Miao M., Wang Z., Guo Z. et al. · Advanced Materials Interfaces · 2022 · 2101908
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The mild in situ route can directly synthesise TOM-Cu3(HITP)2 on desired substrates without a transfer process.
Caveat: Demonstrated on commercial ceramic-based gold IDE and adapted to quartz/glass for characterisation; broader substrate universality is asserted rather than systematically screened.
p004 · 2.2 Morphology · Figure S1 · Linked to 2 structured results
The paper identifies Cu3(HITP)2 as an electrically conductive MOF but does not report a standalone film conductivity, mobility, Seebeck coefficient, or electrochemical conductivity value in the assigned documents.
Caveat: Electrical evidence in this paper is chemiresistive H2S sensor resistance/response rather than intrinsic transport metrology.
p002-p006 · Introduction / 2.5 H2S gas sensor · Figure 3h
TOM-Cu3(HITP)2 film and ordinary Cu3(HITP)2 MOF are assigned as the same Cu3(HITP)2 substance, with slight differences in superficial Cu(I) contents and crystallinity.
Caveat: No CIF or Rietveld refinement is provided; TOM film peaks are broader and weaker.
p006 · 2.4 Spectroscopic Analysis · Figure 3; Table S1 · Linked to 6 structured results
The TOM-micropore hierarchical structure dramatically improves room-temperature H2S sensitivity by facilitating gas mass transfer and exposure of active sites.
Caveat: Application comparison is made against a no-template Raw-Cu3(HITP)2 film; standalone conductivity and selectivity data are not reported in the assigned documents.
p006 · 2.5 H2S gas sensor · Figure 3h · Linked to 4 structured results
The quasi solid-liquid strategy transforms solid HATP aggregation within the PS template into water-insoluble Cu3(HITP)2 aggregation rapidly enough to retain the original TOM morphology.
Caveat: Mechanism is inferred from morphology retention and chemical reaction scheme, not time-resolved spectroscopy.
p003 · 2.1 In Situ Synthesis · Scheme 1; Mechanism S1 · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu3(HITP)2 metal-organic frameworkBrowse family: Cu₃(HITP)₂ / Cu–HITP | Cu3(HITP)2Cu ions coordinated to HITP-derived N sites; Cu(I)/Cu(II) surface species observed by XPS · HITP = 2,3,6,7,10,11-hexaiminotriphenylene, generated from HATP precursor | 2D · PristineMetal-organic graphite analogue; stacked monomolecular layers form parallel micropores; PXRD peaks at 4.6, 9.5 and 27.6 degrees identify Cu3(HITP)2. | p002 · Introduction |
| Cu3(HITP)2 MOF at PS template intermediateBrowse family: Cu₃(HITP)₂ / Cu–HITP | Cu3(HITP)2 with embedded/removable PS templateCu ions coordinated to HITP linker network · HITP linker from HATP precursor | 2D · CompositeIntermediate Cu3(HITP)2 MOF at PS layer before THF template removal; morphology remains isomorphic with solid HATP ligand at PS. | p004 · 2.3 Morphologies of each stage · Figure 2c,g |
| Polystyrene nanosphere template | PSnone · styrene-derived polymer template | unknown · UnknownSelf-assembled PS photonic-crystal template used to generate the TOM morphology. | p004 · 2.3 Morphologies of each stage · Figure 2a,e |
| Raw-Cu3(HITP)2 film without TOM structureBrowse family: Cu₃(HITP)₂ / Cu–HITP | Cu3(HITP)2Cu ions coordinated to HITP linker network · HITP linker from HATP precursor | 2D · PristineNo-template Cu3(HITP)2 film control on IDE; lacks ordered submicron macropores. | p006 · 2.5 H2S gas sensor · Figure S4 |
| TOM-Cu3(HITP)2 filmBrowse family: Cu₃(HITP)₂ / Cu–HITP | Cu3(HITP)2 with three-dimensional ordered submicron macroporesCu ions coordinated to HITP linker network · HITP linker from HATP precursor | 2D · PristineCu3(HITP)2 framework film with TOM-micropore hierarchical morphology; submicron macropores are 3D ordered in short-range domains. | p001 · Abstract |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Cu3(HITP)2 MOF at PS on IDE intermediateresearch_0853__mat__cu_hitp2_ps_intermediate | Electrode · Composite Sample · Composite | Solid HATP ligand at PS layer converted instantly to black Cu3(HITP)2 MOF at PS layer before THF removal.commercial ceramic-based gold interdigital electrode · not reported | p004 · 2.3 Morphologies of each stage · Figure 2c,g |
| Ordinary Cu3(HITP)2 MOF comparisonresearch_0853__mat__cu_hitp2_framework | Powder · Pristine Control · Pristine Framework | Synthesised by previous literature route; exact recipe not provided in assigned documents. | p007 · Experimental Section · Figure 3d-g |
| Pure PS templates on IDEresearch_0853__mat__ps_template | Thin Film · Model System · Model | Self-assembled PS suspension layer on IDE.commercial ceramic-based gold interdigital electrode · not reported | p004 · 2.3 Morphologies of each stage · Figure 2a,e |
| IDE loaded with Raw-Cu3(HITP)2 filmresearch_0853__mat__raw_cu_hitp2 | Electrode · Pristine Control · Pristine Framework | Same in situ synthesis as TOM film except PS suspension replaced by pure water; no TOM structure.commercial ceramic-based gold interdigital electrode · not reported | p007 · Experimental Section |
| TOM-Cu3(HITP)2 film for spectroscopic characterisationsresearch_0853__mat__tom_cu_hitp2 | Thin Film · Target Sample · Pristine Framework | Same TOM-Cu3(HITP)2 synthesis as IDE sample with substrate replaced according to measurement requirements.quartz plate for XRD; glass substrate for XPS material collection · not reported | p007 · Experimental Section |
| IDE loaded with TOM-Cu3(HITP)2 filmresearch_0853__mat__tom_cu_hitp2 | Electrode · Target Sample · Pristine Framework | In situ quasi solid-liquid synthesis on IDE; PS templates removed by repeated THF soaking/washing, water soaking, final THF soaking and vacuum drying at 80 deg C for 24 h.commercial ceramic-based gold interdigital electrode · about several microns | p003 · 2.2 Morphology · Figure 1 |