Measurement evidence
Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks · Yang M., Tan J., Wang Z. et al. · Journal of the American Chemical Society · 2025 · 24152-24161
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Cu-S-HHS solvothermal powder · Powder
Cu-X-HHS/Nafion dispersion on glassy carbon electrode; Ag/Ag+ reference, Pt counter; 0.4 mol/L TBAPF6 in dry acetonitrile; -1.2 to 1.2 V vs Ag/Ag+ at 50 mV s-1 under N2.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu-S-HHS CV redox response | multiple redox peaks from redox-active Cu ions and X-HHS ligands | — | — | Text Qualitative | 24156 · Analysis of the Electronic Structure · Figure S40 |
Cu-Se-HHS solvothermal powder · Powder
Cu-X-HHS/Nafion dispersion on glassy carbon electrode; Ag/Ag+ reference, Pt counter; 0.4 mol/L TBAPF6 in dry acetonitrile; -1.2 to 1.2 V vs Ag/Ag+ at 50 mV s-1 under N2.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu-Se-HHS CV redox response | multiple redox peaks from redox-active Cu ions and X-HHS ligands | — | — | Text Qualitative | 24156 · Analysis of the Electronic Structure · Figure S40 |
Cu-Te-HHS solvothermal powder · Powder
Cu-X-HHS/Nafion dispersion on glassy carbon electrode; Ag/Ag+ reference, Pt counter; 0.4 mol/L TBAPF6 in dry acetonitrile; -1.2 to 1.2 V vs Ag/Ag+ at 50 mV s-1 under N2.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu-Te-HHS CV redox response | multiple redox peaks from redox-active Cu ions and X-HHS ligands | — | — | Text Qualitative | 24156 · Analysis of the Electronic Structure · Figure S40 |