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Mn₂(DSBDC)

This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.

6primary papers
9material records
42linked samples
80linked measurements
362linked results
2013–2025publication span

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6 papers

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Show 9 material identity records
Paper and reported nameFormula and componentsStructure contextSource
Mn2(DSBDC)2025 · Computational Modelling of Lead Free FASnI2Br with Copper-Doped Strontium Titanate and Conductive Metal-Organic Frameworks as Charge Transport LayersMn2(DSBDC)Mn nodes · 2,5-disulfidobenzene-1,4-dicarboxylate (DSBDC)unknown · Model Systemconductive MOF HTL model inputp001 · Introduction
Mn2(DSBDC)2024 · Emerging class of SrZrS3 chalcogenide perovskite solar cells: Conductive MOFs as HTLs - A game changer?Mn2(DSBDC)Mn nodes; infinite (-Mn-S-) chains cited in references · DSBDC4- = 2,5-disulfidobenzene-1,4-dicarboxylate3D · Model Systemmicroporous conductive MOF with DSBDC linker2 · 1. Introduction
Co@Mn2DSBDC2021 · Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivityCo-exchanged Mn2DSBDC, ca. 10.2 at% Co with respect to Mn by XRFMostly Mn2+ nodes with partial Co2+ substitution · DSBDC = 2,5-dimercaptoterephthalate3D · PristineCation-exchanged analogue retaining the Mn2DSBDC crystal structure by pXRD; local Co environment modelled as octahedral O/S coordination.3 · 3.1 Structure, synthesis, and characterization · Fig. 2; Table S1
Cu@Mn2DSBDC2021 · Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivityCu-exchanged Mn2DSBDC, ca. 8.2 at% Cu with respect to Mn by XRFMostly Mn2+ nodes with partial Cu2+ substitution · DSBDC = 2,5-dimercaptoterephthalate3D · PristineCation-exchanged analogue retaining the Mn2DSBDC crystal structure by pXRD; Cu assigned to S-coordinated sites from XANES.5 · 3.2 X-ray absorption spectroscopy · Fig. 4
Mn2DSBDC2021 · Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivityMn2(2,5-dimercaptoterephthalate); reported as Mn2DSBDCMn2+ centres in continuous alternating Mn1/Mn2 chains · DSBDC = 2,5-dimercaptoterephthalate3D · PristineMicroporous MOF with hexagonal pores and continuous Mn-S-Mn-S chains; as-prepared material has DMF coordinated to Mn2 sites.3 · 3.1 Structure, synthesis, and characterization · Fig. 1
Ni@Mn2DSBDC2021 · Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivityNi-exchanged Mn2DSBDC, ca. 7.5 at% Ni with respect to Mn by XRFMostly Mn2+ nodes with partial Ni2+ substitution · DSBDC = 2,5-dimercaptoterephthalate3D · PristineCation-exchanged analogue retaining the Mn2DSBDC crystal structure by pXRD; Ni local environment modelled as octahedral O/S coordination with a second-shell Ni-X feature.6 · 3.2 X-ray absorption spectroscopy · Fig. 5; Table 2
Mn2(DSBDC)(DMF)22017 · Is iron unique in promoting electrical conductivity in MOFs?Mn2(DSBDC)(DMF)2Mn2+ · DSBDC; DMF-coordinated3D · Pristinehoneycomb structure with 1D tubular pores4451 · Experimental results · Fig. 1
Mn2(DSBDC)2015 · Million-fold electrical conductivity enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O)Mn2(DSBDC)(DMF)2.x(DMF) and Mn2(DSBDC)(DMF)2 sample statesMn2+ chains, (-Mn-S-)inf secondary building units · DSBDC4- = 2,5-disulfhydrylbenzene-1,4-dicarboxylate3D · PristineMOF-74 analogue; topologically related to Fe2(DSBDC) but with two distinct Mn sites in the asymmetric unit.6164 · main text · Figure 1a
Mn2(DSBDC)2013 · Mn2(2,5-disulfhydrylbenzene-1,4-dicarboxylate): A microporous metal-organic framework with infinite (-Mn-S-)∞ chains and high intrinsic charge mobilityMn2(C8H2O4S2), activated framework; as-synthesized phase [Mn2(DSBDC)(DMF)2].0.2DMFInfinite one-dimensional Mn2+ chains bridged by thiophenoxide sulfur and carboxylate oxygen atoms · DSBDC4- from 2,5-disulfhydrylbenzene-1,4-dicarboxylic acid (H4DSBDC)3D · PristineTrigonal R-3c framework related to M2(DOBDC), containing linear (-Mn-S-)inf chains and hexagonal one-dimensional pores along the c axis.main p.8186 · Main text, structure discussion · Figures 2-3