Sensing Application — Adjustable Synthesis of Ni-Based Metal-Organic Framework Membranes and Their Field-Effect Transistor Sensors for Mercury Detection

Measurement evidence

Sensing Application

Adjustable Synthesis of Ni-Based Metal-Organic Framework Membranes and Their Field-Effect Transistor Sensors for Mercury Detection · Shen S., Tan P., Tang Y. et al. · ACS Applied Electronic Materials · 2022 · 622-630

7 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

comparative Hg2+ sensing controls

S4-based unmodified Ni3(HITP)2 FET sensor control · Electrode

Ni3(HITP)2, Ni3(HITP)2-GA and Ni3(HITP)2-DNA FET sensors tested with 10 pM to 100 nM Hg2+ sequence.

Atmosphere
PBS solution
Geometry
FET liquid cell
Context
unmodified, GA-only and DNA-only S4 controls
Measurement source
S-11 · Figure S9 caption · Figure S9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Ni3(HITP)2-DNA control responseresponds to Hg2+ ions to some degreeText
Qualitative
627 · 3.2. Hg2+ Sensing Performance · Figure S9
Ni3(HITP)2 and Ni3(HITP)2-GA control responsealmost no response to Hg2+Text
Qualitative
627 · 3.2. Hg2+ Sensing Performance · Figure S9

liquid-gated FET Hg2+ sensing by drain-current change

S1-based Ni3(HITP)2-GA-DNA FET sensor · Electrode

15 uL PBS blank followed by 15 uL Hg2+ solutions from 10 pM to 100 nM; Vgs = -0.1 V and Vds = -0.1 V at room temperature.

Atmosphere
PBS solution, room temperature
Geometry
silicon rubber liquid cell on FET channel
Context
GA-DNA-functionalised S1 membrane sensor
Measurement source
624 · 2.6. Sensing Test · Figure 6a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
S1 Hg2+ final current responsedrain current increases transiently then returns to the initial current value; final current response almost no change with concentrationText
Qualitative
627 · 3.2. Hg2+ Sensing Performance · Figure 6a

liquid-gated FET Hg2+ sensing by drain-current change

S2-based Ni3(HITP)2-GA-DNA FET sensor · Electrode

15 uL PBS blank followed by 15 uL Hg2+ solutions from 10 pM to 100 nM; Vgs = -0.1 V and Vds = -0.1 V at room temperature.

Atmosphere
PBS solution, room temperature
Geometry
silicon rubber liquid cell on FET channel
Context
GA-DNA-functionalised S2 membrane sensor
Measurement source
627 · 3.2. Hg2+ Sensing Performance · Figure 6b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
S2 Hg2+ final current responsedrain current increases transiently then returns to the initial current value; final current response almost no change with concentrationText
Qualitative
627 · 3.2. Hg2+ Sensing Performance · Figure 6b

liquid-gated FET Hg2+ sensing by drain-current change

S3-based Ni3(HITP)2-GA-DNA FET sensor · Electrode

15 uL PBS blank followed by 15 uL Hg2+ solutions from 10 pM to 100 nM; Vgs = -0.1 V and Vds = -0.1 V at room temperature.

Atmosphere
PBS solution, room temperature
Geometry
silicon rubber liquid cell on FET channel
Context
GA-DNA-functionalised S3 membrane sensor
Measurement source
627 · 3.2. Hg2+ Sensing Performance · Figure 6c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
S3 Hg2+ response magnitudecurrent change is less than 1 uA after adding Hg2+less thanText
Approximate
627 · 3.2. Hg2+ Sensing Performance · Figure 6c

liquid-gated FET Hg2+ sensing by drain-current change

S4-based Ni3(HITP)2-GA-DNA FET sensor · Electrode

15 uL PBS blank followed by 15 uL Hg2+ solutions from 10 pM to 100 nM; Vgs = -0.1 V and Vds = -0.1 V at room temperature.

Atmosphere
PBS solution, room temperature
Geometry
silicon rubber liquid cell on FET channel
Context
GA-DNA-functionalised S4 membrane sensor
Measurement source
627 · 3.2. Hg2+ Sensing Performance · Figures 6d and 7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
S4 upper end of linear Hg2+ detection rangeMarked as a best value within this paper100 nM1e-7 MText
Exact Reported
627 · 3.2. Hg2+ Sensing Performance · Figure 7
S4 lower end of linear Hg2+ detection rangeMarked as a best value within this paper10 pM1e-11 MText
Exact Reported
627 · 3.2. Hg2+ Sensing Performance · Figure 7
S4 calibration intercept in plotted fitMarked as a best value within this paperY = 1.32X + 16.78Figure Axis
Exact Reported
627 · Figure 7 · Figure 7
S4 calibration R2Marked as a best value within this paperR2 = 0.981Figure Axis
Exact Reported
627 · Figure 7 · Figure 7
S4 calibration slope in plotted fitMarked as a best value within this paperY = 1.32X + 16.78Figure Axis
Exact Reported
627 · Figure 7 · Figure 7
S4 current response at 100 nM Hg2+Marked as a best value within this paperabout 7.5 uA from Figure 7 point/fitaboutVisual Estimate
Approximate
627 · Figure 7 · Figure 7
S4 current response at 10 pM Hg2+about 2.3 uA from Figure 7 point/fitaboutVisual Estimate
Approximate
627 · Figure 7 · Figure 7

reusability/stability test

S4-based Ni3(HITP)2-GA-DNA FET sensor · Electrode

Sensor stored at 0-4 deg C and retested after 26 h.

Atmosphere
PBS solution; storage at 0-4 deg C
Geometry
FET liquid cell
Context
GA-DNA-functionalised S4 membrane sensor
Measurement source
S-12 · Figure S10 caption · Figure S10
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Reusability after 26 hperformance degradation; sensor is only used as a one-time-use sensorText
Qualitative
627 · 3.2. Hg2+ Sensing Performance · Figure S10

selectivity test by liquid-gated FET current response

S4-based Ni3(HITP)2-GA-DNA FET sensor · Electrode

10 mM Cu2+, Cd2+, Pb2+, Zn2+, Mg2+ and Co2+ nontarget ions compared with 10 pM Hg2+; 15 uL aliquots in PBS.

Atmosphere
PBS solution
Geometry
silicon rubber liquid cell on FET channel
Context
GA-DNA-functionalised S4 membrane sensor
Measurement source
627 · 3.2. Hg2+ Sensing Performance · Figure 8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Target Hg2+ selectivity response concentrationMarked as a best value within this paper10 pM Hg2+ gives significant drain-current change1e-11 MText
Exact Reported
627 · 3.2. Hg2+ Sensing Performance · Figure 8
Estimated Figure 8 Hg2+ current responseMarked as a best value within this paperabout 3.4 uA at 10 pM Hg2+aboutVisual Estimate
Approximate
627 · Figure 8 · Figure 8
Nontarget-ion responsealmost no change or only a slight change for 10 mM Cu2+, Cd2+, Pb2+, Zn2+, Mg2+ and Co2+Text
Qualitative
627 · 3.2. Hg2+ Sensing Performance · Figure 8