cMOF Evidence Base
Diffraction Structure — Electron delocalization and charge mobility as a function of reduction in a metal-organic framework

Measurement evidence

Diffraction Structure

Electron delocalization and charge mobility as a function of reduction in a metal-organic framework · Aubrey M.L., Wiers B.M., Andrews S.C. et al. · Nature Materials · 2018 · 625-632

1 measurement group · 1 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Synchrotron powder X-ray diffraction with Le Bail refinement

X-ray diffraction and scattering

Bulk KxFe2(BDP)3 powder series · Powder

Beamline 17-BM-B, lambda = 0.72959 A; solvated samples sealed in borosilicate capillaries under nitrogen.

Atmosphere
nitrogen glovebox; flame-sealed capillaries
Context
Reduced bulk powder compared with pristine Fe2(BDP)3.
Measurement source
main p.3, article p.627 · Synthesis and spectroscopic properties · Fig. 2a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
PXRD preservation of crystal structure after K reductionPXRD data revealed that the reaction is topotactic for all levels of reduction.——Text
Qualitative		main p.2, article p.626 · Synthesis and spectroscopic properties · Fig. 2a