Spectroscopy — Redox-Active Mixed-Linker Metal–Organic Frameworks with Switchable Semiconductive Characteristics for Tailorable Chemiresistive Sensing

Measurement evidence

Spectroscopy

Redox-Active Mixed-Linker Metal–Organic Frameworks with Switchable Semiconductive Characteristics for Tailorable Chemiresistive Sensing · Zhou X.-C., Liu C., Su J. et al. · Angewandte Chemie - International Edition · 2023 · e202211850

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FT-IR and Raman spectroscopy

Mn2[TTF]x[NiS4]1-x powder series · Powder

FT-IR through KBr pellets (4000-400 cm-1); Raman spectra of the series and linkers.

Geometry
ground crystals/KBr pellet for FT-IR
Context
pristine_framework
Measurement source
4 · Materials and Methods · Figures S6-S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
FT-IR Ni-bis(dithiolene) bandpeak at 1352 cm-1 grows with [NiS4] concentrationText
Rounded Reported
3 · Results and Discussion · Figure S6
Raman Ni-S bandpeak near 380 cm-1 becomes stronger with [NiS4] ratioCaption
Approximate
9 · Results and Discussion · Figure S7