Synthesis · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

S13 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S2

Metal precursorscopper(II) trifluoroacetylacetonate, 25.14 mg (0.068 mmol)

Linker precursorsS-HHS, 16.56 mg (0.04 mmol)

SolventsN-methylpyrrolidone (1 mL); H2O (3 mL)

Atmosphereloosely capped under air

Temperature85

Time24

Work-upcentrifugation; washed with water and acetone

Activationvacuum dried 12 h at 40 ℃

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	hexahydroxytrithiasumanene (S-HHS)	16.56 mg, 0.04 mmol	S13 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S2
Solvent	N-methylpyrrolidone (NMP)	1 mL	S13 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S2
Solvent	H2O	3 mL	S13 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S2
Metal Source	copper(II) trifluoroacetylacetonate	25.14 mg, 0.068 mmol	S13 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S2

Complete recipeSource: Both

S14 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S3

Metal precursorscopper nitrate trihydrate aqueous solution, 540 uL (0.045 mmol, 20 mg/mL)

Linker precursorsSe-HHS, 16.73 mg (0.03 mmol)

SolventsN-methylpyrrolidone (1 mL); H2O (2.46 mL)

Atmospheregently capped in air

Temperature85

Time24

Work-upcentrifugation; washed with water and acetone

Activationvacuum dried 12 h at 40 ℃

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	hexahydroxytriselenasumanene (Se-HHS)	16.73 mg, 0.03 mmol	S14 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S3
Solvent	N-methylpyrrolidone (NMP)	1 mL	S14 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S3
Solvent	H2O	2.46 mL	S14 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S3
Metal Source	copper nitrate trihydrate aqueous solution	540 uL, 0.045 mmol · 20 mg/mL	S14 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S3

Complete recipeSource: Both

S15 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S4

Metal precursorscopper nitrate trihydrate aqueous solution, 540 uL (0.045 mmol, 20 mg/mL)

Linker precursorsTe-HHS, 21.2 mg (0.03 mmol)

SolventsN,N-dimethylacetamide (DMAc, 1 mL); ethylene glycol (3 mL)

Additivessodium acetate, 15 mg (0.18 mmol)

Atmospheregently capped in air

Temperature85

Time24

Work-upcentrifugation; washed with water and acetone

Activationvacuum dried 12 h at 40 ℃

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Linker	hexahydroxytritellurasumanene (Te-HHS)	21.2 mg, 0.03 mmol	S15 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S4
Base	sodium acetate	15 mg, 0.18 mmol	S15 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S4
Solvent	dimethylacetamide (DMAc)	1 mL	S15 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S4
Solvent	ethylene glycol	3 mL	S15 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S4
Metal Source	copper nitrate trihydrate aqueous solution	540 uL, 0.045 mmol · 20 mg/mL	S15 · 2.2. Synthesis of Cu-X-HHS MOFs · Scheme S4