodine exposure · redox-active ligand groups · framework charge balance
Representative materials: NiDT · PtDT · NiTAA-MOF · Mn benzoquinoid framework · Fe-THT
Caveat: Air sensitivity and redox-state disorder can complicate stability and interpretation.
1398 · Topological insulator · Figure 8
Optimised single-crystalline 2D c-MOF growth is presented as essential to distinguish intrinsic in-plane/out-of-plane pathways from grain-boundary effects.
Claimed effects: Single crystals with defined structures can reveal metallic behaviour masked in polycrystalline films and enable single-crystal diffraction/transport studies.
Controlling variables: additives · solvent · metal precursor · feeding sequence · concentration · atmosphere · pressure · reaction time
Representative materials: Cu3HHTP2 · Cu3HITP2 · Ni3(HITP)2 rods
Caveat: Large single-crystal growth remains a major challenge.
1399 · Challenges and opportunities
A vapour-induced conversion approach is cited for constructing conductive Ni3(HITP)2 film with magnetic hysteresis.
Claimed effects: Produces conductive Ni3(HITP)2 film whose magnetic measurements show hysteresis and ferromagnetic assignment.
Controlling variables: vapour conversion environment · film formation · Ni(II) high-spin state · temperature
Representative materials: Ni3(HITP)2 film
Caveat: The review reports the magnetic assignment but does not resolve broader spin-transport physics.
1396 · Magnetic properties
These are the review authors’ synthesis, not newly measured results.
2D c-MOFs are presented as an emerging class of 2D materials combining pre-designable structures, crystallinity, porosity and superior conductivity.
Evidence basis: review_reasoning
Caveat: This is the review authors' framing rather than a measured result.
1391 · Abstract
Conventional conductivity measurements alone may not ascertain the nature of charge transport in 2D c-MOFs.
Evidence basis: multi_reference
Caveat: Requires complementary probes such as TRTS, Hall, UPS, Seebeck and theory.
1393 · Electrical properties
Cu-BHT is presented as the first reported coordination polymer with superconductivity, with theory and experiment making it a central quantum-material benchmark.
Evidence basis: multi_reference
Caveat: A second superconducting phase is noted but not clearly assigned.
1397 · Superconductor · Figure 7
Immature film processing and ill-defined interfaces in thicker polycrystalline films are major barriers to 2D c-MOF electronic devices.
Evidence basis: review_reasoning
Caveat: Not all films are equivalent; high-quality interfacial or single-crystal growth may mitigate this.
1399 · Challenges and opportunities
Dimensionality and interlayer transport can change the electronic character of a 2D c-MOF from semiconductor-like sheets to more metallic bulk behaviour.
Evidence basis: single_reference
Caveat: Based on DFT calculations as summarised by the review.
1394 · Electrical properties
Ferromagnetic semiconducting 2D c-MOFs are positioned as promising spin-polarised carrier sources for spintronic devices.
Evidence basis: multi_reference
Caveat: The review examples are still early and often involve low-temperature behaviour.
1395 · Magnetic properties
Grain boundaries and sample crystallinity can cause the same framework family to appear semiconducting in polycrystalline films but metallic in single-crystal devices.
Evidence basis: single_reference
Caveat: The statement is tied to reviewed single-crystal examples and should not be universalised without primary confirmation.
1394 · Electrical properties
Magnetic MOF design must balance short metal-metal distances, porosity and radical-mediated exchange pathways.
Evidence basis: multi_reference
Caveat: Shortening linkers can strengthen magnetic interactions but may inhibit porosity.
1394 · Magnetic properties
Most reported 2D c-MOFs are described as experimentally semiconducting with hopping transport behaviour.
Evidence basis: multi_reference
Caveat: The review also highlights exceptions and cases where apparent behaviour depends on sample form.
1392 · Electrical properties
The review argues that mechanism identification requires combined conventional conductivity, carrier/electronic-structure probes and theory rather than one measurement type.
Evidence basis: review_reasoning
Caveat: Specific technique choice depends on sample form and target mechanism.
1399 · Challenges and opportunities
The first 2D c-MOF organic spin valve demonstrates magnetoresistance, but spin-polarised transport physics remains unresolved.
Evidence basis: single_reference
Caveat: The cited OSV is by the review authors and is still interpreted cautiously in the review.
1396 · Magnetic properties · Figure 6
The review attributes many electronic performances of 2D c-MOFs to in-plane pi-d conjugation and charge delocalisation across planar metal-ligand frameworks.
Evidence basis: multi_reference
Caveat: Extent of delocalisation varies by material quality and dimensionality.
1392 · Introduction
Most reported 2D c-MOF samples are polycrystalline powders with short-range order, limiting intrinsic single-layer and transport interpretation.
Evidence basis: review_reasoning
Caveat: This is an outlook-level synthesis across the literature.
1398 · Challenges and opportunities
Radical-based redox ligands provide a route to couple magnetic ordering, conductivity and porosity in 2D c-MOFs.
Evidence basis: multi_reference
Caveat: Absolute conductivity and ordering temperatures vary substantially by framework and redox state.
1394 · Magnetic properties
Smaller benzene-core linkers are associated with higher conductivity and possible metallic behaviour through better electronic wave-function overlap.
Evidence basis: multi_reference
Caveat: The review notes anisotropy and grain-boundary effects in these systems.
1393 · Electrical properties
A profound understanding of spin mechanisms in 2D c-MOFs is missing because of complex components and extended framework structures.
Evidence basis: multi_reference
Caveat: Theoretical and molecular-model work is available but not yet sufficient.
1396 · Magnetic properties
The greatest synthetic challenge is controlling ordering and stacked layers in 2D frameworks because ordered structures reduce charge/spin transport barriers.
Evidence basis: review_reasoning
Caveat: The review frames this as a broad outlook statement rather than a single-study result.
1398 · Challenges and opportunities
Temperature-dependent conductivity is used as a heuristic to distinguish hopping semiconducting behaviour from band-like transport, but later caveats show this is insufficient alone.
Evidence basis: multi_reference
Caveat: The review explicitly says conventional conductivity can be insufficient for charge-transport assignment.
1392 · Electrical properties
For most 2D c-MOFs, through-bond transport via metal d orbitals and ligand pi systems is treated as the dominant pathway.
Evidence basis: multi_reference
Caveat: Through-space transport may occur in compact pi-pi stacks but is rarely observed in 2D MOFs.
1392 · Electrical properties
Through-space charge transport is underexplored in 2D MOFs because compact stacked orbital-overlap pathways are structurally complex.
Evidence basis: single_reference
Caveat: The statement is a review-level inference from scarcity rather than a direct proof of absence.
1392 · Electrical properties
For 2D c-MOF topological insulators, controllable oxidation state and diverse frameworks are presented as advantages for controlling doping and electronic structure.
Evidence basis: multi_reference
Caveat: Much of the TI discussion is theoretical or potential-oriented.
1398 · Topological insulator
Every row remains visibly secondary and links to a primary dossier only where the mapping is verified.
| Material | Property | Reported value | Context and quality | Primary evidence | Review source |
|---|---|---|---|---|---|
| SecondaryCu-BHT film | electrical conductivity | up to 1,580 S cm-1 | ambient conditions; thin film Text · Exact Reported | research_0006 | 1393 · Electrical properties |
| SecondaryCu3(C6O6)2 | activation energy | about 0.46 eV | semiconducting behaviour from temperature-dependent conductivity Text · Approximate | research_0792 | 1393 · Electrical properties |
| SecondaryCu3(HIB)2 pellet | conductivity | 1,300 S m-1 | 300 K under vacuum; pellet Text · Exact Reported | No verified corpus mapping | 1393 · Electrical properties · Figure 2 |
| SecondaryCu-BHT films | superconducting Tc | Tc=0.25 K | electrical resistivity, magnetic susceptibility and heat capacity; films Text · Exact Reported | No verified corpus mapping | 1397 · Superconductor · Figure 7 |
| SecondaryCu-BHT monolayer | calculated superconducting Tc | 4.43 K | calculated BCS superconductor; monolayer Text · Exact Reported | No verified corpus mapping | 1397 · Superconductor · Figure 7 |
| Secondary(Me2NH2)2[Fe2L3] | magnetic ordering transition temperature | Tc of 80 K | pristine tetraoxolene radical-based magnet Text · Exact Reported | No verified corpus mapping | 1395 · Magnetic properties |
| SecondaryFe3(THT)2(NH4)3 film | mobility | ~220 cm2 V-1 s-1 | room temperature; TRTS and Hall effect used to demonstrate band-like transport Text · Approximate | research_0001 | 1393 · Electrical properties |
| SecondaryFe-THT | conductivity | 0.2 S cm-1 | 300 K; high-quality Fe-THT Text · Exact Reported | No verified corpus mapping | 1394 · Electrical properties · Figure 2 |
| SecondaryK3Fe2[PcFe-O8] | mobility | about 15 cm2 V-1 s-1 | room temperature; TRTS measurements Text · Approximate | research_0267 | 1396 · Magnetic properties · Figure 5 |
| SecondaryMn benzoquinoid framework | conductivity increase after reduction | 200,000-fold | 295 K; pristine to reduced framework Text · Exact Reported | No verified corpus mapping | 1395 · Magnetic properties · Figure 4 |
| SecondaryNi3(HIB)2 pellet | conductivity | 800 S m-1 | 300 K under vacuum; pellet Text · Exact Reported | No verified corpus mapping | 1393 · Electrical properties · Figure 2 |
| SecondaryNi3(HITP)2 FET | hole mobility | ~48.6 cm2 V-1 s-1 | Ni3(HITP)2-based FET; holes primary carriers Text · Approximate | research_0015 | 1392 · Electrical properties · Figure 1 |
| SecondaryNi3(HITP)2 FET | current on/off ratio | 2x10^3 | Ni3(HITP)2-based FET Text · Exact Reported | research_0015 | 1392 · Electrical properties · Figure 1 |
| SecondaryNi3(HITP)2 film | room-temperature conductivity | 40 S cm-1 | room temperature; van der Pauw method; film Text · Exact Reported | No verified corpus mapping | 1392 · Electrical properties · Figure 1 |
| Secondaryoxidized NiDT | conductivity | 1.6x10^2 S cm-1 | 300 K; van der Pauw method; oxidized NiDT Text · Exact Reported | research_0361 | 1398 · Topological insulator · Figure 8 |
| SecondaryLSMO/Cu3HHTP2/Co OSV | magnetoresistance | negative MR of 25% | 10 K; Cu3HHTP2 approximately 100 nm layer Text · Exact Reported | research_0129 | 1396 · Magnetic properties · Figure 6 |
| SecondaryPTC-Fe pellets | room-temperature conductivity | up to 10 S cm-1 | room temperature; pellets; semiconducting feature Text · Exact Reported | research_0045 | 1395 · Magnetic properties · Figure 5 |
| SecondaryPtDT single layer | calculated Dirac gap | 0.054 eV | band structure calculation; oxidized PtDT TI potential Text · Exact Reported | No verified corpus mapping | 1398 · Topological insulator |
| Secondary(Cp2Co)1.43(Me2NH2)1.57[Fe2L3] | magnetic ordering transition temperature | up to 105 K | post-synthetically reduced framework Text · Exact Reported | No verified corpus mapping | 1395 · Magnetic properties |
Open questions are presented as review-author priorities, not conclusions from the primary database.
Intrinsic mechanisms for charge/spin transport among intralayer and interlayer pathways remain elusive.
Proposed direction: Combine conductivity, FP-TRMC, TRTS, UPS, Hall, Seebeck and theoretical calculations with better structural characterisation.
1399 · Challenges and opportunities
Device fabrication procedures must be improved for future electronic and spintronic applications.
Proposed direction: Prepare higher-quality thin films and heterostructured COF-MOF or MOF-MOF composite films for multifunctional devices.
1400 · Challenges and opportunities
Immature film processing and small granular nanoparticles impede 2D c-MOF device development.
Proposed direction: Improve interfacial synthesis, liquid-phase epitaxy, electrochemical deposition and solvo/hydrothermal film-processing routes.
1399 · Challenges and opportunities
Temperature-dependent conductivity alone is not proper for evaluating intrinsic electrical properties in granular samples.
Proposed direction: Prioritise single crystals, molecular models and multi-probe electronic-structure measurements.
1399 · Challenges and opportunities
Control of ordering and stacked layers is identified as the greatest synthetic challenge for 2D frameworks.
Proposed direction: Optimise additives, solvent, metal precursors, feed sequence, concentration, atmosphere, pressure and reaction time for larger single crystals and better ordered layers.
1398 · Challenges and opportunities
2D c-MOF performance remains modest relative to state-of-the-art inorganic 2D materials with higher-temperature superconductivity or room-temperature magnetic ordering.
Proposed direction: Increase ligand conjugation, tune redox-active groups and ligand cores, and introduce lanthanide or 4d/5d metals for new functions.
1399 · Challenges and opportunities
The review says the clear illustration of the second superconducting phase of Cu-BHT is missing.
Proposed direction: Use higher-quality single/few-layer samples and complementary superconductivity measurements to assign the second phase.
1399 · Challenges and opportunities
Only few 2D c-MOFs have been prepared as highly crystalline atomic-thickness nanosheets, so intrinsic single-layer properties remain limited.
Proposed direction: Develop exfoliation, liquid-air interfacial synthesis and chemical vapour deposition routes for atom-thick 2D c-MOFs on substrates.
1399 · Challenges and opportunities
Coordination-bond instability and redox-active groups limit use under harsh conditions and can cause air sensitivity.
Proposed direction: Design more robust coordination environments and account for air/redox effects during processing and measurement.
1399 · Challenges and opportunities
Transport pathways depend on crystal structure, but polycrystalline powders often require indirect structure determination aided by simulations.
Proposed direction: Grow single crystals for diffraction and in-plane/out-of-plane transport measurements; use XRD, XAFS and HR-TEM with simulations for powders.
1399 · Challenges and opportunities
Mappings show which printed review references have a verified counterpart in the frozen primary corpus.
| Reference | Study | Role and context | Corpus mapping |
|---|---|---|---|
| Ref. 332019 | Title unavailable | structure_property_context · metallic_chalcogen_frameworkUsed for pi-d conjugation/chalcogen framework context and Cu-BHS metallic analogue discussion. | Unmapped |
| Ref. 372016 | Title unavailable | transport_framework · review_contextSupports transport-mechanism framing and temperature-dependent transport interpretation. | Unmapped |
| Ref. 402020 | Title unavailable | through_space_contextCited for through-space charge transport context and its relative scarcity in 2D MOFs. | research_0047 |
| Ref. 422014 | Title unavailable | transport_benchmark · semiconductorFirst semiconductive 2D conjugated MOF example with room-temperature film conductivity. | Unmapped |
| Ref. 432017 | Title unavailable | device_benchmark · thin_filmAir-liquid interfacial Ni3(HITP)2 membrane and FET mobility/on-off benchmark. | research_0015 |
| Ref. 452018 | Title unavailable | transport_benchmark · semiconductorUsed for Cu3(C6O6)2 activation energy and bandgap benchmark. | research_0792 |
| Ref. 462018 | Title unavailable | transport_benchmark · measurement_caveatBand-like transport case where TRTS and Hall measurements are needed beyond conventional conductivity. | research_0001 |
| Ref. 472017 | Title unavailable | transport_benchmark · metallic_anisotropyBenzene-core HIB conductivity and UPS/DFT anisotropic electronic behaviour. | Unmapped |
| Ref. 482015 | Title unavailable | transport_benchmark · metallic_behaviourCu-BHT thin-film high conductivity, ambipolar transport and metallic-behaviour evidence. | research_0006 |
| Ref. 492017 | Title unavailable | metallic_transitionCo-THT metallic transition behaviour upon cooling. | Unmapped |
| Ref. 502019 | Title unavailable | transport_benchmark · redox_environmentFe-THT conductivity and air-oxidation-modulated semiconducting-to-metallic transition. | Unmapped |
| Ref. 522019 | Title unavailable | single_crystal · measurement_caveatSingle-crystal growth and grain-boundary caveat for intrinsic transport interpretation. | Unmapped |
| Ref. 532016 | Title unavailable | theory · dimensionalityDFT dimensionality effect: sheet versus bulk transport character. | Unmapped |
| Ref. 622015 | Title unavailable | magnetic_benchmark · porous_magnetFirst structurally characterised tetraoxolene radical-based magnet in the review. | Unmapped |
| Ref. 632017 | Title unavailable | magnetic_benchmark · redox_switchingPost-synthetic reduction increasing intralayer spin coupling and Tc. | Unmapped |
| Ref. 642019 | Title unavailable | magnetic_benchmark · redox_switchingRedox-switchable manganese framework with conductivity and magnetism change. | Unmapped |
| Ref. 662018 | Title unavailable | ferromagnetic_semiconductor · transport_benchmarkPTC-Fe ferromagnetic semiconductor with high room-temperature conductivity. | research_0045 |
| Ref. 682019 | Title unavailable | magnetic_transport · mobility_benchmarkLayered phthalocyanine MOF with mobility, negative MR and high-temperature magnetic correlations. | research_0267 |
| Ref. 692020 | Title unavailable | magnetic_transport · selenol_frameworkCo-TPHS triphenylenehexaselenol framework with semiconductive behaviour and glassy magnetism after air exposure. | Unmapped |
| Ref. 702019 | Title unavailable | film_synthesis · magnetismVapour-induced conversion approach to conductive ferromagnetic Ni3(HITP)2 film. | Unmapped |
| Ref. 712019 | Title unavailable | redox_magnetism · semiconductorI2-doped NiTAA-MOF showing ligand-oxidation effects on magnetic and semiconducting behaviour. | Unmapped |
| Ref. 722020 | Title unavailable | spin_valve · device_benchmarkFirst 2D c-MOF organic spin valve cited by the review. | research_0129 |
| Ref. 732016 | Title unavailable | spin_theoryRepresentative theoretical spin study noted before the review states mechanisms remain unresolved. | Unmapped |
| Ref. 762019 | Title unavailable | molecular_model · spin_mechanismMolecular model compounds for intrinsic spin state and redox mechanism insight. | research_0148 |
| Ref. 822017 | Title unavailable | superconductor_theory · quantum_materialTheoretical Cu-BHT superconductivity calculations. | Unmapped |
| Ref. 832018 | Title unavailable | superconductor_benchmark · crystallinityExperimental Cu-BHT nanoplate superconductivity and high crystallinity. | Unmapped |
| Ref. 882013 | Title unavailable | topological_insulator_theoryTheoretical nontrivial topological states in 2D Ni3(BHT)2. | Unmapped |
| Ref. 892014 | Title unavailable | topological_insulator_theoryQSH effect and Z2 metallic states in electron-doped Ni3(HITP)2 monolayer. | Unmapped |
| Ref. 912013 | Title unavailable | interfacial_synthesis · redox_controlBottom-up interfacial synthesis of pi-conjugated nickel bis(dithiolene) nanosheets. | Unmapped |
| Ref. 922014 | Title unavailable | redox_control · topological_insulator_contextRedox control of NiDT with oxidised conductivity benchmark and metallic/semiconductor discrepancy. | research_0361 |
| Ref. 932019 | Title unavailable | topological_insulator_context · heavy_atom_effectPlatinum dithiolato analogue showing heavy-atom/SOC topological-insulator potential. | Unmapped |
| Ref. 942019 | Title unavailable | synthesis_contextUsed for top-down versus bottom-up synthesis framing in the outlook. | Unmapped |