Electrochemistry Application — Electron delocalization and charge mobility as a function of reduction in a metal-organic framework

Measurement evidence

Electrochemistry Application

Electron delocalization and charge mobility as a function of reduction in a metal-organic framework · Aubrey M.L., Wiers B.M., Andrews S.C. et al. · Nature Materials · 2018 · 625-632

1 measurement group · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Slow-scan cyclic voltammetry

Fe2(BDP)3 composite working electrode for cyclic voltammetry · Electrode

0.1 M K(TFSI) in anhydrous propylene carbonate; potassium reference/counter; scan shown at 10 uV s-1.

Atmosphere: argon glovebox
Geometry: custom perfluoroalkoxy ethane T-cell; composite electrode on carbon cloth
Context: Composite electrode containing pristine Fe2(BDP)3 active phase.
Measurement source: main p.4, article p.628 · Electrochemical properties · Fig. 3b; Fig. S8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Comproportionation constant for charge-delocalized state	Kc = 2 x 10^14	—	—	Text Rounded Reported	main p.4, article p.628 · Electrochemical properties · Fig. 3b
Separation between first two reductive peaks	0.80 V	—	—	Text Rounded Reported	main p.4, article p.628 · Electrochemical properties · Fig. 3b
First CV phase transition end composition	linear decrease in potential with potassium insertion up to x approximately 1.1	—	approximately	Text Approximate	main p.4, article p.628 · Electrochemical properties · Fig. S8