Defect Engineering to Tailor Metal Vacancies in 2D Conductive Metal-Organic Frameworks: An Example in Electrochemical Sensing
Luo Y., Wu Y., Braun A. et al. · ACS Nano · 2022
Reported here: Ni-BHT
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4 papers
Luo Y., Wu Y., Braun A. et al. · ACS Nano · 2022
Reported here: Ni-BHT
Deng T., Yong X., Shi W. et al. · Advanced Electronic Materials · 2019
Reported here: 2D single-layer pi-conjugated nickel bis(dithiolene) complex
Liu H., Li X., Shi C. et al. · Physical Chemistry Chemical Physics · 2018
Reported here: two-dimensional NiDT metal bis(dithiolene) nanosheet
Kambe T., Sakamoto R., Kusamoto T. et al. · Journal of the American Chemical Society · 2014
Reported here: Nickel bis(dithiolene) complex pi-nanosheet 1
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| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Ni-BHT2022 · Defect Engineering to Tailor Metal Vacancies in 2D Conductive Metal-Organic Frameworks: An Example in Electrochemical Sensing | Ni3BHT / porous Kagome-type Ni-BHT, composition varies with pHNi centres; Ni vacancies inferred from pH-dependent elemental composition · benzenehexathiolato (BHT) | 2D · Pristine2D conductive metal-BHT polymer film; monolayer Ni-BHT structure and XRD pattern shown in SI Figure S19. | 20825 · Results and Discussion · Figure S19 and Table S2 |
| 2D single-layer pi-conjugated nickel bis(dithiolene) complex2019 · 2D Single-Layer π-Conjugated Nickel Bis(dithiolene) Complex: A Good-Electron-Poor-Phonon Thermoelectric Material | (NiC4S4)nplanar nickel tetrasulfide NiS4 groups · dithiolene / benzenehexathiol-derived pi-conjugated sulfur-carbon network | 2D · Model Systemmonolayer 2D coordination polymer / pi-conjugated nickel bis(dithiolene) nanosheet with microporous crystal structure and Kagome conduction bands | 2 · Introduction |
| two-dimensional NiDT metal bis(dithiolene) nanosheet2018 · First-principles prediction of two-dimensional metal bis(dithiolene) complexes as promising gas sensors | NiDT; 2D metal bis(dithiolene) complex with benzenehexathiol-derived dithiolene linkersNi centres in square-planar metal-dithiolene coordination · benzenehexathiol/benzenehexathiolate-derived bis(dithiolene) network | 2D · Model SystemCalculated 2D MDT kagome-type lattice; each metal atom adopts dsp2 hybridisation and a square-planar coordination mode. | p003 · Results and discussion, Geometric properties and adsorption mechanisms · Fig. 1 / text |
| Nickel bis(dithiolene) complex pi-nanosheet 12014 · Redox control and high conductivity of nickel bis(dithiolene) complex π-nanosheet: A potential organic two-dimensional topological insulator | Nickel bis(dithiolene) complex nanosheet; exact empirical formula not reported in this paperNickel bis(dithiolene) complex units with Ni-S coordination in a pi-conjugated framework · Benzenehexathiol-derived phenylene/dithiolene linkers | 2D · PristineSingle-layer nickel bis(dithiolene) complex nanosheets forming a hexagonal kagome lattice; handled here as stacked nanosheets called 1. | main p.1, article p.14357 · Introduction · Figure 1 |