Porosity — Electron delocalization and charge mobility as a function of reduction in a metal-organic framework

Measurement evidence

Porosity

Electron delocalization and charge mobility as a function of reduction in a metal-organic framework · Aubrey M.L., Wiers B.M., Andrews S.C. et al. · Nature Materials · 2018 · 625-632

1 measurement group · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Nitrogen adsorption isotherms and BET surface area

Gas sorption and porosity

Bulk KxFe2(BDP)3 powder series · Powder

Samples activated under evacuation to 180 C; N2 adsorption at 77 K.

Temperature: 77
Atmosphere: nitrogen handling before activation
Context: Pristine and potassium-reduced bulk powders.
Measurement source: main p.2, article p.626 · Synthesis and spectroscopic properties · Fig. 2b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of Fe2(BDP)3Marked as a best value within this paper	1,230 m2 g-1	—	—	Text Rounded Reported	main p.2, article p.626 · Synthesis and spectroscopic properties · Fig. 1a,b
BET surface area of K0.9Fe2(BDP)3	610 m2 g-1	—	—	Text Rounded Reported	main p.2, article p.626 · Synthesis and spectroscopic properties · Fig. 2b
BET surface area of K1.1Fe2(BDP)3	430 m2 g-1	—	—	Text Rounded Reported	main p.2, article p.626 · Synthesis and spectroscopic properties · Fig. 2b