Porosity — Redox-Active Mixed-Linker Metal–Organic Frameworks with Switchable Semiconductive Characteristics for Tailorable Chemiresistive Sensing

Measurement evidence

Porosity

Redox-Active Mixed-Linker Metal–Organic Frameworks with Switchable Semiconductive Characteristics for Tailorable Chemiresistive Sensing · Zhou X.-C., Liu C., Su J. et al. · Angewandte Chemie - International Edition · 2023 · e202211850

1 measurement group · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption-desorption isotherms; BET surface area; pore size distribution

Gas sorption and porosity

Mn2[TTF]x[NiS4]1-x powder series · Powder

N2 sorption at 77 K; Mn2[TTF] degassed at 200 C for 24 h, other samples degassed at 180 C for 24 h under vacuum.

Temperature: 77
Atmosphere: N2; vacuum activation before measurement
Geometry: powder
Context: pristine_framework
Measurement source: 5 · Porosity and specific surface area analysis · Figure 2d; Figure S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of Mn2[NiS4]	398	—	—	Text Exact Reported	3 · Results and Discussion · Figure 2d
BET surface area of Mn2[TTF]Marked as a best value within this paper	528	—	—	Text Exact Reported	3 · Results and Discussion · Figure 2d
BET surface area of Mn2[TTF]0.24[NiS4]0.76	431	—	—	Text Exact Reported	3 · Results and Discussion · Figure 2d
BET surface area of Mn2[TTF]0.49[NiS4]0.51	451	—	—	Text Exact Reported	3 · Results and Discussion · Figure 2d
BET surface area of Mn2[TTF]0.78[NiS4]0.22	433	—	—	Text Exact Reported	3 · Results and Discussion · Figure 2d
pore-width distribution peak of Mn2[NiS4]	0.69 nm	—	—	Figure Axis Approximate	12 · Results and Discussion · Figure S11
pore-width distribution peak of Mn2[TTF]	0.59 nm	—	—	Figure Axis Approximate	12 · Results and Discussion · Figure S11
pore-width distribution peak of Mn2[TTF]0.24[NiS4]0.76	0.65 nm	—	—	Figure Axis Approximate	12 · Results and Discussion · Figure S11
pore-width distribution peak of Mn2[TTF]0.49[NiS4]0.51	0.65 nm	—	—	Figure Axis Approximate	12 · Results and Discussion · Figure S11
pore-width distribution peak of Mn2[TTF]0.78[NiS4]0.22	0.60 nm	—	—	Figure Axis Approximate	12 · Results and Discussion · Figure S11
N2 isotherm type	type I isotherm	—	—	Text Qualitative	3 · Results and Discussion · Figure 2d